The present invention relates to a polyurethane, in particular a thermoplastic polyurethane, obtainable or obtained by reacting at least the components (i) to (ii): (i) a polyisocyanate composition; (ii) a polyol composition, comprising (ii.1) at least one polyester diol or polyether diol having a number-average molecular weight in the range from 500 to 3000 g/mol, (ii.2) at least one polysiloxane having two terminal isocyanate-reactive functionalities selected from the group consisting of thio group, hydroxyl group and amino group. The invention additionally relates to a process for preparing this polyurethane, to the use thereof, to a molded body comprising the polyurethane. Furthermore, the invention relates to foam beads based on polyurethane, obtained or obtainable from the polyurethane, to a process for producing foam beads and also to bead foams and to the use thereof.

A thermoplastic polyurethane (TPU) foam product with high flatness, and a preparation method and a use thereof are provided. The TPU foam product is prepared by processing aliphatic thermoplastic polyurethane (ATPU) beads with a melting range of 20° C. to 50° C. and a melting point of 90° C. to 160° C. by a physical gas foaming process to obtain foamed ATPU beads and heating the foamed ATPU beads with a heat source to make the foamed ATPU beads fused. The TPU foam product with high flatness has a density of 0.08 g/cm.sup.3 to 0.8 g/cm.sup.3 and a flatness value of less than 2 mm, and the flatness value is determined by a fixed-length ruler. The TPU foam product not only has high flatness such that diversified designs are allowed for a surface of the product, but also has high resilience.

Curable compositions include a urethane (meth)acrylate oligomer having a number—average molecular weight of at least 6000 g/mol; at least one mono(meth)acrylate monomer; a multifunctional crosslinking monomer chosen from acrylate monomers, methacrylate monomers, or combinations thereof; and an ethylene-vinyl acetate grafted terpolymer. The mono(meth)acrylate monomers may include a first mono(meth)acrylate with Tg between 50° C. and 175° C. and a second mono(meth)acrylate with Tg between −50° C. and 30° C. The curable compositions may be applied onto a surface of a substrate then cured to form a low-tack adhesive layer on the surface. The curable compositions may be cured by exposure to visible radiation, UV radiation, LED radiation, laser radiation, electron-beam radiation, peroxide, accelerator, or heat. Methods for bonding substrates include contacting a second substrate to a tow-tack adhesive layer on a first substrate, then heating the low-tack adhesive layer to bond the substrates and form a laminate.

The invention relates to an article made from a thermoplastic polyurethane composition having that has high flex modulus, low density, and is capable of withstanding repeated cyclic deformation. The thermoplastic polyurethane composition is formed from the reaction product of a polyol component, which includes a blend of a polyether polyol, such as poly(tetramethylene ether glycol), and polybutadiene diol, a diisocyanate component, and a chain extender component.

A process for providing one or more thermoset polymeric materials onto an object is disclosed wherein said process comprises at least the following steps: Providing a polymeric composition having a viscosity >10 Pa.s at room temperature comprising at least one cross-linkable polymeric material; and then Optionally heating the polymeric composition to achieve a liquid cross-linkable polymeric composition having a viscosity below 4 Pa.s, and then Depositing the polymeric composition onto an object using a spray, swirl or extrusion nozzle and wherein the deposition is performed while the object and/or nozzle are moving to create an object at least partly coated with said polymeric composition; and then Optionally cooling down the at least partly coated object to room temperature, and then Optionally repeating one of foregoing steps, and then Applying a cross-linking treatment selected from radical curing, UV curing and/or heat treatment in order to convert the cross-linkable polymeric material(s) into thermoset polymeric material(s).

The invention relates to a thermoplastic polyurethane material that has high flex modulus, low density, and is capable of withstanding repeated cyclic deformation. The thermoplastic polyurethane composition is formed from the reaction product of a polyol component, which includes a blend of a polyether polyol, such as poly(tetramethylene ether glycol), and polybutadiene diol, a diisocyanate component, and a chain extender component.

The present invention relates to a thermoplastic polyurethane obtainable or obtained by converting a polyisocyanate composition, a one chain extender, and a polyol composition, wherein the polyol composition comprises a polyol (P1) which has a molecular weight Mw in the range from 500 to 2000 g/mol and has at least one aromatic polyester block (B1), wherein the hard segment content in the thermoplastic polyurethane is <75%. The present invention further relates to a process for producing a shaped body comprising such a thermoplastic polyurethane, and to shaped bodies obtainable or obtained by a process of the invention.

The invention relates to a noncrosslinked block copolymer foam, comprising at least one rigid block and at least one flexible block, in which the copolymer includes at least one carboxylic acid chain end blocked with a polycarbodiimide. The invention also relates to a process for manufacturing this foam and to articles manufactured therefrom.

Expandable thermoplastic polyurethane comprising blowing agent, wherein the Shore hardness of the thermoplastic polyurethane is from A 44 to A 84.

Expandable thermoplastic polyurethane comprising blowing agent, wherein the Shore hardness of the thermoplastic polyurethane is from A 44 to A 84.