Patent classifications
C08F2810/00
Polymer, method for producing same, water- and oil-proofing composition, article, and water- and oil-proof paper
To provide a polymer which can provide a water- and oil-proof paper with excellent water and oil resistance. A polymer comprising the following units a, and at least the following units b among the following units b and the following units c, wherein the ratio of units a to all the units in the polymer is from 28 to 70 mol %, the total ratio of units b and units c to all the units in the polymer is from 30 to 72 mol %, and the ratio of units b to the sum of units b and units c is at least 45 mol %: units a: units represented by (CH.sub.2CHR.sup.f) (wherein R.sup.f is a C.sub.1-8 perfluoroalkyl group), units b: units represented by (CH.sub.2CH(OH)), units c: units represented by (CH.sub.2CH(OC(O)R)) (wherein R is a C.sub.1-4 alkyl group).
PROCESS FOR MANUFACTURING PAPER OR CARDBOARD
A process for making a sheet of paper or cardboard from a fiber suspension, includes injection of a polymer P3 into a cellulosic fiber suspension, formation of a sheet of paper or cardboard, and drying of the sheet of paper or cardboard. The P3 polymer is prepared, prior to the injection, from a water-soluble P1 polymer of at least one nonionic monomer, such as acrylamide, methacrylamide, N,N-dimethylacrylamide, and acrylonitrile. The P1 polymer is subjected to a Re1 reaction to give a P2 polymer, which is then subjected to a Re2 reaction to give the P3 polymer, which is injected into the fibrous suspension within 24 hours of the start of the Re1 reaction.
Modified polyisobutylene polymer for rubber compounding and rubber composition including same
Disclosed is a modified polyisobutylene polymer for rubber compounding. The modified polyisobutylene polymer is prepared by reacting reactants including a polyisobutylene in which the main chain is isobutylene, an unsaturated dicarboxylic anhydride, and an amino group-containing silane compound. The modified polyisobutylene polymer includes a diamide structure. When the modified polyisobutylene polymer is used as an additive for rubber compounding, the processability of the rubber is increased, the dispersibility of fillers is significantly improved, and the effect of obtaining excellent grip performance and improved rolling resistance can be achieved.
FLUOROPOLYMER POWDER AND METHOD FOR PRODUCING SAME
The invention provides a powder that is easily redispersible in a liquid medium such as water. The powder contains a fluoropolymer. The fluoropolymer contains at least one group A selected from the group consisting of SO.sub.2Y, COOR, SO.sub.3X, SO.sub.2NR.sup.1.sub.2, and COOX, wherein Y is a halogen atom; R is a C1-C4 alkyl group; X is M.sub.1/L or NR.sup.1.sub.4, where M is a hydrogen atom or an L-valent metal, the L-valent metal being a metal in group 1, group 2, group 4, group 8, group 11, group 12, or group 13 of the periodic table; and R.sup.1s are each individually a hydrogen atom or a C1-C4 alkyl group. The powder exhibits a dispersion of 50% or higher. The dispersion is calculated by filtering a composition obtainable by mixing the powder with water through a mesh having an opening of 20 m.
METHOD OF PRODUCING MODIFIED CONJUGATED DIENE-BASED POLYMER, MODIFIED CONJUGATED DIENE-BASED POLYMER, RUBBER COMPOSITION AND TIRE
A method, of the present disclosure, of producing a modified conjugated diene-based polymer includes a polymerization reaction process of polymerizing a conjugated diene monomer in the presence of a polymerization catalyst composition to obtain a conjugated diene-based polymer, an organic metal compound adding process of adding an organic metal compound after the polymerization reaction process, and a modification reaction process of modifying the conjugated diene-based polymer with a modifying agent after the organic metal compound adding process. A rubber composition of the present disclosure includes a modified conjugated diene-based polymer produced by the method. A tire of the present disclosure includes the rubber composition.
