C08H6/00

Fluid catalytic cracking process of crude lignin oil (CLO)

A FCC process including the steps of (a) adding a crude lignin oil (CLO) to a FCC unit, wherein the FCC unit has a FCC riser, a catalyst regenerator and a reactor/stripper, wherein CLO is a crude lignin oil composition including lignin and a polar organic solvent in 1:10 to 1:0.3 w/v ratio, (b) optionally adding a second feed including a conventional FCC feedstock to the FCC unit, (c) adding a regenerated catalyst from the regenerator to the FCC riser for catalytic cracking and upgrading the CLO and second feedstock to produce upgraded products and deactivated catalyst, (d) adding the upgraded products and deactivated catalyst from the FCC riser to the reactor/stripper and separating upgraded products from deactivated catalyst in the reactor/stripper, (e) adding the deactivated catalyst from (d) to the regenerator to regenerate the deactivated catalyst to provide regenerated catalyst; and
collecting the upgraded products.

PROCESSES FOR PRODUCING PHARMACEUTICAL EXCIPIENTS FROM LIGNOCELLULOSIC BIOMASS, AND PHARMACEUTICAL EXCIPIENTS OBTAINED THEREFROM
20220331432 · 2022-10-20 ·

In some variations, the invention provides a process for producing a microcrystalline cellulose material, comprising: fractionating lignocellulosic biomass feedstock in the presence of an acid, a solvent for lignin, and water, to generate cellulose-rich solids and a liquid containing hemicellulose and lignin; chemically and/or mechanically treating the cellulose-rich solids to form microcrystalline cellulose having an average crystallinity of at least 60%; and recovering the microcrystalline cellulose as a pharmaceutical excipient. The pharmaceutical excipient may function as an antiadherent, a binder, a coating, or a disintegrant. In some embodiments, the pharmaceutical excipient further comprises a lignin-derived lubricant, glidant, sorbent, preservative, or other component. The pharmaceutical excipient may be present in a pill, tablet, capsule, powder, slurry, or other pharmaceutically effective and acceptable form.

Modified lignin manufacturing method, modified lignin, and modified lignin-including resin composition material

A method for producing a modified lignin, including reacting one or more kind of a second generation ethanol fermentation residue and a second generation ethanol saccharification residue, with a phenol compound, a modified lignin having a ratio ((2H+G)/S) of a total of twice of a relative existence ratio H (%) of an H-type skeleton and a relative existence ratio G (%) of a G-type skeleton with respect to a relative existence ratio S (%) of an S-type skeleton, obtained from integrated values measured by .sup.31P-NMR, of 2.5 or more, and an existence ratio of an aliphatic hydroxy group obtained by the same method of less than 20%, and a modified lignin-containing resin composition material.

Method for preparing dispersant using lignin degradation products

A method for preparing dispersant using lignin degradation products includes preparation of lignin degradation products: degrading lignin which are used as raw materials using alkali through microwave-assisted activation at the presence of a metal oxide catalyst to obtain the lignin degradation products; and preparation of dispersant: preparing dispersant by molecularly reforming and chemically modifying the lignin degradation products obtained in the step of preparation of lignin degradation products.

Cellulose-containing compositions and methods of making same

Cellulose-containing compositions and method of making same are disclosed. The compositions comprise a cellulose product comprising a type-I cellulose, a type-II cellulose, amorphous cellulose, or a combination thereof. Further, methods are disclosed for making these compositions and for further hydrolyzing these compositions. Additionally, uses for the cellulose-containing compositions are disclosed.

Humic acid-based supercapacitors

A supercapacitor electrode comprises a mixture of graphene sheets and humic acid. The humic acid occupies 0.1% to 99% by weight of the mixture and the graphene sheets are selected from a pristine graphene material having essentially zero % of non-carbon elements, or a non-pristine graphene material having 0.001% to 5% by weight of non-carbon elements. The non-pristine graphene is selected from graphene oxide, reduced graphene oxide, graphene fluoride, graphene chloride, graphene bromide, graphene iodide, hydrogenated graphene, nitrogenated graphene, chemically functionalized graphene, or a combination thereof. The mixture has a specific surface area greater than 500 m.sup.2/g.

Adhesion-promoting composition for a textile material and associated reinforcing textile material
20220282143 · 2022-09-08 ·

The invention relates to an adhesion-promoting composition for a textile material, comprising a salt of lignosulphonate, an epoxy hardener for said salt, comprising at least two epoxide units, and an elastomer latex. The lignosulphonate salt can be a lignosulphonate of sodium, potassium, magnesium, ammonium or calcium. The invention also relates to the use of such a composition for providing a reinforcing textile material with adhesive properties, in relation to a rubber material, to a reinforcing textile material, particularly a textile structure, thread or cord, at least partially coated and/or impregnated with said composition, and to a part consisting of rubber or comprising a rubber material, in which the rubber comprises at least one reinforcing textile material, on the surface thereof and/or integrated into the rubber material.

Method for purifying lignin

The present document discloses a method for purifying lignin. The method comprises steps of solvent dissolution, ultrasonic vibration, centrifugal filtration, stirring in water at a constant temperature, and membrane filtration and drying. In the present application, lignin extracted from a plant fiber raw material using an organic solvent is added to a specific solvent, and is purified by sequentially performing the steps of ultrasonic vibration, centrifugal filtration, stirring in water at a constant temperature, and membrane filtration and drying. Any of the steps cannot be omitted and the sequence thereof cannot be reversed. The steps are efficiently coordinated to achieve a synergistic effect, so as to remove impurities in lignin, and significantly improve the purity of the lignin while maintaining a high purification yield. The invention has broad application prospects and high market value.

Functional lignin, and its use in producing blends, copolymers, and self-healing elastomers
11441035 · 2022-09-13 · ·

A composition comprising lignin compounds possessing 8-30 (or 5-15 or 8-12) phenyl rings interconnected by ether and alkylene linkages and containing hydroxy and/or methoxy groups attached to said phenyl rings, wherein said composition possesses a glass transition temperature of 80-100° C. (or 95-98° C.) and a degree of substitution (DS) of carboxylic acid groups per phenyl ring of at least 0.5 and a DS of methoxy groups per phenyl ring of no more than 1.2, 1.1, or 1.0, wherein at least 90 wt % of said lignin compounds has a molecular weight within a range of 500-5000 g/mol, 1500-3000 g/mol, or 2000-2500 g/mol and/or wherein the molecular weight distribution of the lignin compounds is characterized by a polydispersity index of 1.0-1.5, 1.0-1.4, or 1.0-1.3, and wherein other lignin compounds not possessing the above characteristics are not present. Methods for producing the lignin extract and lignin copolymers and blends produced therefrom are also described.

Lignin hybrid polymers obtained from the reaction of lignin and compatible polymer precursors, and starting compositions for forming lignin hybrid polymers

The disclosed invention provides starting compositions for making lignin hybrid polymers, reactions of lignin and polymer precursors to manufacture lignin hybrid polymers, and final lignin hybrid polymers produced. The most important process requirement is the compatibility of lignin and polymer precursors. Lignin and the polymer precursors must be compatible to assure that the lignin and polymers precursors react and produce a lignin hybrid polymer with useful properties. The lignin hybrid polymers can be in the form of a polyol, a thermoplastic resin, or a thermoset resin. The lignin hybrid polyol, thermoplastic resin, or thermoset resin can be used in a wide range of products including, but not limited to, coatings, adhesives, sealants, elastomers, binders, thermoset resins, thermoplastic resins, and polyurethane systems.