C08G83/00

Ion pump with hyperbranched polymers

A device for transport of ions and/or charged molecules between a source and a target electrolyte, comprising: a first electrode provided at or in said source electrolyte, and a second electrode provided at or in said target electrolyte; and wherein said first and second electrodes provides an electrical control of an ion flow, and further comprising means for limiting an electronic current between said source and said target electrodes, such that at least after a voltage is applied a potential difference between said source and target electrodes is maintained, which effects ion transport from said source to said target electrode; wherein the device further comprises an ion- and/or permselective polyelectrolyte for transport ions and/or charged molecules via electrophoresis and functions as an ion-selective membrane; and wherein said polyelectrolyte comprises a cross-linked hyperbranched polymer.

Metal ion-directed carboxylic acid functionalized polyoxometalate hybrid compounds and their preparation method and applications for catalyzing the degradation of chemical warfare agent simulants
11358133 · 2022-06-14 · ·

Metal ion-directed carboxylic acid functionalized polyoxometalate hybrid compounds, and their preparation method and applications in catalyzing the degradation of chemical warfare agent simulants. In the synthesis, Na.sub.2MoO.sub.4, p-hydroxybenzonic acid (PHBA), alanine (Ala), KCl, transition metal cations and As.sub.2O.sub.3 as raw materials and water are used as solvent. At room temperature, 2-chloroethyl ethyl sulfide (CEES) and the prepared polyoxometalate hybrid compounds were mixed together in anhydrous ethanol and stirred, and H.sub.2O.sub.2 was subsequently added into the reaction system. The catalytic reaction for the degradation of CEES was finished within 5 min under stirring. In the catalytic hydrolysis of diethyl cyanophosphonate (DECP), the catalyst, DECP, DMF and H.sub.2O were put together and mixed fully. The prepared polyoxometalate hybrid compounds have the advantages of high conversion, high selectivity and easy recyclability in catalyzing the degradation of two types of chemical warfare agent simulant.

POLYNUCLEOTIDE CAPTURE MATERIALS, AND SYSTEMS USING SAME
20220170008 · 2022-06-02 ·

Methods for processing polynucleotide-containing biological samples, and materials for capturing polynucleotide molecules such as RNA and/or DNA from such samples. The RNA and/or DNA is captured by polyamindoamine (PAMAM (Generation 0)) bound to a surface, such as the surface of magnetic particles. The methods and materials have high efficiency of binding RNA and of DNA, and of release, and thereby permit quantitative determinations.

BLOCK COPOLYMERS AND USES THEREOF

An encoding/decoding apparatus and method using a low-density parity-check code (LDPC code) is disclosed. Basic column group information, serving as a set of information regarding positions of rows with weight 1, is extracted from a reference column in each column group of a predetermined parity-check matrix. Column group information transforms the positions of rows with weight 1 into positions whose lengths are within a required parity length. A parity-check matrix is generated according to the generated column group information. Data is enclosed or decoded based on the generated parity-check matrix.

Resin composition, and resin film, metal foil with resin, metal clad laminate, wiring board, and circuit mount component using same

One aspect of the present invention relates to a resin composition containing a polyrotaxane (A), an epoxy resin (B), and a curing agent (C), in which the curing agent (C) contains an acid anhydride (C-1) in an amount of 0.1 parts by mass or more and less than 10 parts by mass based on a total of 100 parts by mass of the polyrotaxane (A), the epoxy resin (B), and the curing agent (C).

Branched multi-functional macromonomers and related polymers and uses thereof

Disclosed are methods, compositions, reagents, systems, and kits to prepare and utilize branched multi-functional macromonomers, which contain a ring-opening metathesis polymerizable norbornene group, one or more reactive sites capable of undergoing click chemistry, and a terminal acyl group capable of undergoing a coupling reaction; branched multi-cargo macromonomers; and the corresponding polymers are disclosed herein. Various embodiments show that the macromonomers and polymers disclosed herein display unprecedented control of cargo loading of agents. These materials have the potential to be utilized for the treatment of diseases and conditions such as cancer and hypertension.

Branched multi-functional macromonomers and related polymers and uses thereof

Disclosed are methods, compositions, reagents, systems, and kits to prepare and utilize branched multi-functional macromonomers, which contain a ring-opening metathesis polymerizable norbornene group, one or more reactive sites capable of undergoing click chemistry, and a terminal acyl group capable of undergoing a coupling reaction; branched multi-cargo macromonomers; and the corresponding polymers are disclosed herein. Various embodiments show that the macromonomers and polymers disclosed herein display unprecedented control of cargo loading of agents. These materials have the potential to be utilized for the treatment of diseases and conditions such as cancer and hypertension.

Solvent-free solid electrolyte

A solvent-free polymer electrolyte having a polymer matrix which is conductive for lithium ions and a lithium salt, wherein the polymer matrix has at least one pseudo-polyrotaxane which includes at least one linear polymer and at least one ring-shaped molecule, and wherein the lithium salt is arranged in the polymer matrix and is at least partially chemically bonded to the polymer matrix, wherein the polymer matrix includes at least one pseudo-polyrotaxane with at least one completely or partially chemically modified cyclodextrin or at least one completely or partially chemically modified crown ether, in which the present hydroxyl groups of the cyclodextrin, or the scaffold of the crown ether, are/is partly or completely modified by functional groups, wherein the functional groups comprise alkyl, aryl, alkenyl, alkynyl groups (C.sub.n, with n≤5), or other short-chain polymer groups having up to 20 repeating units.

End-group functionalized comb structure polycarboxylic acid and method for preparing the same

A method for preparing comb structure temperature/pH-responsive polycarboxylic acid by end-group functionalization adopts temperature/pH-responsive monomer, unsaturated halogenated hydrocarbon, small monomer of carboxylic acid and other raw materials to prepare polycarboxylic acid material via self-polymerization, substitution and copolymerization. Temperature/pH-responsive monomers are first self-polymerized to obtain temperature/pH-responsive polymer chain with end-group functionalization, and then substitution with unsaturated halogenated hydrocarbons is conducted to obtain temperature/pH-responsive macromonomers with end-group functionalization, finally the obtained product is copolymerized with small carboxylic acid monomers to prepare comb structure polymer with polycarboxylic acid main chain and temperature/pH-responsive side chain.

Bionic fiber adsorptive material with multi-adsorption sites and preparation method and use thereof

The present invention provides a bionic fiber adsorptive material with multi-adsorption sites and a preparation method and use thereof, and the material is rich in multi-adsorption sites (N, O and S). The material is obtained by blending three polyethyleneimine polymers modified by multifunctional groups respectively with a carboxylated nanocellulose and graphene oxide, then adopting a coaxial spinning method based on a principle of imitating spider spinning, and then adopting a post-crosslinking technology. The material has a multilayer structure with the nanocellulose as a skeleton, the graphene oxide as an outer layer, and the three polyethyleneimine polymers modified by the multifunctional groups respectively as an inner layer, and a connection among the layers is a chemical bond connection. Densities of N, O and S adsorption sites of the material according to the present invention are all higher than 5 mmol/g.