Patent classifications
C08J2345/00
Stable mass polymerizable polycycloolefin compositions as 3D printing materials and a method of fabrication thereof
Embodiments in accordance with the present invention encompass compositions encompassing a latent organo-ruthenium compound, a pyridine compound, a photosensitizer and an ultra violet light blocking compound along with one or more monomers which undergo ring open metathesis polymerization (ROMP) when said composition is exposed to suitable actinic radiation to form a substantially transparent film or a three dimensional object. Surprisingly, the compositions are very stable at ambient conditions to temperatures up to 80° C. for several days and undergo mass polymerization only when subjected to actinic radiation under inert atmosphere such as for example a blanket of nitrogen. Accordingly, compositions of this invention are useful in various opto-electronic applications, including as 3D printing materials, coatings, encapsulants, fillers, leveling agents, among others.
PREPARATION OF METALLOCENE CONTAINING CATIONIC POLYMERS FOR ANION EXCHANGE APPLICATIONS
Chemically inert, mechanically tough, cationic metallo-polyelectrolytes designed as durable anion-exchange membranes (AEMs) via ring-opening metathesis polymerization (ROMP) of cobaltocenium-containing cyclooctene with triazole as the only linker group, followed by backbone hydrogenation to provide a new class of AEMs with a polyethylene-like framework and alkaline-stable cobaltocenium cation for ion transport, which exhibit excellent thermal, chemical and mechanical stability, as well as high ion conductivity.
SOLVENT BLENDS FOR OLEFIN SHRINK FILM SEAMING, SHRINK LABELS FORMED WITH SAID SOLVENT BLENDS AND METHODS OF PROVIDING SEAMS WITH SAID SOLVENT BLENDS
A solvent blend useable for tackifying a surface of a plastic film includes a terpene based solvent and one or more of a solvent from the group consisting of a straight chain alkane, a branched chain alkane, a cyclic alkane, a substituted cyclic alkane, a straight chain ether, a branched chain ether, a cyclic ether, a substituted cyclic ether, a cyclic diether, a substituted cyclic diether, a straight chain ketone, a branched chain ketone, a cyclic ketone, a substituted cyclic ketone, a straight chain ester, and a branched chain ester.
Gels derived from poly(ethylidene norbornene)-b-poly(cyclopentene) block copolymer nanocomposites for viscosity modifications and drilling fluid applications
The present application is directed to a nanocomposite organo gel having a continuous polymeric network structure, wherein polymer chains are held together by ionic interaction between polymer chain ends, interparticle chain entanglements, layered silicate surface modifier, ionic salt, and layered silicate. The present application is also directed to methods of making and using the nanocomposite organo gel.
HARD COAT FILM AND METHOD FOR PRODUCING SAME
The present invention provides a hard coat film having excellent adhesion to a hard coat layer when a cycloolefin polymer film is used as a base material.
The hard coat film of the present invention comprises a hard coat layer containing an ionizing radiation curable resin laminated on at least one surface of a cycloolefin polymer base film through a primer layer. This primer layer contains a modified polyolefin resin in which a polyolefin resin is graft-modified with an α,β-unsaturated carboxylic acid or a derivative thereof, and a (meth)acrylic acid ester. In this modified polyolefin resin, the graft weight of the α,β-unsaturated carboxylic acid or derivative thereof is 0.4 to 7 wt. % when the amount of the modified polyolefin resin is taken as 100 wt. %.
POLY(CYCLOHEXADIENE) HOMOPOLYMER BASED COMPOSITIONS AND USES THEREOF
The disclosure relates to methods for producing poly(cyclohexadiene) homopolymers (PCHD). The PCHD is formed by polymerizing a 1,3-cyclohexadiene monomer in the presence of a catalyst, in a hydrocarbon solvent, and at a temperature of −100° C. to 120° C. The catalyst is selected from the group consisting of a Bronsted acid, a Lewis acid, and combinations thereof. PCHD produced under these conditions has good solubility in non-polar solvents, and a number average molecular weight of 300 to 5,000 Dalton; a weight average molecular weight of 5,000 to 15,000 Delton; and a polydispersity index of 3.0 to 8.0. The PCHD is useful for producing crosslinked materials having good physical properties. The crosslinked materials can be combined with a rubbery polymer to produce compositions valuable for further downstream uses.
CYCLIC DIENE-BASED COPOLYMERS
Disclosed herein are copolymers formed by cationic polymerfization of one or more cyclic dienes and a comonomer selected from the group consisting of a monoterpene, a branched styrene, and combinations thereof, in the presence of a catalyst. Random copolymers having repeat units derived from a cyclic conjugated diene, such as 1,3-cyclohexadiene, and a comonomer such as a monoterpene, can be prepared as soluble products in hydrocarbon solvents. The copolymers can be crosslinked with various crosslinking agents to form materials having good oxidative stability and fire retardancy. The uncrosslinked and crosslinked copolymers have useful properties such as a low dissipation factor, low dielectric constants, and a good balance of thermomechanical and electrical properties that make them valuable in electronic applications.
ANION-EXCHANGE MEMBRANES AND METHODS OF MAKING AND USING THE SAME
The invention relates to an anion-exchange membrane (AEM) having a multiblock copolymer including a hydrophilic norbornene-based monomer and a hydrophobic alkene-based or norbornene-based monomer. The hydrophilic norbornene-based monomers include one or more cationic head groups such as a quaternary ammonium ion, which can optionally be crosslinked with a crosslinking agent to increase the structural stability of the polymer. These AEMs can be employed in electrochemical devices such as fuel cells.
WATER BASED DISPERSION TO MAKE COATINGS WITH INCREASED MVTR BARRIER PROPERTIES
The present invention relates to an aqueous dispersion, comprising or consisting of A) at least one cyclic olefin copolymer, B) at least one surfactant; optionally C) at least one adhesion promoter; optionally D) at least one film-forming resin; optionally E) at least one additive; and F) water. Additionally, the invention relates to methods of manufacturing the aqueous dispersion, to an article, which comprises at least one substrate and at least one coating layer obtained from the aqueous dispersion and applied onto the substrate; and to methods of improving MVTR of a substrate.
LAMINATED UNCURED SHEET
A laminated uncured sheet of the present disclosure has a structure in which resin sheet layers and resin layers are alternately laminated and a through hole penetrating in the laminating direction is formed, wherein the resin sheet layers are formed with a thermosetting resin composition containing a thermosetting resin as a main component, the resin layers are formed with a thermoplastic resin composition containing a thermoplastic resin, and the thermoplastic resin composition is adhered to the inner wall surface of the resin sheet layer part in the through hole.