FILLER-REINFORCED RESIN STRUCTURE
The present invention relates to a filler-reinforced resin structure, and the structure is a structure containing a carbodiimide-modified polyolefin (A) having a carbodiimide group content of 1 to 200 mmol/100 g; or a structure containing a carbodiimide-modified polyolefin (A) having a carbodiimide group content of 1 to 200 mmol/100 g, a polypropylene resin, and a carbon fiber, and the structure containing 0.0001 to 140 mmol of the carbodiimide group based on 100 g of resin components in the structure.
FUNCTIONALIZED POROUS ORGANIC POLYMERS AS URANIUM NANO-TRAPS FOR EFFICIENT URANIUM EXTRACTION
Compositions are provided for efficient uranium extraction, for example from wastewater, seawater, or other water sources. The compositions can include a functionalized porous organic polymer functionalized with one or more uranium binding moieties, e.g. having a plurality of amidoxime or amidrazone groups covalently attached thereto. The compositions can include covalent organic frameworks, porous aromatic frameworks, and various porous organic polymers, especially those having a hierarchical pore size distribution over a range of pore sizes. The compositions can have functional groups such as amidoxime or an amidrazone covalently attached thereto. The hierarchical pore size distribution can be determined based upon at least 60% of the pore sizes in the range of pore sizes having a pore volume of at least 0.01 cm.sup.3 g.sup.?1 in the pore size distribution at 77 K. Methods of making the compositions and methods of using the compositions are also provided.
IMPREGNATED CELLULAR CARBON NANOCOMPOSITES
Disclosed herein is a nanocomposite including a carbonaceous perimorph, the perimorph having a diameter of less than 1,000 ?m and comprising interconnected cells, each of a plurality of the cells comprising a carbonaceous cell wall possessing an average thickness of less than 100 nm or smaller and a morphology corresponding to a surface region of a, non-metallic template particle, the template particle having a diameter of less than 1,000 ?m, and an interior space bounded and enclosed by the cell wall.
POLYVINYL ALCOHOL USED AS DISPERSING AGENTS FOR POLYVINYL CHLORIDE SUSPENSION POLYMERIZATION, DISPERSING AGENTS COMPRISING THE POLYVINYL ALCOHOL, AND METHOD FOR PRODUCING POLYVINYL CHLORIDE USING THE POLYVINYL ALCOHOL
The polyvinyl alcohol according to the present invention to be used as a dispersant for suspension polymerization for polyvinyl chloride has a degree of saponification of 60 to 80 mol %, a block character of 0.4 to 0.6, an integration value defined by the following (a) of 0.04 to 0.1 and an integration value defined by the following (b) of 0.01 to 0.2 in a .sup.1H-NMR spectrum, and a 0.1% by mass aqueous solution of the polyvinyl alcohol has a UV absorbance at a wavelength of 320 nm of 0.18 or more and less than 0.3. (a) An integration value from 5.42 to 5.62 ppm of a peak or peaks observed at 5.50 to 5.54 ppm when an integration value from 3.65 to 4.05 ppm of a peak or peaks observed at 3.83 to 3.87 ppm is assumed to be 100. (b) An integration value from 5.76 to 5.98 ppm of a peak or peaks observed at 5.86 to 5.90 ppm when an integration value from 3.65 to 4.05 ppm of a peak or peaks observed at 3.83 to 3.87 ppm is assumed to be 100.
ULTRAHIGH MELT FLOW STYRENIC BLOCK COPOLYMERS
The disclosure relates to a hydrogenated styrenic block copolymer with high vinyl content, low viscosity, low order-disorder temperature and improved processability. The hydrogenated styrenic block copolymers can be extruded or molded with a minimum of additives. The hydrogenated styrenic block copolymers have high melt flows allowing for ease in processing such as injection molding, overmolding, dipping, extrusion, roto-molding, slush molding, fiber spinning, film making, 3D printing and foaming.