A thermoset material containing -hydroxyesters wherein said thermoset material is subject to a mechano-chemical process to regenerate an epoxide and a carboxylic acid functionality. A curative for epoxidized plant-based oils and epoxidized natural rubber is created from the reaction between a naturally occurring polyfunctional acid and an epoxidized plant-based oil is disclosed. The curative may be used to produce porosity-free castable resins and vulcanize rubber formulations based on epoxidized natural rubber. Materials made from disclosed materials may be advantageously used as leather substitutes.

Provided are a carboxylic acid-modified nitrile-based copolymer latex composition, a preparation method thereof, a latex composition for dip-molding including the same, and an article molded by the same, the carboxylic acid-modified nitrile-based copolymer latex composition including: a carboxylic acid-modified nitrile-based copolymer, wherein the carboxylic acid-modified nitrile-based copolymer includes a 2-hydroxyethyl methacrylate monomer-derived repeating unit in an amount of more than 0.1 wt % to less than 12 wt %, and a coagulum in the carboxylic acid-modified nitrile-based copolymer latex composition has an amount of less than 1 wt %.

There are provided a tire that combines a low elastic modulus at low temperatures with a high hysteresis loss at low temperatures and has excellent on-ice brake performance, and a vulcanized rubber and a rubber composition from which the tire is obtained. A rubber composition comprising a rubber component comprising a natural rubber, a polybutadiene rubber, and a styrene-butadiene copolymer rubber, and 50 to 90 parts by mass of a filler comprising silica relative to 100 parts by mass of the rubber component, wherein the mass n of the natural rubber in the rubber component is 40% by mass or more, the mass n, the mass b of the polybutadiene rubber, and the mass s of the styrene-butadiene copolymer rubber satisfy the relation: sbn, provided that when n=b, s<b, and 50% by mass or more of the silica is comprised in a phase comprising the polybutadiene rubber and the styrene-butadiene copolymer rubber.

An aqueous adhesive composition for treating a reinforcing fiber for bonding to a thermosetting polymer matrix and products made therefrom such as power transmission belts. The adhesive composition includes: water as the solvent or dispersing medium; a polyelectrolyte co-curable with the polymer matrix; a primer material compatible with the fiber and co-curable with the polyelectrolyte; and optionally a rubber curative compatible with the polyelectrolyte and the polymer matrix. A fiber-reinforced, composite polymer system may thus include a thermosetting polymer matrix, a reinforcing fiber embedded therein, and an adhesive composition coating the fiber; the adhesive composition including a polyelectrolyte co-curable with the polymer matrix and a primer material compatible with the fiber and co-curable with the polyelectrolyte. The adhesive composition may include a curative compatible with the polyelectrolyte. In one preferred embodiment, the invention is an aqueous adhesive composition including water, an epoxy resin, a maleated polybutadiene derivative, and a curative.

The dynamic fatigue and hysteresis performances of fiber reinforced rubber compounds are compared using different plasticizers. Fiber reinforced rubber compounds including a non-linear functionalized fatty acid ester, preferably a trimellitate, and more preferably Tris (2-Ethylhexyl) Trimellitate (TOTM) are shown to demonstrate greatly improved dynamic fatigue and hysteretic performance as compared to reference fiber reinforced rubber compounds including conventional reference plasticizers such as Di-isodecyl phthalate (DIDP).

Disclosed herein are polysaccharide-elastomer masterbatch compositions and processes for preparing the masterbatch compositions. One method comprises a step of a) mixing i) an aqueous polysaccharide dispersion, or ii) a basic aqueous polysaccharide solution, with a rubber latex solution containing a rubber component to form a mixture. The method further comprises the steps of: b) coagulating the mixture obtained in step a) to produce a coagulated mass; and c) drying the coagulated mass obtained in step b). The masterbatch compositions are useful in preparing rubber-containing articles.

Provided is a rubber composition that can improve the on-ice performance of a rubber article such as a tire while maintaining the wear resistance of the rubber article at a good level. The rubber composition contains a rubber component and fibrous or flat particles, where the particles form a plurality of aggregates in the rubber composition, and a proportion of aggregate having an aggregation diameter of 10 m or more and 1000 m or less is 70% or more among the plurality of aggregates.

The present invention has as its object the provision of a production process of a rubber composition containing a modified conjugated diene-based polymer, which can provide a rubber composition in which processability is excellent, and a filling agent, when contained, has favorable dispersibility therein.

The production process of a rubber composition according to the present invention includes: a first step of kneading a modified conjugated diene-based polymer that is obtained by polymerizing a monomer containing a conjugated diene compound and has at least one nitrogen-containing functional group selected from the group consisting of a primary amino group, a secondary amino group, a tertiary amino group and groups in which these amino groups have been converted into an onium group, and a basic compound having an acid dissociation constant of 8.0 or more; and a second step of kneading the kneaded product obtained in the first step and a cross-linking agent.

An aqueous adhesive composition for treating a reinforcing fiber for bonding to a thermosetting polymer matrix and products made therefrom such as power transmission belts. The adhesive composition includes: water as the solvent or dispersing medium; a polyelectrolyte co-curable with the polymer matrix; a primer material compatible with the fiber and co-curable with the polyelectrolyte; and optionally a rubber curative compatible with the polyelectrolyte and the polymer matrix. A fiber-reinforced, composite polymer system may thus include a thermosetting polymer matrix, a reinforcing fiber embedded therein, and an adhesive composition coating the fiber; the adhesive composition including a polyelectrolyte co-curable with the polymer matrix and a primer material compatible with the fiber and co-curable with the polyelectrolyte. The adhesive composition may include a curative compatible with the polyelectrolyte. In one preferred embodiment, the invention is an aqueous adhesive composition including water, an epoxy resin, a maleated polybutadiene derivative, and a curative.

A rubber-reinforcing cord of the present invention is a rubber-reinforcing cord for reinforcing a rubber product. The rubber-reinforcing cord includes at least one strand. The strand includes at least one filament bundle and a coating provided to cover at least a portion of a surface of the filament bundle. The coating includes a rubber component and a crosslinking agent. The crosslinking agent includes two or more isocyanate compounds.