Compositions that are curable by free radical redox reactions are disclosed. Free radical curing reactions between polythiols and polyalkyenyls are initiated by the reaction of metal complexes and organic peroxides. The compositions are useful as sealants.

Process for the production of a liquid mercapto-terminated polythioethersulfide comprising the step of reacting, at a temperature in the range 0-100° C. and in the presence of a catalyst: at least one compound selected from the group consisting of (i) dimercapto-dioxa-alkanes (DMDAs) and (ii) glycol di(mercapto carboxylic acid ester)s (GDMEs), at least one dimercapto-dialkyl sulfide (DMDS) at least one di-epoxide, and optionally at least one branching agent selected from compounds having at least three terminal groups selected from epoxy and mercapto groups,
wherein the molar ratio (DMDA+GDME)/DMDS is in the range 1.1-4.0.

Described herein are polyphenylene sulfide (“PPS”) polymer compositions including a low MFR PPS polymer and E-CR glass fibers. It was surprisingly discovered that the PPS polymer compositions had significantly improved retention of tensile strength and tensile elongation after water aging (“water aging performance”), relative to corresponding PPS polymer compositions having E glass fibers instead of the E-CR glass fibers. Moreover, it was also discovered that PPS polymer compositions including E-CR glass fibers in conjunction with a low MFR PPS polymer and a high MFR PPS polymer had unexpected synergies with respect to water aging performance, relative to corresponding polymer compositions including E-CR glass fibers and either a low MFR PPS polymer or a high MFR PPS. Due at least in part to the improved water aging performance, the PPS polymer compositions can be advantageously incorporated into application settings where the polymer composition is in contact with water. Examples include, but are not limited to, drinking water applications.

Described herein are polymer compositions having a poly(ether sulfone) polymer and (i) a polysulfone polymer or (ii) a poly(phenyl sulfone) polymer. In some embodiments, the polymer compositions can optionally include one or more additives. It has been surprisingly found that the aforementioned polymer compositions have outstanding anti-stick properties with respect to proteins.

Described herein are polymer compositions having a poly(ether sulfone) polymer and (i) a polysulfone polymer or (ii) a poly(phenyl sulfone) polymer. In some embodiments, the polymer compositions can optionally include one or more additives. It has been surprisingly found that the aforementioned polymer compositions have outstanding anti-stick properties with respect to proteins.

A degradable polyethylene glycol derivative represented by formula (1). R.sup.1, R.sup.2, and R.sup.4 represent each independently a hydrogen atom or a hydrocarbon group having from 1 to 6 carbon atoms, and at least one of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 is the hydrocarbon group; P.sup.1 is a straight-chain or branched polyethylene glycol chain having a number of ethylene glycol units of 3 or more; P.sup.2 is a straight-chain polyethylene glycol chain having a number of ethylene glycol units of 3 or more; w is an integer of 1 to 8; u is an integer of 1 to 10; X.sup.1 is a chemically reactive functional group; and Z.sup.1, Z.sup.2 and Z.sup.3 are each independently a selected divalent spacer. ##STR00001##

A semicrystalline polyphenylsulfone, has the structure Formula (I) wherein n and R are defined herein. The semicrystalline polyphenylsulfone, which exhibits a crystalline melting point in a range of 215 to 270° C., can be prepared from amorphous polyphenylsulfone using a solvent-induced crystallization method. An additive manufacturing method utilizing particles of the semicrystalline polyphenylsulfone is described.

A composition is described comprising an amine-reactive material; and a polymeric catalyst comprising hydroxyl groups and tertiary amine groups. The polymeric catalyst is typically suspended or dispersed in a liquid dispersant. The liquid dispersant does not covalently bond with the tertiary amine groups. The liquid dispersant is typically a hydroxy-functional or thiol-functional. Also described is a polymer network comprising the cured composition described herein, a polymer catalyst, and catalyst dispersion; as well as methods.

Aspects of the present disclosure relate to Schiff base oligomers and uses thereof. In at least one aspect, an oligomer is represented by Formula (I) wherein each instance of R.sup.4, R.sup.5, R.sup.6, R.sup.7, R.sup.8, R.sup.10, R.sup.11, R.sup.12, R.sup.13, and R.sup.14 is independently selected from the group consisting of hydrogen, alkyl, cycloalkyl, alkoxyl, aryloxyl, ether, and heterocyclyl. Each instance of R.sup.9 of Formula (I) is independently selected from the group consisting of alkyl, cycloalkyl, aryl, heterocyclyl, and ether. Each instance of R.sup.28 and R.sup.29 of Formula (I) is independently selected from the group consisting of hydrogen, alkyl, and aryl. Each instance of R.sup.33 of Formula (I) is independently selected from the group consisting of alkyl, cycloalkyl, aryl, heterocyclyl, and a bond. Each instance of R.sup.41 of Formula (I) is independently —NH— or a bond and each instance of R.sup.40 is independently —NH— or —NH—NH—.

Aspects of the present disclosure relate to Schiff base oligomers and uses thereof. In at least one aspect, an oligomer is represented by Formula (I) wherein each instance of R.sup.4, R.sup.5, R.sup.6, R.sup.7, R.sup.8, R.sup.10, R.sup.11, R.sup.12, R.sup.13, and R.sup.14 is independently selected from the group consisting of hydrogen, alkyl, cycloalkyl, alkoxyl, aryloxyl, ether, and heterocyclyl. Each instance of R.sup.9 of Formula (I) is independently selected from the group consisting of alkyl, cycloalkyl, aryl, heterocyclyl, and ether. Each instance of R.sup.28 and R.sup.29 of Formula (I) is independently selected from the group consisting of hydrogen, alkyl, and aryl. Each instance of R.sup.33 of Formula (I) is independently selected from the group consisting of alkyl, cycloalkyl, aryl, heterocyclyl, and a bond. Each instance of R.sup.41 of Formula (I) is independently —NH— or a bond and each instance of R.sup.40 is independently —NH— or —NH—NH—.