A water-soluble photo-activatable polymer including: a photo-activatable group adapted to be activated by an irradiation source and to form a covalent bond between the water-soluble photo-activatable polymer and a matrix having at least one carbon; a reactive group adapted to covalently react with a biomaterial for subsequent delivery of the biomaterial to a cell; a hydrophilic group; and a polymer precursor. A composition including a monomolecular layer of the water-soluble photo-activatable polymer and a matrix having at least one carbon, wherein the monomolecular layer is covalently attached to the matrix by a covalent bond between the photo-activatable group and the at least one carbon. The composition further includes a biomaterial having a plurality of active groups, wherein the biomaterial is covalently attached to the monomolecular layer by covalent bonding between the active groups and reactive groups. Also provided is a method for delivery of a biomaterial to a cell.

A water-soluble photo-activatable polymer including: a photo-activatable group adapted to be activated by an irradiation source and to form a covalent bond between the water-soluble photo-activatable polymer and a matrix having at least one carbon; a reactive group adapted to covalently react with a biomaterial for subsequent delivery of the biomaterial to a cell; a hydrophilic group; and a polymer precursor. A composition including a monomolecular layer of the water-soluble photo-activatable polymer and a matrix having at least one carbon, wherein the monomolecular layer is covalently attached to the matrix by a covalent bond between the photo-activatable group and the at least one carbon. The composition further includes a biomaterial having a plurality of active groups, wherein the biomaterial is covalently attached to the monomolecular layer by covalent bonding between the active groups and reactive groups. Also provided is a method for delivery of a biomaterial to a cell.

Provided are: a curable composition that makes it possible to form a cured film having excellent wear resistance and weather resistance; a laminate that is provided with the cured film; and an automobile headlamp lens. The curable composition makes it possible to obtain a cured film in which the relationship between a haze value (Hx) that is obtained by a wear resistance test and a haze value (Hy) that is obtained by a weather resistance test satisfies Hy0.3 Hx+5.0 when a cured film having a thickness of 10 m is produced.

The present invention provides polymer modified aqueous urea formaldehyde resin (UF resin) binder compositions useful in making a treated glass mat, e.g., for roofing shingles, wherein the polymer modifier is an multistage aqueous emulsion acorn copolymer comprising one protuberant polymer stage containing phosphorous acid groups and one or more other polymer stage comprising an addition copolymer incompatible with the protuberant polymer stage, wherein the multistage aqueous emulsion copolymer has a measured Tg of from 60 to 25 C., or, preferably from 31 30 to 12 C. and, further wherein the weight ratio of the total of monomers used to make the one or more other polymer stage to the total amount of monomers used to make the protuberant polymer stage ranges from 3:1 to 50:1, or, preferably, from 3:1 to 30:1 or, more preferably, from 3:1 to 20:1, or, even more preferably, from 8:1 to 12:1.

Biodegradable photoluminescent polymer (BPLP) which comprises an oligomer synthesized from a multifunctional monomer, a diol, and an amino acid by reacting (i) a multifunctional monomer comprising citric acid or triethyl citrate with (ii) a diol to form a reaction product, and further reacting the reaction product with (iii) an amino acid, wherein the amino acid is linked as a side group to the oligomer backbone. The BPLP of the present invention poses tunable fluorescence emission characteristics and are cell-compatible and biodegradable. The BPLP can serve as both implant materials and bioimaging probes.

Biodegradable photoluminescent polymer (BPLP) which comprises an oligomer synthesized from a multifunctional monomer, a diol, and an amino acid by reacting (i) a multifunctional monomer comprising citric acid or triethyl citrate with (ii) a diol to form a reaction product, and further reacting the reaction product with (iii) an amino acid, wherein the amino acid is linked as a side group to the oligomer backbone. The BPLP of the present invention poses tunable fluorescence emission characteristics and are cell-compatible and biodegradable. The BPLP can serve as both implant materials and bioimaging probes.

A modified liquid diene-based rubber (A) including, in a molecule, a modified group (a) containing a (meth)acryloyl group as a part thereof and at least one modified group (b) selected from a dicarboxylic acid monoester and a dicarboxylic acid monoamide, with the proviso that the modified group (b) comprises no (meth)acryloyl group as a part thereof, wherein the functional group equivalent weights of the modified group (a) and the modified group (b) are each in the range of 700 to 40,000 g/eq. Also provided is a curable resin composition containing the modified liquid diene-based rubber.

A modified liquid diene-based rubber (A) including, in a molecule, a modified group (a) containing a (meth)acryloyl group as a part thereof and at least one modified group (b) selected from a dicarboxylic acid monoester and a dicarboxylic acid monoamide, with the proviso that the modified group (b) comprises no (meth)acryloyl group as a part thereof, wherein the functional group equivalent weights of the modified group (a) and the modified group (b) are each in the range of 700 to 40,000 g/eq. Also provided is a curable resin composition containing the modified liquid diene-based rubber.

A photopolymerizable material contains, as a main polymerization component, a bicarbazole compound represented by structural formula (1).

##STR00001##

In structural formula (1), X.sup.1 and X.sup.2 are each independently a photopolymerizable functional group, a structural site having a photopolymerizable functional group, or a hydrogen atom, at least one of X.sup.1 and X.sup.2 is a photopolymerizable functional group or a structural site having a photopolymerizable functional group, R.sup.1 and R.sup.2 are each independently a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, an alkoxy group having 1 to 4 carbon atoms, a bromine atom, or a chlorine atom, and at least one of R.sup.1 and R.sup.2 is a hydrogen atom.

A polymerization initiator system for reactive monomers and unsaturated polymers which is contains a Group 4 transition metal or Group 4 transition metal-containing compound, peroxide or diazo compound that is capable of being reduced by the Group 4 transition metal or Group 4 transition metal-containing compound, and pinacol compound is disclosed. Further disclosed are methods for preparing the polymerization initiator and using the polymerization initiator for low temperature curing.