A method of preparing a poly(ester-carbonate) includes contacting an aqueous solution including a dicarboxylic acid with a first solution including phosgene and a first organic solvent in a tubular reactor to provide a first reaction mixture. A dihydroxy aromatic compound, the corresponding dialkali metal salt of the dihydroxy aromatic compound, or a combination comprising at least one of the foregoing, water, and a second organic solvent are combined to provide a second reaction mixture. The method further includes introducing the first reaction mixture, the second reaction mixture, and a second solution comprising phosgene to a tank reactor, wherein the tank reactor has a first pH of 7 to 10. The pH is optionally raised to 9 to 11 to provide a third reaction mixture including the poly(ester-carbonate). Poly(ester-carbonate)s prepared according to the method described herein are also disclosed.

The present invention relates to an aromatic polycarbonate obtained via the melt transesterification of a diaryl carbonate, a bisphenol and an endcapping agent selected from paracumyl phenol, dicumyl phenol, p-tert-butyl phenol and mixtures of at least two of said endcapping agents, said polycarbonate having a melt volume rate of at least 20 cm.sup.3/10 min (ISO 1133, 300 C., 1.2 kg), a terminal hydroxyl group content of at most 800 ppm by weight, a Fries branching content of at most 1300 ppm by weight and a content of bulky end groups of at least 20 mol % defined as the sum of the mol % of end-groups based on said bisphenol and the mol % of end-groups based on said endcapping agent.

The invention provides polyurethane and polyisocyanurate foams and methods for the preparation thereof. More particularly, the invention relates to closed-celled, polyurethane and polyisocyanurate foams and methods for their preparation. The foams are characterized by a fine uniform cell structure and little or no foam collapse. The foams are produced with a polyol premix composition which comprises a combination of a hydrohaloolefin blowing agent, a polyol, a silicone surfactant, and a non-amine catalyst used alone or in combination with an amine catalyst.

A capped bisphenol polyether oligomer including a reactive end group, wherein the capped bisphenol polyether oligomer further includes a repeating unit derived from: a bisphenol monomer, a benzylic dihalide, a tertiary cycloalkyl dihalide, or a combination thereof; and optionally, the capped bisphenol polyether oligomer further includes a branching agent.

A method for making oligomers is described. The method includes reacting a polyol with a precursor having mixed functionality. The precursor includes a curable functional group and an isocyanate group capable of reacting with an alcohol group of the polyol. The precursor reacts with the alcohol group of the polyol to form a urethane linkage and to add a covalently bonded curable functional group to the polyol. The oligomers can be included in coating compositions for optical fiber and lead to coatings having improved tear strength.

The invention relates to poly(oligo(ethylene glycol) methacrylate) microgels, to the process for preparing same and the uses thereof in various fields of application such as optics, electronics, pharmacy and cosmetics.

These microgels have the advantage of being monodisperse, pH-responsive and temperature-responsive. They can carry magnetic nanoparticles or biologically active molecules. These microgels may also form transparent films, which have novel optical and electromechanical properties.

A carbonate-containing oligomer, a manufacturing method for a carbonate-containing oligomer and a crosslinked product are provided. The carbonate-containing oligomer includes a structure represented by formula (I), and formula (I) is defined as in the specification. The crosslinked product is obtained by mixing the carbonate-containing oligomer with a modified polyphenylene ether resin, and adding a peroxide to perform a curing reaction.

The invention relates to poly(oligo(ethylene glycol) methacrylate) microgels, to the process for preparing same and the uses thereof in various fields of application such as optics, electronics, pharmacy and cosmetics. These microgels have the advantage of being monodisperse, pH-responsive and temperature-responsive. They can carry magnetic nanoparticles or biologically active molecules. These microgels may also form transparent films, which have novel optical and electromechanical properties.

Provided is a polyorganosiloxane, wherein a value obtained by integrating dw/d log(M) from 2.5log(M)3.1 is 0 to 10% of a value obtained by integrating dw/d log(M) over the entire range of log (M) in a differential molecular weight distribution curve, wherein the differential molecular weight distribution curve is determined by gel permeation chromatography using the polystyrene calibration curve, has an x-axis showing a logarithmic value log(M) of a molecular weight M and has a y-axis showing dw/d log(M) obtained by differentiating a concentration fraction w with respect to the logarithmic value log(M) of the molecular weight

Provided is a polyorganosiloxane, wherein a value obtained by integrating dw/d log(M) from 2.5log(M)3.1 is 0 to 10% of a value obtained by integrating dw/d log(M) over the entire range of log (M) in a differential molecular weight distribution curve, wherein the differential molecular weight distribution curve is determined by gel permeation chromatography using the polystyrene calibration curve, has an x-axis showing a logarithmic value log(M) of a molecular weight M and has a y-axis showing dw/d log(M) obtained by differentiating a concentration fraction w with respect to the logarithmic value log(M) of the molecular weight.