Patent classifications
C08J9/00
Process for enhancing the melt strength of propylene-based polymer compositions
Disclosed is a process for preparation of a propylene-based polymer composition involving the steps of: (a) mixing a propylene-based polymer and a peroxydicarbonate in a mixing device, wherein the mixing takes place at a temperature of ≤30° C., wherein the peroxydicarbonate is introduced into the mixing process in a dry form; (b) keeping the mixed composition at a temperature of ≤30° C.; (c) feeding the mixed composition into a melt extruder; (d) homogenizing the mixed composition at a temperature where the propylene-based polymer is in solid state during an average residence time of ≥6.0 and ≤30.0 seconds; (e) further homogenizing the mixed composition at a temperature at which the propylene-based polymer is in the molten state; and (f) extruding the homogenized material from a die outlet of the melt extruder followed by cooling and solidification; wherein the steps (a) through (f) are conducted in that order.
Molding compositions and foam molded articles made thereof
A foamed article formed by foam injection molding or foam extrusion of a composition is disclosed. The article is formed from a molding composition consisting essentially of: 100 phr of at least two different hydrogenated styrenic block copolymers (HSBC), a first HSBC and a second HSBC, having different molecular weights, a molecular weight ratio of at least 1.2:1, respectively; and a weight ratio of ranging from 5:95 to 95:5, respectively; 10-55 phr of a polypropylene having a melt flow of at least 2 g10/min; and optionally up to 55 phr of a plasticizer, selected from hydrocarbon based oils, fatty acids, triglyceride oils, and mixtures thereof. The composition has a melt flow rate of 2-50 g/10 min, a Shore A hardness of 60-90, a melt strength (F) of at least 0.010 N, and a melt strength (V) of at least 10.
Porous body, and method for producing porous body
The present invention provides a porous body, the swelling of which under acidic conditions is suppressed, and a method for producing the porous body. The first porous body of the present invention is formed of a copolymer of an epoxy compound and a curing agent, wherein the porous body is a porous body containing no primary to tertiary amino groups and has an interconnected pore structure in which holes provided inside the porous body communicate with each other. The second porous body of the present invention is formed of a copolymer of an epoxy compound and a curing agent, wherein the porous body is a porous body containing no nitrogen atom to be quaternized by acid treatment, and has an interconnected pore structure in which holes provided inside the porous body communicate with each other.
VISCOELASTIC POLYURETHANE FOAM WITH AQUEOUS POLYMER DISPERSANT
A reaction system for forming a viscoelastic polyurethane foam includes an isocyanate component and an isocyanate-reactive component that includes at least a polyol component, an additive component, and a preformed aqueous polymer dispersant. The mixture includes 50.0 wt % to 99.8 wt % of the polyol component, 0.1 wt % to 49.9 wt % of the additive component, and 0.1 wt % to 6.0 wt % of the preformed aqueous polymer dispersant. The aqueous polymer dispersant has a pH from 6.0 to 12.0 and includes from 5 wt % to 60 wt % of a polymeric component and from 40 wt % to 95 wt % of a fluid medium. The polymeric component includes at least one base polymer derived from 20 wt % to 100 wt % of at least one hydrophilic acid monomer having at least one carbonyl group, phosphate group, phosphonate group, or sulfonyl group, and optionally derived from at least one hydrophobic terminally unsaturated hydrocarbon monomer.
Shape Memory Polymers
New shape memory polymer compositions, methods for synthesizing new shape memory polymers, and apparatus comprising an actuator and a shape memory polymer wherein the shape memory polymer comprises at least a portion of the actuator. A shape memory polymer comprising a polymer composition which physically forms a network structure wherein the polymer composition has shape-memory behavior and can be formed into a permanent primary shape, re-formed into a stable secondary shape, and controllably actuated to recover the permanent primary shape. Polymers have optimal aliphatic network structures due to minimization of dangling Chains by using monomers that are symmetrical and that have matching amine and hydroxl groups providing polymers and polymer foams with clarity, tight (narrow temperature range) single transitions, and high shape recovery and recovery force that are especially useful for implanting in the human body.
Shape Memory Polymers
New shape memory polymer compositions, methods for synthesizing new shape memory polymers, and apparatus comprising an actuator and a shape memory polymer wherein the shape memory polymer comprises at least a portion of the actuator. A shape memory polymer comprising a polymer composition which physically forms a network structure wherein the polymer composition has shape-memory behavior and can be formed into a permanent primary shape, re-formed into a stable secondary shape, and controllably actuated to recover the permanent primary shape. Polymers have optimal aliphatic network structures due to minimization of dangling chains by using monomers that are symmetrical and that have matching amine and hydroxl groups providing polymers and polymer foams with clarity, tight (narrow temperature range) single transitions, and high shape recovery and recovery force that are especially useful for implanting in the human body.
HYBRID POLYURETHANE SPRAY FOAMS MADE WITH URETHANE PREPOLYMERS AND RHEOLOGY MODIFIERS
Hybrid spray foams utilize a urethane reactant, a crosslinker, and an (optional) epoxy and/or acrylic resin along with a blowing agent and rheology modifier to produce a quick-setting foam that remains in place until the foam forms and cures. The urethane reactant may be formed as an adduct with or without the use of isocyanate chemistry. In some embodiments, the polyurethane oligomer is made by reacting cyclocarbonates and di- or polyamines, while in other embodiments the polyurethane backbone employs the use of commercially available capped or blocked urethane oligomers made by any method. The oligomers contain reactive groups, typically at the oligomer ends, that crosslink with crosslinkers or with acrylic or epoxy resins to form hybrid polyurethane foams. Foams may also contain a plasticizer, and/or a surfactant as well as other optional additives. Methods of making such foams are also provided.
INFRARED ATTENUATION AGENT BLENDS
Inorganic infrared attenuation agent blends have been developed to improve the thermal insulation properties of polymeric foams such as polystyrene low density foams. The inorganic infrared attenuation agent blends can include two or more metal oxides such as silicon dioxide, manganese (IV) oxide, iron (III) oxide, magnesium oxide, bismuth (III) oxide, cobalt oxide, zirconium (IV) oxide, molybdenum (III) oxide, titanium oxide, and calcium oxide. In some preferred embodiments, the inorganic infrared attenuation agent blends can include four or more of these metal oxides.
TPU FOR INMOLD ASSEMBLY OF AN OUTER SHOE SOLE ON ETPU
A molded article (M) contains a molded article (M-1) made of a thermoplastic elastomer (TPE-1) and a foamed pellet material made of a thermoplastic elastomer (TPE-2). The molded article (M-1) has a softening temperature TS (TPE-1) that deviates by no more than 25° C. from the processing temperature TP (TPE-2) of the thermoplastic elastomer (TPE-2). The softening temperature is determined by TMA in accordance with ISO 11359-3:2014. A process can be used for producing the molded article. The molded article can be used for application in the sports, industry, medicine, sports medicine, safety, automotive and consumer goods field, especially as a shoe sole, a part of a shoe sole, a bicycle saddle, a cushioning, a mattress, an underlay, a grip, a protective film, or a component in automobile interiors and exteriors.
Elastic body, bump stop, electromagnetic induction device, power generation system, detection device, and production method for elastic body
An elastic body of this disclosure contains magnetized magnetic powder dispersed in an elastic member, and generates an induced current in a circuit by undergoing an elastic deformation to cause a change in magnetic flux density. The elastic member is an elastomeric foam.