The invention provides a multimodal propylene butene random copolymer having a melt flow rate (MFR2) of 1.0 to 20.0 g/10 min and a butene content of 1.5 to 8.0 wt %, wherein said copolymer is prepared using a single site catalyst and wherein said copolymer comprises (i) 30 to 70 wt % of a propylene butene copolymer (A) having an MFR2 of 0.5 to 20.0 g/10 min and a butene content of 0.5 to 10.0 wt %; and (ii) 70 to 30 wt % of a propylene butene copolymer (B) having an MFR2 of 0.5 to 20.0 g/10 min and a butene content of 1.0 to 8.0 wt %; wherein copolymers (A) and (B) are different.

The invention provides a polyolefin composition comprising: (i) 55 to 95 wt % of a propylene butene random copolymer having an MFR.sub.2 of 1.0 to 20.0 g/10 min, a butene content of 1.5 to 8.0 wt % and prepared using a single site catalyst; and (ii) to 45 wt % of an ethylene based plastomer having a density of 860 to 905 kg/m.sup.3, an MFR.sub.2 of 0.3 to 30 g/10 min and prepared using a single site catalyst.

The invention provides a multimodal propylene butene random copolymer having a melt flow rate (MFR.sub.2) of 1.0 to 20.0 g/10 min and a butene content of 5.0 to 20.0 wt %, wherein said copolymer is prepared using a single site catalyst and wherein said copolymer comprises: (i) 30 to 70 wt % of a propylene butene copolymer (A) having an MFR.sub.2 of 0.5 to 20.0 g/10 min and a butene content of 2.0 to 10.0 wt %; and (ii) 70 to 30 wt % of a propylene butene copolymer (B) having an MFR.sub.2 of 0.5 to 20.0 g/10 min and a butene content of 4.0 to 20.0 wt %; wherein copolymers (A) and (B) are different.

The present disclosure provides a method of determining a relative decrease in catalytic efficacy of a catalyst in a test sample of a catalyst solution with unknown catalytic activity. The method includes (a) mixing the test sample with a test solvent to form a test mixture and (b) measuring the increase in the temperature of the test mixture at predetermined time intervals immediately after forming the test mixture. A predetermined feature is used to determine both a test value in the increase in temperature measured in (b) and a control value in a known increase in temperature of a control mixture of the test solvent with a control sample of a control catalyst solution. The relative decrease in catalytic efficacy of the catalyst in the test sample having the unknown catalytic activity is then determined from: Relative Decrease in Catalytic Efficacy=Control Value−Test Value/Control Value.

The present disclosure provides a method of determining a relative decrease in catalytic efficacy of a catalyst in a test sample of a catalyst solution with unknown catalytic activity. The method includes (a) mixing the test sample with a test solvent to form a test mixture and (b) measuring the increase in the temperature of the test mixture at predetermined time intervals immediately after forming the test mixture. A predetermined feature is used to determine both a test value in the increase in temperature measured in (b) and a control value in a known increase in temperature of a control mixture of the test solvent with a control sample of a control catalyst solution. The relative decrease in catalytic efficacy of the catalyst in the test sample having the unknown catalytic activity is then determined from: Relative Decrease in Catalytic Efficacy=Control Value−Test Value/Control Value.

Ion exchange membranes for use in electrochemical energy conversion and storage applications include copolymers having a backbone produced from an olefin, such as ethylene, and a cyclic olefin, such as norbornene. Haloalkyl side chains with terminal halide groups are connected to the polymer backbone via Friedel-Crafts alkylation. The halide groups are then replaced with ionic groups via substitution. The ion exchange membrane material can then be cast or impregnated into a reinforcing mesh to form cation exchange membrane or anion exchange membranes. Rigidity of the ion exchange membranes can be controlled by varying the ratio of olefin to cyclic olefin in the polymer backbone.

The present invention relates to a process for the production of a polyethylene by polymerisation of a reaction mixture comprising ethylene in the presence a catalyst system and an antistatic agent according to formula I: (I) wherein R1, R2 and R3 stand for a moiety according to formula II or a hydrocarbon moiety having 1 to 20 carbon atoms (II) wherein each of R4, R5 and R6 may be the same or different, and wherein each of R4, R5 and R6 is a hydrocarbon moiety having 1 to 10 carbon atoms, and wherein at least one of R1, R2 and R3 is a moiety according to formula II. Such process allows for the reduction of sheeting in the polymerisation reactor without compromising the polymerisation reaction kinetics.

##STR00001##

A styrene resin having a syndiotactic structure, with an endothermic amount in a range of 175 to 260° C. of less than 30% based on the total endothermic amount, and a styrene resin composition containing 50 to 95% by mass of a thermoplastic resin composition and 5 to 50% by mass of a glass filler, the thermoplastic resin composition containing 100 parts by mass containing 80 to 100% by mass of a styrene resin having a syndiotactic structure and 0 to 20% by mass of a rubbery elastic material, 0.2 to 2.0 parts by mass of at least one kind of an antioxidant selected from a phenol-based antioxidant and a sulfur antioxidant, 1.5 to 5.0 parts by mass of at least one kind of a compound selected from a polyphenylene ether or a modified polyphenylene ether, and at least one kind selected from a nucleating agent or a release agent.

The present invention relates to a catalyst system for producing ethylene copolymers in a high temperature solution process, the catalyst system comprising (i) a metallocene complex of a group 4 transition metal comprising at least one ligand selected from optionally substituted cyclopentadienyl (Cp), indenyl (Ind) and fluorenyl (Flu) ligands and (ii) a solid alkyl aluminium oxide cocatalyst The invention relates also to the preparation of the catalyst system, use thereof in the high temperature solution process and to a process comprising polymerizing ethylene and a C.sub.4-10 alpha-olefin comonomer in a high temperature solution process in the presence of the catalyst system.

A bimodal poly(ethylene-co-1-alkene) copolymer comprising a higher molecular weight poly(ethylene-co-1-alkene) copolymer component and a lower molecular weight poly(ethylene-co-1-alkene) copolymer component. The copolymer is characterized by a unique combination of features comprising, or reflected in, its density; molecular weight distributions; component weight fraction amount; viscoelastic properties; and environmental stress-cracking resistance. Additional inventive embodiments include a method of making the copolymer, a formulation comprising the copolymer and at least one additive that is different than the copolymer, a method of making a manufactured article from the copolymer or formulation; the manufactured article made thereby, and use of the manufactured article.