Semicrystalline bifuran polyesters wherein the diacid and/or diol components include bifuran units such as those derived from 2,2′-bifuran-5,5′-dicarboxylic acid (BFA), dimethyl-2,2′-bifuran-5,5′-dicarboxylate (BFE), and/or bis(hydroxyethyl) bifuranoate (BHEB) Polyethylene-BFE (PEBF) having a high ΔH.sub.f and high T.sub.g determined by DSC on the second heating ramp is described. Polybutylene-BFE (PBBF), polyhexylene-BFE (PHBF), polypropylene-BFE (PPBF), etc., are also described. Method for making bifuran polyesters includes melt esterification or transesterification and polycondensation of one or more monomers comprising a diacid component and a diol component, wherein the one or more monomers include a bifuran monomer, such as BFA, BFE, BHEB or BFD. Also described is a method of forming a bifuran polyester prepolymer in the melt, pelletization, crystallization, and solid state polymerization.

A liquid crystal polyester resin composition includes, as essential components: a component (A): liquid crystal polyester; a component (B): a glass fiber; and a component (C): a fibrous inorganic filling material different from the component (B), in which a blending amount of the component (B) with respect to 100 parts by mass of the component (A) is 50 parts by mass or more and 90 parts by mass or less, a blending amount of the component (C) with respect to 100 parts by mass of the component (A) is 1 part by mass or more and 40 parts by mass or less, and a condition (1) and a condition (2) are satisfied.

A solid-state polymerized poly(tetramethylene-2,5-furandicarboxylate) polymer is produced in a process including: providing a poly (tetramethylene-2,5-furandicarboxylate) polycondensate having a number average molecular weight (Mn) of at least 10,000, as determined by Gel Permeation Chromatography (GPC) using polystyrene as standard, and having a content of carboxylic acid end groups of at most 50 meq/kg; and keeping the poly(tetramethylene-2,5-furandicarboxylate) polycondensate at a temperature in the range of 80 to 140° C. to obtain a semi-crystalline polycondensate; and subjecting the semi-crystalline polycondensate to solid-state polymerization by keeping the semi-crystalline polycondensate at a temperature of at least 140° C. and below its melting point, whilst the semi-crystalline polycondensate is either under a flow of inert gas or under vacuum to obtain the solid-state polymerized poly(tetramethylene-2,5-furandicarboxylate) polymer.

The present invention relates to a pellet of a liquid crystal polyester resin composition, including a liquid crystal polyester resin (A) and an inorganic filler (B), in which the pellet has voids with a sphere equivalent diameter of 10 μm to 1000 μm, an abundance ratio of voids having a sphere equivalent diameter of less than 400 μm in a total amount of the voids is in a range of 40% to 90%, and an average number of the voids in one pellet having a length of 1 mm to 5 mm and a maximum diameter of 1 mm to 3 mm is in a range of 4 to 9.

The invention relates to the field of polymers and relates to a process for crystallizing polyester. More particularly, this is a crystallization process comprising a step of provision of a polyester comprising at least one 1,4:3,6-dianhydrohexitol unit, a step of provision of a coalescence-preventing additive, and a step of crystallization of said semicrystalline polyester. The process according to the invention makes it possible to greatly limit, indeed even to eliminate, the phenomenon of agglomeration of the polyester granules during the crystallization.

An electrically or thermally conductive polymer composition, includes: a polyester polymer having a backbone including at least 12 consecutive carbon atoms between ester linkages; and conductive particles dispersed in the polyester polymer. A component including an electrically or thermally conductive polymer composition is also disclosed. A method for self-regulating a temperature of a component is also disclosed.

A semicrystalline polyphenylsulfone, has the structure Formula (I) wherein n and R are defined herein. The semicrystalline polyphenylsulfone, which exhibits a crystalline melting point in a range of 215 to 270° C., can be prepared from amorphous polyphenylsulfone using a solvent-induced crystallization method. An additive manufacturing method utilizing particles of the semicrystalline polyphenylsulfone is described.

Disclosed herein are ropes containing bundles of filaments, where each bundle includes at least 70% by volume of liquid crystal polymer filaments, and where at least one bundle includes liquid crystal polymer filaments of at least 10 denier per filament in size. Also disclosed herein are methods of pulling or lifting an object by applying tension to such a rope connected to the object, where the rope is arranged over a sheave or a non-rotating guide surface, and a ratio of a diameter of the sheave or an effective diameter of the non-rotating guide surface, D, to a diameter of the rope, d, is at least 20:1.

A method of making a non-solid state polyester that includes: a) reacting terephthalic acid and ethylene glycol; b) removing the water continuously; c) polymerizing the monomers and oligomers in vacuum conditions at a temperature to form molten polyester having an IV (intrinsic viscosity) of about 0.7 to 0.85 dl/g; d) extruding the molten polyester through a die; e) cutting and quenching the molten polyester, forming polyester pellets; f) drying the polyester pellets and transferring the polyester pellets to a storage vessel; g) transferring the polyester pellets to the upper end of a conditioning vessel while a countercurrent flow of air is circulated through the polyester pellets; and h) transferring the polyester pellets to the top of a crystallizer vessel to form a bed of polyester pellets flowing by gravity towards the bottom of the vessel while a countercurrent flow of nitrogen is circulated through the bed, and heating the polyester pellets, wherein increase of the IV of the polyester pellets is less than about 0.01 to 0.015 dl/g and the polyester pellets have a crystallinity greater than about 52%.

Some variations provide an oligomer composition comprising: polarizable first thermotropic liquid-crystal oligomer molecules (preferably urethanes or ureas) containing first triggerable reactive end groups, wherein the first triggerable reactive end groups are selected from the group consisting of hydroxyl, isocyanate, blocked isocyanate, acrylate, epoxide, amine, vinyl, ester, thiol, conjugated diene, substituted alkene, furan, maleimide, anthracene, and combinations thereof, and wherein the polarizable first thermotropic liquid-crystal oligomer molecules are characterized by a weight-average molecular weight from about 200 g/mol to about 10,000 g/mol; optionally, a plurality of polarizable second thermotropic liquid-crystal oligomer molecules containing second triggerable reactive end groups, wherein the second triggerable reactive end groups are capable of reacting with the first triggerable reactive end groups; and optionally, a reactive coupling agent capable of reacting with the first triggerable reactive end groups. Methods are described for converting the oligomer composition into an anisotropic thermally conductive polymer. Many commercial uses are disclosed.