The invention discloses a lignin degradation product-bisphenol A-polyurethane polycondensate additive, and a preparation method thereof. Lignin is used as a raw material, and is degraded by an alkali activator, a metal catalyst and nitrobenzene to obtain the lignin degradation product; then, the obtained lignin degradation product is uniformly mixed with bisphenol A, and polyurethane is added; finally, the additive is obtained after heating reaction and drying. The preparation process of the invention is simple, and the obtained lignin degradation product has a small and stable molecular weight and has abundant phenolic hydroxyl and alcoholic hydroxyl sites, which can improve the dispersibility of the product, with strong cohesiveness and good waterproofness. It solves the problem of industrial application that lignin replaces part of phenols in the prior art, which leads to the decline of product performance, improves the total substitution rate of chemicals derived from biomass to bisphenol A derived from fossil resources, and significantly reducing the discharge of phenolic compounds. The additive is an environment-friendly polymeric material with excellent development potential.

The invention relates to a method for producing stabilized lignin from lignin-containing raw materials, comprising two process steps. The invention also relates to the stabilized lignin produced in this way.

It is disclosed purifies industrial lignin, performs Mannich reaction on purified industrial lignin, aldehyde and amino acid, simultaneously dopes nitrogen and sulfur elements into lignin, and performs high-temperature activation to obtain the carbonized amino acid modified lignin in accordance with a principle of green chemistry; a porous carbon material is prepared from the carbonized amino acid modified lignin by means of a two-step activation method, and an electrochemical workstation is applied to investigate electrochemical performance of the carbonized amino acid modified lignin as a supercapacitor; layered porous carbon having high specific surface area is prepared, the layered porous carbon has high specific heat capacity and stable cycle performance without attenuation when the supercapacitor is prepared from the layered porous carbon, and the method used has a wide application prospect in the aspect of preparing a porous carbon material for the supercapacitor.

An environmentally-friendly epoxy tannin resin based polyurea adhesive and its preparation method are provided. The method includes preparing the environmentally-friendly water-resistant tannin-based wood adhesive by graft copolymerization of epoxy tannin, which is obtained by epoxidation of tannin using epoxy chloropropane, with triethylene tetramine and subsequent deamination reaction of them with urea.

A solid multiphase polymer blend material comprising: (i) a polyphenolic substance having a molecular weight of at least 500 g/mol; and (ii) a polyester having a molecular weight of at least 500 g/mol; wherein at least a portion of the polyphenolic substance is covalently bonded directly or through a linking moiety to the polyester. Methods for producing the blend material are also described, e.g., homogeneously melt blending a mixture comprising components (i) and (ii) under conditions resulting in covalent attachment of at least a portion of the polyphenolic substance directly or through a linking moiety to the polyester. Methods for producing objects made of the blend material by melt extrusion are also described.

Processes are provided for the production of humic acids from coal such as lignite, involving mixing comminuted coal solids with an aqueous alkaline solution under subcritical extraction conditions, which comprise an extraction temperature of from 25 to 50° C.; an extraction pressure of from > 0.1 MPa to < 0.5 MPa; a flow of an oxygen containing gas; and potassium hydroxide.

Disclosed are biodegradable polyester polymers comprising lignin-containing segments and vegetable-oil based segments. Also disclosed herein are methods of making biodegradable polyester polymers and the articles made from these polymers.

A method of depolymerizing a biopolymer in a biomass is presented, the method comprising the step of contacting the biopolymer with a reaction system comprising at least one catalyst, at least one electron source, and at least one solvent. A second method of depolymerizing a biopolymer in a biomass is presented, the method comprising the step of contacting the biopolymer with an electrochemical cell comprising at least one catalyst, at least one solvent, at least one electrolyte, an anode, and a cathode. A third method of depolymerizing a biopolymer is presented, the method comprising the steps of providing a biopolymer; adding a photoredox-active functional group to the biopolymer to form a modified biopolymer; and irradiating the modified biopolymer with light in the presence of a reaction mixture; said mixture comprising a photoredox catalyst.

A low energy production process for producing paper pulp from lignocellulosic biomass, the process comprising the following successive steps: a) extracting lignins and hemicellulose from lignocellulosic biomass by putting at least one solid lignocellulosic raw material in the presence of a mixture, composed only of water and of formic acid, at atmospheric pressure and under controlled conditions of reaction temperature between ambient temperature and the reflux temperature of the mixture at atmospheric pressure, preferably between 80° C. and 100° C., with a weight ratio of the at least one solid lignocellulosic raw material/liquid mixture comprised between 1/1 and 1/15, and for a determined period of time of reaction; and b) separating, at atmospheric pressure and at the reaction temperature, a solid fraction, constituting raw paper pulp, from an organic phase containing in solution at least the starting formic acid and water mixture, solubilized monomeric and polymeric sugars, lignins.

An integrated approach for utilizing waste products of 2G bio-refineries to fractionate the lignin of high purity. The present invention also provides a method of recycling of two waste products (2-G ethanol residue as the substrate (LRBR) and fusel oil/synthetic fusel oil (SFO) as one of the solvent) of the biorefineries in a beneficial manner to fractionate the lignin of high purity. The present method of separating high purity lignin comprises fractioning extractive-free lignin rich residue with a solvent, wherein the solvent is a mixture of SFO/Fusel oil and Formic acid. An optimized ratio of waste fusel oil and formic acid gave more than >85% yields of high purity lignin.