Patent classifications
C08F2438/00
METHOD FOR PREPARING VINYL ETHER POLYMER BY PHOTO-INITIATED POLYMERIZATION
The invention relates to a method for preparing a vinyl ether polymer by photo-initiated polymerization, which comprises the step of: under a protective atmosphere, performing photo-initiated polymerization on a vinyl ether monomer in the presence of an organic halogenated hydrocarbon and manganese carbonyl under irradiation of light having a wavelength of 365-550 nm at −25° C. to 25° C., to obtain a vinyl ether polymer after the reaction is completed. In the method, a vinyl ether monomer is subjected to cationic polymerization in the presence of manganese carbonyl and an organic halogenated hydrocarbon under visible light, to prepare a vinyl ether polymer with controlled molecular weight and narrow molecular weight distribution.
Modified High Cis Polydiene Polymer, Related Methods And Rubber Compositions
Disclosed herein are a modified high cis polydiene polymer, processes for preparing the modified high cis polydiene polymer, and tire rubber compositions containing the modified high cis polydiene polymer. The processes make use of a functionalizing compound of formula I or formula II and a coupling agent to prepare the modified high cis polydiene polymer from a quantity of conjugated diene monomer polymerized using a lanthanide-based catalyst system. The modified high cis polydiene polymer includes at least one polymer chain having a residue from the functionalizing compound and a residue from the coupling agent and can be utilized in tire rubber compositions in combination with other ingredients such as fillers.
HYDROGEL
A hydrogel includes a dendritic core with 2 to 30 arms, and first and second acrylamide monomers incorporated into each arm. The first acrylamide monomer is: (I), wherein R.sub.1 and R.sub.2 are independently selected from an alkyl, an alkylamino, an alkylamido, an alkylthio, an aryl, a glycol, and optionally substituted variants thereof; and the second acrylamide monomer is: (II), wherein R.sub.3 and R.sub.4 are independently hydrogen or an alkyl; L is a linker including a linear chain of 2 to 20 atoms selected from carbon, oxygen, and nitrogen and optional substituents on the carbon and any nitrogen atoms; A is an N substituted amide: (III), where R.sub.5 is hydrogen or an alkyl; E is a linear chain of 1 to 4 atom(s) selected from carbon, oxygen and nitrogen, and optional substituents on the carbon and any nitrogen atoms; and Z is an optional nitrogen containing heterocycle.
##STR00001##
THERMOPLASTIC RESIN COMPOSITION
A thermoplastic resin composition containing a thermoplastic resin and composite particles in which a polymer graft chain is bonded to a particle surface. The thermoplastic resin composition of the present invention can be suitably used in manufactured products such as audio equipment, electric appliances, construction buildings, industrial equipment, automobile members, members of two-wheelers such as motorcycles and bicycles, and containers.
RUBBER WITH BACKBONE AND END-GROUP FUNCTIONALIZATION
Novel functionalized rubbers having low hysteresis and good compatibility with fillers, such as carbon black and silica, have been synthesized. These functionalized rubbers, including functionalized polybutadiene rubber and functionalized styrene-butadiene rubber, can be beneficially used in making a wide variety of rubber products that have enhanced physical properties. These improved properties are realized because the functional groups therein improve compatibility with reinforcing fillers that are typically included in such rubber compounds. These functionalized rubbers are comprised of polymer chains of the structural formula:
##STR00001##
wherein Polydiene represents a polymer chain which is comprised of at least one diene monomer and wherein R.sup.1 and R.sup.2 can be the same or different and represent alkyl groups containing form 1 to 8 carbon atoms. These rubbers can also be functionally terminated with a silicon containing terminator.
CONSUMER PRODUCT COMPRISING BIODEGRADABLE DELIVERY PARTICLES
A consumer product comprising a biodegradable delivery particle having a benefit agent containing core and a shell.
CONSUMER PRODUCT COMPRISING BIODEGRADABLE DELIVERY PARTICLES
A consumer product comprising a biodegradable delivery particle having a benefit agent containing core and a shell.
CONSUMER PRODUCT COMPRISING BIODEGRADABLE DELIVERY PARTICLES
A consumer product composition including a biodegradable delivery particle having a benefit agent containing core and a shell.
RECYCLABLE CROSSLINKED POLYMER NETWORKS CONTAINING DYNAMIC DIALKYL AMINO DISULFIDE LINKAGES
A composition for forming a dynamic crosslinked polymer network may comprise (a) a dynamic crosslinker having formula R—R″R′N—S—S—NR′R″—R, wherein each R is a polymerizable group comprising a carbon-carbon (C—C) double bond capable of undergoing free radical polymerization and each R′ and each R″ are independently selected alkyl groups; (b) a polymer comprising a C═C double bond capable of undergoing free radical polymerization, a monomer comprising a C═C double bond capable of undergoing free radical polymerization, or combinations thereof; and (c) a free radical initiator, wherein the dynamic crosslinker does not comprise a urethane group.
METHOD FOR PRODUCING ORGANIC TELLURIUM COMPOUND AND METHOD FOR PRODUCING VINYL POLYMER
Provided is a method for producing an organic tellurium compound that enables the production of an organic tellurium compound in high yield using metallic tellurium as a source material and produces less amount of side products. A method for producing an organic tellurium compound includes the steps of: (A) reacting metallic tellurium with a compound represented by a general formula (1) below; and (B) reacting a compound obtained by the step (A) with an organic halogen compound, the metallic tellurium having a copper content of less than 100 ppm,
M(R.sup.1)m Formula (1)
where R.sup.1 represents an alkyl group having 1 to 8 carbon atoms, an aryl group or an aromatic heterocyclic group, M represents an alkali metal or an alkaline earth metal, m represents 1 when M is an alkali metal, and m represents 2 when M is an alkaline earth metal.