An one-part polyurethane composition, including: A) 15-75 wt.-% of at least one isocyanate-functional polyurethane polymer; B) 5-30 wt.-% of at least one organic thixotropy agent; C) 2-25 wt.-% of at least one plasticizer having viscosity of less than 500 mPa s, measured at 0° C. with cone-plate viscosimeter, shear rate 10 s.sup.−1, cone angle 1°, spindle 25-2, and cone tip-plate distance of 0.05 mm; D) 0-15 wt.-% of at least one solvent; E) 0-50 wt.-% of at least one filler; F) at least one catalyst for curing of polyurethane compositions; wherein isocyanate-functional polyurethane polymer has NCO content in range of 0.8%-2.5% by weight and is obtained from reaction of methylene diphenyl diisocyanate (MDI) and polyol in NCO/OH ratio of at least 3/1 and subsequent removal of non-reacted MDI; and polyol has viscosity, measured according to ASTM D4878-15 at 25° C., of less than 2000 mPa s; and isocyanate-functional polyurethane polymer has remaining content of MDI of at most 0.5% by weight.

A moisture curable composition capable of cure to an elastomeric body, the composition comprising: (i) an organopolysiloxane polymer having at least two silicon-bonded hydroxyl or hydrolysable groups per molecule and a viscosity of from 1,000 to 75,000 maPa.Math.s at 25° C.; (ii) a siloxane and/or silane cross-linker; (iii) an organosilicate resin comprising SiO.sub.4/2 (Q) siloxane units and R.sup.2.sub.3SiO.sub.1/2 (M) siloxane units wherein each R.sup.2 is selected from hydrocarbon groups, —OH and/or alkoxy containing groups and which M groups are reactive with components (i) and/or (ii); and (iv)_a condensation cure catalyst. The organosilicate resin (iii) is generally used to reinforce the composition.

A moisture-curable composition, including at least one organic polymer P containing reactive silane groups, between 1.0 wt.-% and 25.0 wt.-%, preferably between 2.0 wt.-% and 20 wt.-%, in particular between 2.5 wt.-% and 10 wt.-%, based on the total composition, of dimethyl or diethyl esters of aliphatic C3 to C5 dicarboxylic acids, and at least one curing catalyst for alkoxysilane groups. The moisture-curable composition is particularly suitable as elastic adhesive, coating, filler, or sealant and shows superior overpaintability, in particular with automotive topcoats or similar paints.

A composition includes a reaction product of a mixture of elemental sulfur and at least a first ethylenically unsaturated compound comprising a hydroxyl or carboxyl group.

The present invention provides a liquid polysiloxane comprising a siloxane-thiourea segment and a crosslinkable functional group(s) selected from one or more ethylenically unsaturated groups, silyl hydride groups, alkylenethiol groups and combinations thereof.

The present disclosure relates to a polyol resin blend for use in a polyurethane formulation. The polyol resin blend generally includes (a) an amine having a pKa value between about 6 and about 8.5 and a protonated amine obtained by contacting a methylamino-containing tertiary amine or primary etheramine having a pKa value greater than about 9 and an acid compound, (b) a polyol, and (c) a halogenated olefin. The present disclosure also provides polyurethane formulations containing the polyol resin blend and methods of making polyurethane foam from such polyurethane formulations.

The present invention is drawn to an aqueous polyurethane dispersion comprising: —anionic polyurethane particles comprising both free pending carboxylate groups of formula —COO.sup.−M.sup.+ where M.sup.+ is a cation resulting from neutralization of carboxylic acid groups with a base, and pending carboxylate ester groups resulting from esterification of free carboxylic acid groups with an epoxysilane, —crosslinking particles made of water-insoluble transition metal compounds. It is also drawn to a method of coating a substrate comprising applying such an aqueous polyurethane dispersion onto a substrate and letting it dry, preferably without applying any heat or radiation.

An aqueous composition including: a) at least one epoxy silane containing at least one epoxy group and at least one hydrolysable group bound to Si, b) at least one non-ionic wetting agent and either c1) between 0.2 and 2 wt. % of at least one mercapto silane containing at least one mercapto group and at least one hydrolysable group bound to Si, and as many water-soluble acids as required for the pH of resulting composition to be between 1 and 6, on the condition that epoxy silane content amounts to between 0.2 and 1 wt. %, or c2) between 0.1 and 1 wt. % of a water-soluble organotitanate, in relation to entire weight of aqueous composition, and as many water-soluble bases as required for the pH of resulting composition to be between 8 and 14, on the condition that the epoxy silane content amounts to between 0.2 and 0.5 wt. %.

The disclosure relates to epoxy-based compositions comprising a decarboxylated rosin acid (DCR) component, suitable as an efficient plasticizer. It further improves hardness, elasticity, UV exposure viability properties of the paint and coating compositions. The DCR increases the bio-based renewable material content of a coating formulation and provide solutions for phthalate-free products. The DCR has a density of 0.9 to 1.0 g/cm.sup.3, a flash point of 135 to 175° C., an acid value of < 50 mg KOH/g, measured according to ASTM D465, and a viscosity of 15 to 60 cSt at 40° C., measured according to ASTM D-445.

A moisture-curable composition is shown and described herein. The moisture-curable composition comprises a moisture-curable resin and a moisture scavenger selected from a cyanoalkylalkoxysilane. The inclusion of the cyanoalkylalkoxysilane in the moisture-curable composition has been found to effectively scavenge moisture and control the rate of curing and viscosity increase in the composition.