Multi-layer optical films that can be utilized as polarizer or mirror films and can be incorporated into optical stacks. The optical film includes a plurality of alternating polymeric first and second interference layers numbering greater than 50 and disposed between, and integrally formed with, first and second skin layers, each of the first and second interference layers has an average thickness less than 250 nm. The first and second interference layers and the first and second skin layers are compositions that include polyester.

Multi-layer optical films that can be utilized as polarizer or mirror films and can be incorporated into optical stacks. The optical film includes a plurality of alternating polymeric first and second interference layers numbering greater than 50 and disposed between, and integrally formed with, first and second skin layers, each of the first and second interference layers has an average thickness less than 250 nm. The first and second interference layers and the first and second skin layers are compositions that include polyester.

In some aspects, the present disclosure pertains to multi-arm polymers that comprise a core, a plurality of polymer segments having a first end that is covalently attached to the core and a second end comprising a moiety that comprises a reactive group, wherein the polymer segments comprise one or more free-radical-polymerizable monomers. In some aspects, systems are provided that comprise a first composition comprising such a multi-arm polymer and a second composition comprising a multifunctional compound that comprises functional groups that are reactive with the reactive groups of the multi-arm polymer. In some aspects, systems are provided that comprise crosslinked reaction products of such a multi-arm polymer and such a multifunctional compound.

Improved processes for making glyceride oligomers are generally disclosed herein. In some embodiments, the disclosed processes provide improved methods of using olefin metathesis to oligomerize unsaturated glycerides to make novel branched-chain polyester compositions. In some aspects, the disclosure also provides compositions formed by such processes.

Described herein are methods of preparing cutin-derived monomers, oligomers, or combinations thereof from cutin-containing plant matter. The methods can include heating the cutin-derived plant matter in a solvent at elevated temperature and pressure. In some preferred embodiments, the methods can be carried out without the use of additional acidic or basic species.

The present disclosure relates to a composition that includes ##STR00001##
where A includes at least one of a carbon-carbon bond or a bridging group, R includes between 0 and 4 of a first hydrocarbon, and n is between 2 and 3,000. In some embodiments of the present disclosure, the bridging group may include a linear hydrocarbon chain and/or a branched hydrocarbon chain. In some embodiments of the present disclosure, the bridging group may include between 1 and 10 carbon atoms.

The present disclosure relates to a composition that includes ##STR00001##
where A includes at least one of a carbon-carbon bond or a bridging group, R includes between 0 and 4 of a first hydrocarbon, and n is between 2 and 3,000. In some embodiments of the present disclosure, the bridging group may include a linear hydrocarbon chain and/or a branched hydrocarbon chain. In some embodiments of the present disclosure, the bridging group may include between 1 and 10 carbon atoms.

Described herein is a feasible, significantly simplified production method that avoids challenging lactonization steps and converts a low molecular weight aliphatic polyester, consisting of hydroxy acids and a comonomer, whose molecular weight has been increased by step-growth polymerization reactions. The molecular weight of the aliphatic polyester, based on comparison of initial and final weight average molecular weights (M.sub.w,1/M.sub.w,2), increased significantly at a rate which permits the use of reactive extrusion to produce high molecular weight aliphatic polyesters in a simple, economically feasible manner.

Described herein is a feasible, significantly simplified production method that avoids challenging lactonization steps and converts a low molecular weight aliphatic polyester, consisting of hydroxy acids and a comonomer, whose molecular weight has been increased by step-growth polymerization reactions. The molecular weight of the aliphatic polyester, based on comparison of initial and final weight average molecular weights (M.sub.w,1/M.sub.w,2), increased significantly at a rate which permits the use of reactive extrusion to produce high molecular weight aliphatic polyesters in a simple, economically feasible manner.

This invention relates to a curable composition comprising: I. a first component comprising a resin having at least one functional group selected from the group consisting of β-ketoester and malonate functional groups, II. a second component comprising at least one curing agent having at least one aldehyde functional group, and III. a third component comprising at least one primary amine or at least one secondary amine, salts thereof, or combinations thereof.