Patent classifications
C08G2250/00
Polymer Compositions with Improved Anti-Dent and Particulate Release Performance
Compositions include from about 50 wt % to about 85 wt % of a liquid crystal polymer resin, from about 0.1 wt % to about 15 wt % of a polyetherimide polymer, from about 0.05 wt % to about 8 wt % of a compatibilizer, and from about 2 wt % to about 25 wt % of a mineral filler. A 50 mm60 mm sample having a thickness of 0.6 mm molded from the composition exhibits an anti-dent performance characterized by a dent depth from 30-40 micrometers as measured using a three dimensional surface profiler; the sample is tested using a drop tester with a 1.6 mm diameter steel ball having a weight of 50 grams dropped from a height of 50 mm. Articles including the composition, including components of a mobile compact camera module, are also described.
Liquid crystal polymer, composition, liquid crystal polymer film, laminated material and method of forming liquid crystal polymer film
A liquid crystal polymer, composition, liquid crystal polymer film, laminated material and method of forming liquid crystal polymer film are provided. The liquid crystal polymer includes a first repeating unit, a second repeating unit, a third repeating unit, a fourth repeating unit, and a fifth repeating unit. The first repeating unit has a structure of Formula (I), the second repeating unit has a structure of Formula (II), the third repeating unit has a structure of Formula (III), the fourth repeating unit has a structure of Formula (IV), and the fifth repeating unit has a structure of Formula (V), a structure of Formula (VI), or a structure of Formula (VII) ##STR00001## wherein A.sup.1, A.sup.2, A.sup.3, A.sup.4, X.sup.1, Z.sup.1, R.sup.1, R.sup.2, R.sup.3 and Q are as defined in the specification.
Method of forming semicrystalline polyetherimide, and polyetherimide-containing composition
In a method of forming a semicrystalline polyetherimide, a solvent mixture is combined with an amorphous polyetherimide in a weight ratio of 1:1 to 50:1, respectively, to form a first dispersion. The solvent mixture includes dichloromethane and a C.sub.1-C.sub.6 alkanol in a weight ratio of 0.5:1 to 15:1, respectively. The first dispersion is agitated to form a second dispersion containing a semicrystalline polyetherimide, and the semicrystalline polyetherimide is isolated from the second dispersion. The isolated semicrystalline polyetherimide exhibits a melting point in a range of 230 to 300 C. Also described is a composition that includes a polyetherimide, dichloromethane, and a C.sub.1-C.sub.6 alkanol in specific ratios.
Articles made from hydrophilic thermoplastic polyurethane compositions
An article is prepared by injection molding, wherein the article is formed from a hydrophilic thermoplastic polyurethane composition, wherein the thermoplastic polyurethane composition comprises the reaction product of a hydroxyl terminated polyol intermediate component, an aliphatic isocyanate component, and, optionally, a chain extender component. For injection molding, the hydrophilic thermoplastic polyurethane has a crystallization temperature measured by dynamic scanning calorimetry of at least 75 C.
LIQUID CRYSTALLINE POLYESTER, MOLDED ARTICLE, AND ELECTRIC/ELECTRONIC COMPONENT
Provided is a liquid crystalline polyester that is excellent in dimensional stability while having a low dielectric loss tangent. The liquid crystalline polyester includes 90% by mol or more of a constitutional unit derived from an aromatic hydoxycarboxylic acid with respect to the amount of all constitutional units. In the liquid crystalline polyester, a dielectric loss tangent at a measurement frequency of 10 GHz is 1.010.sup.3 or less, a difference (anisotropy) between mold shrinkage rates in the machine direction (MD) of the injection-molded piece of the liquid crystalline polyester and a transverse direction (TD) with respect to the machine direction is 1.00 or less, and a melt viscosity measured under conditions of a shear rate of 1000/s and the melting point of the liquid crystalline polyester to the melting point+20 C. is 25 Pa.Math.s or more.
Polymer composition for laser direct structuring
A laser activatable polymer composition is provided. The composition contains at least one laser activatable additive and at least one high naphthenic thermotropic liquid crystalline polymer that contains repeating units derived from naphthenic hydroxycarboxylic and/or dicarboxylic acids in an amount of about 10 mol. % or more. The polymer composition exhibits a dielectric constant of about 5 or less as determined at a frequency of 2 GHz.
Polymer compositions with improved anti-dent and particulate release performance
Compositions include from about 50 wt % to about 85 wt % of a liquid crystal polymer resin, from about 0.1 wt % to about 15 wt % of a polyetherimide polymer, from about 0.05 wt % to about 8 wt % of a compatibilizer, and from about 2 wt % to about 25 wt % of a mineral filler. A 50 mm60 mm sample having a thickness of 0.6 mm molded from the composition exhibits an anti-dent performance characterized by a dent depth from 30-40 micrometers as measured using a three dimensional surface profiler; the sample is tested using a drop tester with a 1.6 mm diameter steel ball having a weight of 50 grams dropped from a height of 50 mm. Articles including the composition, including components of a mobile compact camera module, are also described.
Adhesives
The present disclosure relates to an aqueous dispersion containing at least one semicrystalline polyurethane-polyurea polymer and at least one surface-deactivated polyisocyanate. The melting temperature of the semicrystalline polyurethane-polyurea polymer is at least 55 C. The disclosure also relates to a process for preparing the aqueous dispersion, the use of the aqueous dispersion for producing coated substrates or adhesive films, flat or three-dimensional substrates coated with the aqueous dispersion, a substrate coated with at least one semicrystalline polyurethane-polyurea polymer and at least one surface-deactivated polyisocyanate, an adhesive film including at least one semicrystalline polyurethane-polyurea polymer and at least one surface-deactivated polyisocyanate, and a dried adhesive film obtained from such an aqueous dispersion.
Anisotropic thermally conductive polymers with dynamic molecular weight, and methods of making the same
Some variations provide an oligomer composition comprising: polarizable first thermotropic liquid-crystal oligomer molecules (preferably urethanes or ureas) containing first triggerable reactive end groups, wherein the first triggerable reactive end groups are selected from the group consisting of hydroxyl, isocyanate, blocked isocyanate, acrylate, epoxide, amine, vinyl, ester, thiol, conjugated diene, substituted alkene, furan, maleimide, anthracene, and combinations thereof, and wherein the polarizable first thermotropic liquid-crystal oligomer molecules are characterized by a weight-average molecular weight from about 200 g/mol to about 10,000 g/mol; optionally, a plurality of polarizable second thermotropic liquid-crystal oligomer molecules containing second triggerable reactive end groups, wherein the second triggerable reactive end groups are capable of reacting with the first triggerable reactive end groups; and optionally, a reactive coupling agent capable of reacting with the first triggerable reactive end groups. Methods are described for converting the oligomer composition into an anisotropic thermally conductive polymer. Many commercial uses are disclosed.
PREPARATION METHOD OF LIQUID CRYSTAL SYNERGISTIC HIGH-CONDUCTIVITY SILICONE RUBBER COMPOSITE MATERIAL
A preparation method of liquid crystal synergistic high-conductivity silicone rubber composite is provided, including following steps: firstly, synthesizing BP6; then synthesizing FLCPU; finally, mixing VMQ and FLCPU by mechanical blending, then adding conductive carbon black and 2,5-Dimethyl-2,5-bis(hexyl) vulcanizing agent in sequence, then obtaining FLCPU modified VMQ/CCB rubber compound; and hot-pressing the rubber compound on a flat vulcanizer to obtain a finished product, and detecting the material of the finished product before and after modification to extract data.