A curable polymer latex composition obtainable by: (a) subjecting a monomer mixture comprising i. at least one conjugated diene; ii. at least one ethylenically unsaturated nitrile; iii. optionally at least one ethylenically unsaturated acid; iv. optionally at least one further ethylenically unsaturated compound different from any of the compounds (i)-(iii); to free-radical emulsion polymerization in an aqueous reaction medium to form a raw polymer latex; and (b) allowing the obtained raw latex to mature in the presence of at least one thiocarbonyl-functional compound, wherein the at least one thiocarbonyl-functional compound is present in an amount of at least 0.05 wt.-%, based on the total amount of monomers subjected to free-radical emulsion polymerization in step (a), and (c) optionally compounding the matured polymer latex with one or more cross-linking agent. Methods for making such curable polymer latex composition or rubber articles made therefrom, respectively.

A laminate has an olefin-aromatic vinyl compound-aromatic polyene copolymer and a metal foil. The number average molecular copolymer weight is between 5000 and 100000; the aromatic vinyl compound monomer is aromatic vinyl compound having between 8 and 20 carbon atoms, and the aromatic vinyl compound monomer unit content is between 10 and 60 mass %; the aromatic polyene is selected having between 5 and 20 carbon atoms and vinyl and/or vinylene groups in the molecule, the content derived from the aromatic polyene unit is between 1.5 and 20 pieces per number average molecular weight; and the olefin is selected having between 2 and 20 carbon atoms, being ethylene alone, or having a mass ratio of α-olefin monomer components other than ethylene to an ethylene monomer component contained in the olefin, of 1/7 or less, and the total monomer units of the olefin, aromatic vinyl compound, and aromatic polyene is 100 mass %.

A laminate has an olefin-aromatic vinyl compound-aromatic polyene copolymer and a metal foil. The number average molecular copolymer weight is between 5000 and 100000; the aromatic vinyl compound monomer is aromatic vinyl compound having between 8 and 20 carbon atoms, and the aromatic vinyl compound monomer unit content is between 10 and 60 mass %; the aromatic polyene is selected having between 5 and 20 carbon atoms and vinyl and/or vinylene groups in the molecule, the content derived from the aromatic polyene unit is between 1.5 and 20 pieces per number average molecular weight; and the olefin is selected having between 2 and 20 carbon atoms, being ethylene alone, or having a mass ratio of α-olefin monomer components other than ethylene to an ethylene monomer component contained in the olefin, of 1/7 or less, and the total monomer units of the olefin, aromatic vinyl compound, and aromatic polyene is 100 mass %.

Methods for preparing water soluble, non-peptidic polymers carrying carboxyl functional groups, particularly carboxylic acid functionalized poly(ethylene glycol) (PEG) polymers are disclosed, as are the products of these methods. In general, an ester reagent R(C═O)OR′, wherein R′ is a tertiary group and R comprises a functional group X, is reacted with a water soluble, non-peptidic polymer POLY-Y, where Y is a functional group which reacts with X to form a covalent bond, to form a tertiary ester of the polymer, which is then treated with a strong base in aqueous solution, to form a carboxylate salt of the polymer. Typically, this carboxylate salt is then treated with an inorganic acid in aqueous solution, to convert the carboxylate salt to a carboxylic acid, thereby forming a carboxylic acid functionalized polymer.

Methods for preparing water soluble, non-peptidic polymers carrying carboxyl functional groups, particularly carboxylic acid functionalized poly(ethylene glycol) (PEG) polymers are disclosed, as are the products of these methods. In general, an ester reagent R(C═O)OR′, wherein R′ is a tertiary group and R comprises a functional group X, is reacted with a water soluble, non-peptidic polymer POLY-Y, where Y is a functional group which reacts with X to form a covalent bond, to form a tertiary ester of the polymer, which is then treated with a strong base in aqueous solution, to form a carboxylate salt of the polymer. Typically, this carboxylate salt is then treated with an inorganic acid in aqueous solution, to convert the carboxylate salt to a carboxylic acid, thereby forming a carboxylic acid functionalized polymer.

The present invention provides a curable composition, a pressure-sensitive adhesive, an adhesive tape, and an adhesive product. The present invention belongs to the technical field of acrylate pressure-sensitive adhesives. The pressure-sensitive adhesive formed of the curable composition of the present invention has good high-temperature and high-humidity repulsion resistance. The curable composition comprises: a monomer component, comprising at least two polymerizable monomers, wherein the polymerizable monomers comprise a non-tertiary alcohol (meth)acrylate monomer, and an acid-functional non-ester unsaturated monomer having at least one olefinic bond; a (meth)acrylate polymer tackifying resin having a specific molecular weight and a glass transition temperature; a non-(meth)acrylate polymer tackifying resin component, comprising at least two non-(meth)acrylate polymer tackifying resins, wherein at least a part of non-(meth)acrylate polymer tackifying resins has a softening point greater than or equal to 130° C.; a cross-linking agent component, comprising an isocyanate cross-linking agent and at least one non-isocyanate cross-linking agent.

The present invention provides a curable composition, a pressure-sensitive adhesive, an adhesive tape, and an adhesive product. The present invention belongs to the technical field of acrylate pressure-sensitive adhesives. The pressure-sensitive adhesive formed of the curable composition of the present invention has good high-temperature and high-humidity repulsion resistance. The curable composition comprises: a monomer component, comprising at least two polymerizable monomers, wherein the polymerizable monomers comprise a non-tertiary alcohol (meth)acrylate monomer, and an acid-functional non-ester unsaturated monomer having at least one olefinic bond; a (meth)acrylate polymer tackifying resin having a specific molecular weight and a glass transition temperature; a non-(meth)acrylate polymer tackifying resin component, comprising at least two non-(meth)acrylate polymer tackifying resins, wherein at least a part of non-(meth)acrylate polymer tackifying resins has a softening point greater than or equal to 130° C.; a cross-linking agent component, comprising an isocyanate cross-linking agent and at least one non-isocyanate cross-linking agent.

This invention includes a wettable biomedical device containing a high molecular weight hydrophilic polymer and a hydroxyl-functionalized silicone-containing monomer.

This invention includes a wettable biomedical device containing a high molecular weight hydrophilic polymer and a hydroxyl-functionalized silicone-containing monomer.

The present invention provides a gel having an interpenetrating network formed from a first network structure and a second network structure, the first network structure being composed of a first crosslinked polymer formed from at least one noncrosslinkable compound selected from the group consisting of a compound represented by the following formula (I) and a compound represented by the following formula (II), and at least one crosslinkable compound selected from the group consisting of a compound represented by the following formula (III) and a compound represented by the following formula (IV), and the second network structure being composed of a second crosslinked polymer having at least one selected from the group consisting of an acidic dissociative group, an acidic dissociative group in a salt form, and a derivative group of an acidic dissociative group:

##STR00001##

wherein the groups are as defined in the DESCRIPTION.