Vents and micro-structures of rubber molds may become clogged with rubber that is difficult to remove. These vents and micro-structures can be cleaned of rubber, even if heat aged, by subjecting the mold to high temperatures in the presence of a solvent to devulcanize any rubber present. If the rubber used with the mold being cleaned includes carbon black, a solvent may be used to dissolve the devulcanized polymer, leaving the carbon black which can be removed by water jets or other cleaning means.

The invention provides a method of making a electrocatalyst from waste tires. The method comprises the steps of providing rubber pieces; optionally contacting the rubber pieces with a sulfonation bath to produce sulfonated rubber; pyrolyzing the rubber to produce tire-derived carbon composite comprising carbon black, wherein the pyrolyzing comprises heating to at least 200° C.-2400° C.; activating the tire-derived carbon composite by contacting the tire-derived carbon composite with an alkali anion compound to provide activated tire-derived carbon supports; and loading the activated carbon-based supports with platinum cubes. In another embodiment, the tire-derived carbon composite is activated by annealing in a carbon dioxide atmosphere.

Crumb rubber obtained from recycled tires is subjected to an interlinked substitution process. The process utilizes a reactive component that interferes with sulfur bonds. The resulting treated rubber exhibits properties similar to those of the virgin composite rubber structure prior to being granulated, and is suitable for use in fabricating new tires, engineered rubber articles, and asphalt rubber for use in waterproofing and paving applications.

A process for extracting fuel products from waste rubber, comprising the steps of subjecting the waste rubber to pyrolysis to produce a pyrolysis vapour, subjecting the pyrolysis vapour to a condensation step to produce a pyrolytic oil having a boiling point range of 45-400° C. and a flash point below 25° C., and then subjecting the pyrolytic oil to a vacuum steam stripping step so as to recover a fraction having a first composition having a flash point above 55° C., a boiling point range starting at 140° C. or higher, a density at 15° C. of less than 990 kg/m.sup.3, a total acid number TAN of up to 12, a styrene content of less than 3000 ppm, and an organic halogen (as C1) content of less than 50 ppm, and a second composition having an initial boiling point not exceeding 75° C. under atmospheric pressure, a density at 15° C. of greater than 790 kg/m.sup.3, a benzene content of at least 1.25 vol %, an existent gum (washed) content greater than 10 mg/100 ml, an organic halogen (as Cl) content of less than 50 mg/kg, and a colour of less than 5.0.

Crumb rubber obtained from recycled tires is subjected to an interlinked substitution process. The process utilizes a reactive component that interferes with sulfur bonds. The resulting treated rubber exhibits properties similar to those of the virgin composite rubber structure prior to being granulated, and is suitable for use in fabricating new tires, engineered rubber articles, and asphalt rubber for use in waterproofing and paving applications.

Fossil-fuel and rubber-derived waste stream conversion to composite lumber substitutes or barrier members; the composites having material properties and uses of greater value than the solid waste stream components separately or together. Preferred combinations including waste materials derived from waste carpet, waste tires, and waste bituminous roofing shingles, all enormous problems for landfill disposal. In a range of formulation ratios, when combined with a binder, new and marketable products are made from solid waste. Improved resistance to rot, to water, and to weathering is exhibited in synergy with improved compressive and flexural strength, enabling production of a wide variety of useful and environmentally-friendly structural products, for example. Product weight and strength can be engineered to suit and may be structural members for architectural, engineering or agricultural use. Advantageously, the new products themselves can be re-used—by an end-of-life process for making more new products, achieving the capacity to make and remake multigenerational products from solid wastes and to reduce loading of landfills. Production by profile extrusion and by RIM molding are described.

Recycled rubber is provided, which is formed by depolymerizing 100 parts by weight of rubber and 0.5 to 10 parts by weight of modifier, wherein the modifier is formed by reacting (a) R.sup.1-M, (b) double bond monomer, (c) ethylene sulfide, and (d) polymerization terminator, wherein R.sup.1 is C.sub.4-C.sub.16 alkyl group, M is Li, Na, K, Ba, or Mg and (b) double bond monomer is 1,3-butadiene, isoprene, 1,3-pentadiene, 2,3-dimethyl-1,3-butadiene, 2-methyl-1,3-pentadiene, 2,3-dimethyl-1,3-pentadiene, 2-phenyl-1,3-butadiene, 4,5-diethyl-1,3-octadiene, styrene, 1-ethylene naphthalene, 3-methylstyrene, 3,5-diethylstyrene, 4-propylstyrene, 2,4,6-trimethylstyrene, 4-dodecylstyrene, 3-methyl-5-n-hexylstyrene, 4-phenylstyrene, 2-ethyl-4-benzylstyrene, 3,5-diphenylstyrene, 2,3,4,5-tetraethyl styrene, 3-ethyl-1-vinylnaphthalene, 6-isopropyl-1-vinylnaphthalene, 6-cyclohexyl-1-vinylnaphthalene, 7-dodecyl-2-vinylnaphthalene, α-methyl styrene, or a combination thereof.

Crumb rubber obtained from recycled tires is subjected to an interlinked substitution process. The process utilizes a reactive component that interferes with sulfur bonds. The resulting treated rubber exhibits properties similar to those of the virgin composite rubber structure prior to being granulated, and is suitable for use in fabricating new tires, engineered rubber articles, and asphalt rubber for use in waterproofing and paving applications.

Crumb rubber obtained from recycled tires is subjected to an interlinked substitution process. The process utilizes a reactive component that interferes with sulfur bonds. The resulting treated rubber exhibits properties similar to those of the virgin composite rubber structure prior to being granulated, and is suitable for use in fabricating new tires, engineered rubber articles, and asphalt rubber for use in waterproofing and paving applications.

Vents and micro-structures of rubber molds may become clogged with rubber that is difficult to remove. These vents and micro-structures can be cleaned of rubber, even if heat aged, by subjecting the mold to high temperatures in the presence of a solvent to devulcanize any rubber present. If the rubber used with the mold being cleaned includes carbon black, a solvent may be used to dissolve the devulcanized polymer, leaving the carbon black which can be removed by water jets or other cleaning means.