C08G77/00

Fluoroalkyl group-containing curable organopolysiloxane composition, cured product thereof, and transducer or the like provided with cured product
11479670 · 2022-10-25 · ·

A curable organopolysiloxane composition is provided. The composition can be easily processed into a film shape and has a high specific dielectric constant, high dielectric breakdown strength, and a low Young's modulus, allowing for a high energy density to be achieved, in addition to having excellent mechanical strength when used as a dielectric layer in a transducer. A fluoroalkyl group-containing curable organopolysiloxane composition, which can be cured by an addition reaction, comprises: an organopolysiloxane containing an alkenyl group and a fluoroalkyl group; an organohydrogen polysiloxane having SiH at both terminals of a molecular chain but not having a fluoroalkyl group; and a linear fluoroalkyl group-containing organohydrogen polysiloxane or a branched fluoroalkyl group-containing organohydrogen polysiloxane having T units.

Electronic device comprising a conformal viscoelastic or non-Newtonian coating

A composition for forming a protective coating on an electronic device that is in the form of a non-Newtonian fluid that exhibits both viscous and elastic properties, and that forms at least one coating that is hydrophobic, oleophobic, or oleophilic is disclosed. The viscous and elastic properties associated with the non-Newtonian fluid allows the composition to redistribute after being applied as a coating an electronic device. Methods for protecting an electronic device from liquid contaminants by applying the disclosed composition and electronic devices comprising the composition are also disclosed. An electronic device, such as a printed circuit board, having a film made of the composition is also disclosed.

SILICONE ELASTOMERS BY FREE RADICAL MEDIATED CURE

Curable compositions of this disclosure comprise a mixture of: a silanol, a free radical initiator, an iodonium salt; and optionally an alkoxysilane, and/or an MQ resin, and/or (meth)acrylate monomer(s). In another aspect, cured compositions of this disclosure comprise: a cured silicone, a free radical initiator or residue thereof, an iodonium salt or residue thereof; and optionally a poly(meth)acrylate and/or an MQ resin, which may comprise the cured silicone. In another aspect, cured compositions of this disclosure comprise: a continuous phase of cured silicone, a discontinuous phase of poly(meth)acrylate inclusions, and optionally an MQ resin, which may comprise the cured silicone. The poly(meth)acrylate inclusions may have an average diameter of less than 1.0 micrometer or smaller. The compositions may be pressure sensitive adhesives. The curable and cured compositions may be solvent-free.

Process for purifying acetoxysiloxanes

Processes are described for purifying acidic, preferably superacidic, in particular trifluoromethanesulfonic acid-acidified, end-equilibrated acetoxysiloxanes, wherein the acidic, preferably superacidic, in particular trifluoromethanesulfonic acid-acidified, acetic anhydride-containing and optionally acetic acid-containing equilibrated, preferably end-equilibrated acetoxysiloxane, which is optionally dissolved in an inert solvent, is contacted with a base, the precipitate is filtered off thereafter and then the filtrate obtained is optionally purified by distillation.

Degradable silyl-containing thermosetting networks

A process of: providing a polyfunctional compound selected from polyisocyanate, polyacrylate, and polyepoxy; and reacting the polyfunctional compound with a hydroxyl- or amine-terminated silyl-containing compound. The polyfunctional compound and the silyl-containing compound are at least difunctional. A thermoset made by this process.

Water-based gel-consolidation type lost circulation material system suitable for fractured lost circulation formation, preparation method and use thereof

The present discloses a water-based gel-consolidation type lost circulation material system suitable for fractured lost circulation formation, preparation method and use thereof.

SILICONE PRESSURE SENSITIVE ADHESIVE AND METHOD OF MAKING THE SAME

A process for producing a silicone pressure sensitive adhesive is shown and described herein. The process comprises reacting a MQ silicone resin with a polydiorganosiloxane in the absence of a solvent. The MQ silicone resin is a solid, solventless MQ resin. The reaction may be conducted in the presence of a catalyst, a chain extension reagent, or a combination thereof, and the resulting pressure sensitive adhesive can be dissolved in a solvent and the solids content adjusted. The present method provides a manner to provide a cleaner adhesive material that is free of unwanted materials such as aromatic solvents and also substantially free of cyclic siloxane impurities.

Composition for acoustic wave probe, silicone resin for acoustic wave probe formed of the same, acoustic wave probe, ultrasound probe, acoustic wave measurement apparatus, ultrasound diagnostic apparatus, photoacoustic wave measurement apparatus, and ultrasound endoscope

Provided are a composition for an acoustic wave probe which includes polysiloxane that has a vinyl group and a phenyl group, polysiloxane that has two or more Si—H groups in a molecular chain, a titanium oxide particle, and a silica particle, in which at least one of the titanium oxide particle (C) or the silica particle (D) is a particle subjected to surface treatment; a silicone resin for an acoustic wave probe; an acoustic wave probe; an acoustic wave measurement apparatus; an ultrasound diagnostic apparatus; an ultrasound probe; a photoacoustic wave measurement apparatus; and an ultrasound endoscope.

COMPOSITION FOR FORMING PHOTOCURABLE SILICON-CONTAINING COATING FILM

A method for producing a coated substrate includes applying a photocurable silicon-containing coating film-forming composition to an uneven substrate; and exposing the photocurable silicon-containing coating film-forming composition to light, wherein the photocurable silicon-containing coating film-forming composition comprises a hydrolyzable silane, a hydrolysate thereof, or a hydrolytic condensate thereof, wherein the hydrolyzable silane is a hydrolyzable silane of the following Formula (1):


R.sup.1.sub.aR.sup.2.sub.bSi(R.sup.3).sub.4−(a+b)  Formula (1)

wherein R.sup.1 is a functional group relating to photocrosslinking; R.sup.2 is an alkyl group and is bonded to a silicon atom via an Si—C bond; R.sup.3 is an alkoxy group, an acyloxy group, or a halogen group; a is an integer of 1; b is an integer of 0 to 2; and a+b is an integer of 1 to 3.

LATE FIRST ROW TRANSITION METAL ARYL DIIMINE CATALYSTS FOR HYDROFUNCTIONALIZATION AND DEHYDROCOUPLING
20230116103 · 2023-04-13 ·

Aryl diimine first row metal compounds are described, as well as their synthesis and use as catalysts for the hydrofunctionalization of unsaturated organic compounds and main group element—main group element bond formation by dehydrogenative coupling.