The invention relates to a method for the preparation of a hyperbranched polyester mixture obtainable by reacting a hydroxyl group containing carboxylic acid (B) with at least one carboxylic acid group and at least two hydroxyl groups with a diol (C) having a molecular weight of more than 100 g/mol, optionally in the presence of at least one further reactant, wherein the at least one further reactant is a polyol (A) having at least three hydroxyl groups under a reaction condition allowing ester and ether formation; and reacting the mixture resulting from step (a) with a hydrophobic carboxylic acid (D) resulting in the hyperbranched polyester mixture. The invention further relates to said hyperbranched polyester mixture and the use as wax inhibitor, as pour point depressant, as lubricant or in lubricating oils.

Disclosed herein is a porous polymeric material having a repeating unit according to Formula (I) or (IV), wherein each of A and E has a π conjugated system and each of X and G contain a flexible tetraphenylethylene (TPE) group. Also disclosed herein are fluorescent chemical sensors or biosensors or environmental monitoring assays or nanosheets or composite materials that include the polymer, and a method of detecting a volatile organic chemical or a metal ion in solution phase. ##STR00001##

A polymer/activated carbon composite made up of a branched polyethylenimine and magnetic cores involving Fe.sub.3O.sub.4 disposed activated carbon. The magnetic cores have activated carbonyl groups on the surface. A process for removing organic dyes, such as methyl red, as well as heavy metal ions from a polluted aqueous solution or an industrial wastewater utilizing the composite is introduced. A method of synthesizing the polymer/activated carbon composites is also specified.

The present invention relates to a method of producing a supramolecular hydrogel which is formed by the mixing and gelation of at least two dispersions of different types of synthetic hydrogelators, said hydrogelators being formed of synthetic building blocks comprising one or more hydrogen bonding units, wherein each bonding unit comprises a ureido-pyrimidinone subunit and each bonding unit is conjugated with a hydrophilic polymer unit, the method comprising the steps of: a) providing a first dispersion of one type of hydrogelators, b) mixing the first dispersion with a second dispersion of another type of hydrogelators, and c) allowing the dispersions to form the hydrogel, wherein the types of hydrogelators are selected from multifunctional hydrogelators and monofunctional hydrogelators, wherein the steps of the method are conducted under biocompatible conditions, and wherein the hydrophilic polymer unit of the hydrogelators comprised in the first dispersion has a minimal hydrophilicity such that the first dispersion does not form a hydrogel under the biocompatible conditions applied.

A polymer/activated carbon composite made up of a branched polyethylenimine and magnetic cores involving Fe.sub.3O.sub.4 disposed activated carbon. The magnetic cores have activated carbonyl groups on the surface. A process for removing organic dyes, such as methyl red, as well as heavy metal ions from a polluted aqueous solution or an industrial wastewater utilizing the composite is introduced. A method of synthesizing the polymer/activated carbon composites is also specified.

A method of preparing tunable inorganic patterned nanofeatures by infiltration of a block copolymer scaffold having a plurality of self-assembled periodic polymer microdomains. The method may be used sequential infiltration synthesis (SIS), related to atomic layer deposition (ALD). The method includes selecting a metal precursor that is configured to selectively react with the copolymer unit defining the microdomain but is substantially non-reactive with another polymer unit of the copolymer. A tunable inorganic features is selectively formed on the microdomain to form a hybrid organic/inorganic composite material of the metal precursor and a co-reactant. The organic component may be optionally removed to obtain an inorganic feature s with patterned nanostructures defined by the configuration of the microdomain.

Certain embodiments comprise administering a residence structure to a subject (e.g., a patient) such that the residence structure is retained at a location internal to the subject for a particular amount of time (e.g., at least about 24 hours) before being released. In certain embodiments, the structure has a modular design, combining a material configured for controlled release of therapeutic, diagnostic, and/or enhancement agents with a structural material necessary for gastric residence but configured for controlled and/or tunable degradation/dissolution to determine the time at which retention shape integrity is lost and the structure passes out of the gastric cavity. For example, in certain embodiments, the residence structure comprises a first elastic component, a second component configured to release an active substance, and, optionally, a linker. In some such embodiments, the linker may be configured to degrade.

The invention relates to a method for attenuating vibrations and/or shocks, said method comprising providing a damper assembly which comprises a moving part and a supramolecular polymer in contact with said moving part, and exposing said moving part to said vibrations and/or shocks, wherein said supramolecular polymer is obtained by reacting: at least one first polymer [polymer (P1)] comprising a polymer chain [chain (R)] consisting of a plurality of non-ionisable recurring units [units (U)], said polymer (P1) having two chain ends (E1, E1′), each end comprising at least one ionisable acid group, and at least one second polymer [polymer (P2)] comprising a polymer chain [chain (R)] consisting of a plurality of recurring units [units (U)], said chain (R) being equal to or different from that of polymer (P1), and said polymer (P2) having two chain ends (E2, E2′), each end comprising at least one ionisable amino group.

Hyperbranched polydiorganosiloxane polyoxamide polymers are formed from reaction mixtures containing AX.sub.g and BZ.sub.m compounds where either A or B is a siloxane-based group, and each X is either an oxalylamino-functional group or an amino-functional group, and each Z is either an amino-functional group or an oxylamino-functional group, such that upon reaction X and Z form an oxamide bond.

In some aspects, the present disclosure pertains to multi-arm polymers that comprise a core, a plurality of polymer segments having a first end that is covalently attached to the core and a second end comprising a moiety that comprises a reactive group, wherein the polymer segments comprise one or more free-radical-polymerizable monomers. In some aspects, systems are provided that comprise a first composition comprising such a multi-arm polymer and a second composition comprising a multifunctional compound that comprises functional groups that are reactive with the reactive groups of the multi-arm polymer. In some aspects, systems are provided that comprise crosslinked reaction products of such a multi-arm polymer and such a multifunctional compound.