The disclosed invention provides starting compositions for making lignin hybrid polymers, reactions of lignin and polymer precursors to manufacture lignin hybrid polymers, and final lignin hybrid polymers produced. The most important process requirement is the compatibility of lignin and polymer precursors. Lignin and the polymer precursors must be compatible to assure that the lignin and polymers precursors react and produce a lignin hybrid polymer with useful properties. The lignin hybrid polymers can be in the form of a polyol, a thermoplastic resin, or a thermoset resin. The lignin hybrid polyol, thermoplastic resin, or thermoset resin can be used in a wide range of products including, but not limited to, coatings, adhesives, sealants, elastomers, binders, thermoset resins, thermoplastic resins, and polyurethane systems.

A system for generating a self-receive signal includes: a signal generator; a first signal processor; a second signal processor; and an antenna. The system also includes a first passive coupling device: defining a first input port electromagnetically coupled to the signal generator; defining a first transmitted port; defining a first coupled port electromagnetically coupled to the first signal processor; and characterized by a first phase balance between the first transmitted port and the first coupled port. The system further includes a second passive coupling device: defining a second input port electromagnetically coupled to the antenna; defining a second transmitted port electromagnetically coupled to the first transmitted port; defining a second coupled port electromagnetically coupled to the second signal processor; and characterized by a second phase balance between the second transmitted port and the second coupled port substantially similar to the first phase balance.

Processes disclosed are capable of converting biomass into high-crystallinity, hydrophobic cellulose. In some variations, the process includes fractionating biomass with an acid (such as sulfur dioxide), a solvent (such as ethanol), and water, to generate cellulose-rich solids and a liquid containing hemicellulose and lignin; and depositing lignin onto cellulose fibers to produce lignin-coated cellulose materials (such as dissolving pulp). The crystallinity of the cellulose material may be 80% or higher, translating into good reinforcing properties for composites. Optionally, sugars derived from amorphous cellulose and hemicellulose may be separately fermented, such as to monomers for various polymers. These polymers may be combined with the hydrophobic cellulose to form completely renewable composites.

A flame-retardant composition is described comprising a mixture of a water dispersible organic polymer; and a water dispersible derivative of an unsaturated dicarboxylic acid or anhydride thereof. The water dispersible derivative typically has a solubility in a 0.1 N aqueous solution of NaOH at 25° C. of at least 25 g/liter. Also described is a flame-retardant composition comprising the mixture described dispersed in an aqueous carrier and method of making a flame-retardant composition.

A visibly transparent, homogeneous UV-blocking cellulose nanocrystal/lignin nanocomposite film and a method of making the same. The film is made by dispersing cellulose nanocrystals and lignin in an aqueous, alkaline solution to yield a dispersion; casting the dispersion onto a substrate; and evaporating the aqueous, alkaline solution to yield a homogeneous, visibly transparent film that at least partially absorbs ultraviolet (UV) radiation.

A deep eutectic solvent includes at least one carboxylic acid with at least two carboxylic acid functional groups and a number of carbon atoms in the range of 4 to 10; at least one alcohol which includes at least two alcohol functional groups, and which is selected from the group of alcohols having a number of carbon atoms in the range of 2 to 12, polyethylene glycol and polypropyleneglycol; and water in an amount of 10 to 50 wt. % of the total weight of the deep eutectic solvent. It is also related to the use of these deep eutectic solvents, as solvents for solubilising lignin from a lignin material or for preparing a lignin prepolymer, and a process for preparing a lignin prepolymer which involves the use of the deep eutectic solvents, as well as to the lignin prepolymer as such and uses for producing films, etc.

A method of pyrolysis of Kraft lignin is disclosed, including the steps of providing a microwave generator system, providing a Kraft lignin feedstock in the system, providing a biochar in the system as a microwave receptor, providing nitrogen atmosphere in the system, and heating the feedstock and receptor using microwave energy to make a biooil. A biooil made using the above method is also disclosed as is a biooil having a high phenolic content, in the range of 86.6% to 97.9%.

The invention relates to a method for treating lignin, wherein the method comprises the following steps: a) dissolving lignin into an aqueous composition, which contains a compound selected from the class of phenols, while keeping the temperature of the composition at 0-60° C.; and b) allowing the composition to react while keeping the temperature of the composition at 60-100° C. and the pH of the composition at a pH value of 6-14. The invention relates further to a method for producing a binder composition and to different applications thereof.

The present relates to a process for the depolymerization of lignin using chemicals recoverable by the soda or kraft mill recovery cycles. The process involves the use of sodium hydroxide or white liquor to depolymerize lignin in black liquor or other lignins (e.g. hydrolysis lignin, kraft lignin) by conducting the reaction at 170-250° C. for up to 3 hours in the presence or absence of a co-solvent and a capping agent. The depolymerized lignin is then obtained by acidifying the reaction products to a low pH to precipitate the de-polymerized lignin, followed by particle coagulation, cake filtration and washing with acid and water to obtain a purified depolymerized lignin product.

The disclosed invention provides starting compositions for making lignin hybrid polymers, reactions of lignin and polymer precursors to manufacture lignin hybrid polymers, and final lignin hybrid polymers produced. The most important process requirement is the compatibility of lignin and polymer precursors. Lignin and the polymer precursors must be compatible to assure that the lignin and polymers precursors react and produce a lignin hybrid polymer with useful properties. The lignin hybrid polymers can be in the form of a polyol, a thermoplastic resin, or a thermoset resin. The lignin hybrid polyol, thermoplastic resin, or thermoset resin can be used in a wide range of products including, but not limited to, coatings, adhesives, sealants, elastomers, binders, thermoset resins, thermoplastic resins, and polyurethane systems.