An asymmetric benzotrichalcogenophene compound and a polymer are provided. The asymmetric benzotrichalcogenophene compound is a heterocyclic compound having furan, thiophene, selenophene and/or tellurophene subunits. The polymer has an asymmetric benzotrichalcogenophene subunit and can be formed by polymerizing the asymmetric benzotrichalcogenophene compound and an electron-accepting compound. The polymer may be used as a semiconductor active layer material in an organic field effect transistor or a heterogeneous interface material of an organic solar cell.

The present invention addresses a first problem of providing a polymer that has electrochromic characteristics, and that can form a sheet which seems more transparent when applied to an electrochromic element and is decolored. The present invention for solving the problem is a polymer obtained by forming a complex between, and binding together, compound A represented by formula 1: BP1-L1-BP2 and at least one specific metal ion selected from the group consisting of first metal ions having a coordination number of 4, second metal ions having a coordination number of 6, and third metal ions having a coordination number of 4 and 6. In the formula, L1 represents a single bond or a divalent group, and BP1 and BP2 may be identical or different from each other and each independently represent a bipyridine derivative.

Polymers, monomers, chromophoric polymer dots and related methods are provided. Highly fluorescent chromophoric polymer dots with narrow-band emissions are provided. Methods for synthesizing the chromophoric polymers, preparation methods for forming the chromophoric polymer dots, and biological applications using the unique properties of narrow-band emissions are also provided.

Polymers, monomers, chromophoric polymer dots and related methods are provided. Highly fluorescent chromophoric polymer dots with narrow-band emissions are provided. Methods for synthesizing the chromophoric polymers, preparation methods for forming the chromophoric polymer dots, and biological applications using the unique properties of narrow-band emissions are also provided.

A method of preparing a crystalline copper-based coordination polymer comprises preparing a mixture of copper ions and a first quaternized carboxylate pyridyl ligand; adding a second polypyridyl ligand; and forming crystals of a copper-based coordination polymer therefrom. The crystalline copper-based coordination polymer is suitable for providing a sensing platform for detecting the presence of one or more target nucleic acid sequences such as viral RNA, in particular Dengue virus and/or Zika virus RNA with high selectivity and high specificity. A method of detecting at least a first target nucleic acid sequence, in particular from a viral RNA, in particular it is Flavivirus RNA, in a sample is also provided. Further provided is a kit including the crystalline copper-based coordination polymer and an oligonucleotide probe.

A method of preparing a crystalline copper-based coordination polymer comprises preparing a mixture of copper ions and a first quaternized carboxylate pyridyl ligand; adding a second polypyridyl ligand; and forming crystals of a copper-based coordination polymer therefrom. The crystalline copper-based coordination polymer is suitable for providing a sensing platform for detecting the presence of one or more target nucleic acid sequences such as viral RNA, in particular Dengue virus and/or Zika virus RNA with high selectivity and high specificity. A method of detecting at least a first target nucleic acid sequence, in particular from a viral RNA, in particular it is Flavivirus RNA, in a sample is also provided. Further provided is a kit including the crystalline copper-based coordination polymer and an oligonucleotide probe.

The present invention relates in a first aspect to a method of preparing a crystalline lanthanum-carboxylate coordination polymer and the crystalline lanthanum-carboxylate coordination polymer obtained or obtainable by the method. In another aspect of the present invention, also provides a method of detecting a target nucleic acid sequence in a sample.

The present invention relates in a first aspect to a method of preparing a crystalline lanthanum-carboxylate coordination polymer and the crystalline lanthanum-carboxylate coordination polymer obtained or obtainable by the method. In another aspect of the present invention, also provides a method of detecting a target nucleic acid sequence in a sample.

Disclosed is a polymetalloxane including a constituent unit represented by the following general formula (1), which stably exists in a transparent and uniform state in a solution and can form a homogeneous cured film:

##STR00001##

wherein R.sup.1 is an organic group and at least one of R.sup.1 is an (R.sup.3.sub.3SiO) group, R.sup.3 is optionally selected from specific groups, R.sup.2 is optionally selected from specific groups, when plural R.sup.1, R.sup.2, and R.sup.3 exist, they may be the same or different, M represents a specific metal atom, m is an integer indicating a valence of a metal atom M, and a is an integer of 1 to (m2).

The present invention relates to an organic/heterometallic hybrid polymer including a plurality of organometal complexes and a plurality of transition metals, the organic/heterometallic hybrid polymer, wherein the plurality of organometal complexes are linked in a linear manner by sandwiching each of the plurality of transition metals therebetween, the organometal complexes include two ligands each having a terpyridyl group and one connector having Ru(dppe).sub.2 and two ethynylene groups, and the two ligands are linked by the connector, so that a nitrogen atom at position 1 of the terpyridyl group is directed toward the terminal side of the molecule of the organometal complex, and the terpyridyl groups of at least two different organometal complexes of the plurality of organometal complexes are bound to one of the transition metals through a coordinate bond, thereby linking the plurality of organometal complexes while sandwiching the plurality of transition metals alternately therebetween.