A resin composition includes 100 parts by weight of an unsaturated C═C double bond-containing polyphenylene ether resin; 15 parts by weight to 40 parts by weight of a hydrogenated styrene-butadiene-styrene triblock copolymer; 1 part by weight to 20 parts by weight of a compound of Formula (1); and 0.001 part by weight to 0.5 part by weight of a compound of Formula (2), a compound of Formula (3), a compound of Formula (4) or a combination thereof. Moreover, an article may be made from the resin composition, including a prepreg, a resin film, a laminate or a printed circuit board.

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A resin composition includes 100 parts by weight of an unsaturated C═C double bond-containing polyphenylene ether resin; 15 parts by weight to 40 parts by weight of a hydrogenated styrene-butadiene-styrene triblock copolymer; 1 part by weight to 20 parts by weight of a compound of Formula (1); and 0.001 part by weight to 0.5 part by weight of a compound of Formula (2), a compound of Formula (3), a compound of Formula (4) or a combination thereof. Moreover, an article may be made from the resin composition, including a prepreg, a resin film, a laminate or a printed circuit board.

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Provided is a block copolymer composition which contains a block copolymer having a specific molecular structure and has a molecular weight distribution within an appropriate range. A polymerizable composition containing a macromonomer (A) which has a group having a radical-reactive unsaturated double bond at one terminal of a poly(meth)acrylate segment, a vinyl monomer (B), and an organic iodine compound (C), or a polymerizable composition containing a macromonomer (A), a vinyl monomer (B), an azo-based radical polymerization initiator (E), and iodine is polymerized to obtain a block copolymer composition containing a block copolymer in which constitutional units of all blocks are derived from vinyl monomers and at least one block has a branched structure.

Provided is a block copolymer composition which contains a block copolymer having a specific molecular structure and has a molecular weight distribution within an appropriate range. A polymerizable composition containing a macromonomer (A) which has a group having a radical-reactive unsaturated double bond at one terminal of a poly(meth)acrylate segment, a vinyl monomer (B), and an organic iodine compound (C), or a polymerizable composition containing a macromonomer (A), a vinyl monomer (B), an azo-based radical polymerization initiator (E), and iodine is polymerized to obtain a block copolymer composition containing a block copolymer in which constitutional units of all blocks are derived from vinyl monomers and at least one block has a branched structure.

Provided is a binder composition for a non-aqueous secondary battery electrode with which it is possible to form a slurry composition for a non-aqueous secondary battery electrode having excellent stability and an electrode for a non-aqueous secondary battery having excellent peel strength after thermal drying. The binder composition for a non-aqueous secondary battery electrode contains a particulate polymer A and a particulate polymer B. The particulate polymer A includes: a backbone portion formed of a block copolymer that includes an aromatic vinyl monomer unit and an aliphatic conjugated diene monomer unit; and a graft portion. The particulate polymer B includes an aliphatic conjugated diene monomer unit in a proportion of 70.0 mass % or more and includes a graft portion.

Provided is a binder composition for a non-aqueous secondary battery electrode with which it is possible to form a slurry composition for a non-aqueous secondary battery electrode having excellent stability and an electrode for a non-aqueous secondary battery having excellent peel strength after thermal drying. The binder composition for a non-aqueous secondary battery electrode contains a particulate polymer A and a particulate polymer B. The particulate polymer A includes: a backbone portion formed of a block copolymer that includes an aromatic vinyl monomer unit and an aliphatic conjugated diene monomer unit; and a graft portion. The particulate polymer B includes an aliphatic conjugated diene monomer unit in a proportion of 70.0 mass % or more and includes a graft portion.

Provided is a binder composition for a non-aqueous secondary battery electrode with which it is possible to form a slurry composition for a non-aqueous secondary battery electrode having excellent stability and an electrode for a non-aqueous secondary battery having excellent peel strength after thermal drying. The binder composition for a non-aqueous secondary battery electrode contains a particulate polymer A and a particulate polymer B. The particulate polymer A includes: a backbone portion formed of a block copolymer that includes an aromatic vinyl monomer unit and an aliphatic conjugated diene monomer unit; and a graft portion. The particulate polymer B includes an aliphatic conjugated diene monomer unit in a proportion of 70.0 mass % or more and includes a graft portion.

Provided are a (meth)acrylic block copolymer exhibiting good active energy ray curability, in particular, curability of a blend thereof with an acrylate monomer, and an active energy ray curable composition comprising the (meth)acrylic block copolymer. The (meth)acrylic block copolymer includes a methacrylic polymer block (A) having an active energy ray curable group including a partial structure represented by the general formula (1) below wherein R.sup.1 denotes a hydrocarbon group having 1 to 10 carbon atoms, and W denotes a saturated hydrocarbon group having 1 to 10 carbon atoms, and an acrylic polymer block (B) having no active energy ray curable groups. ##STR00001##

Provided are a (meth)acrylic block copolymer exhibiting good active energy ray curability, in particular, curability of a blend thereof with an acrylate monomer, and an active energy ray curable composition comprising the (meth)acrylic block copolymer. The (meth)acrylic block copolymer includes a methacrylic polymer block (A) having an active energy ray curable group including a partial structure represented by the general formula (1) below wherein R.sup.1 denotes a hydrocarbon group having 1 to 10 carbon atoms, and W denotes a saturated hydrocarbon group having 1 to 10 carbon atoms, and an acrylic polymer block (B) having no active energy ray curable groups. ##STR00001##

This invention relates to a process for forming an azide-grafted polymer. The process comprises mixing a free-radical-reactive polymer with a free-radical initiator and an azide monomer that contains at least one unsaturated C═C bond capable of reacting with a radical, under solid-state grafting conditions, to form an azide-grafted polymer. The formed azide-grafted polymer can be used to prepare a long-chain branched or cross-linked polymer.