C08J2351/00

VINYL-BASED RESIN PARTICLES AND METHOD FOR MANUFACTURING SAME
20200399413 · 2020-12-24 · ·

The present invention provides vinyl-based resin particles capable of forming uniform pores in a thermosetting resin film when the particles are used as a pore-forming material for a thermosetting resin. Specifically, the present invention provides vinyl-based resin particles for use in making a thermosetting resin porous, the particles having a temperature of 300 to 350 C. at 10% mass loss when heated at a rate of 10 C./min in an air atmosphere, and the particles having a mass loss percentage of 85 to 100% after being heated at 350 C. for 5 hours in an air atmosphere.

Method for producing acrylate rubber at reduced emulsifier concentration

Method for producing a thermoplastic moulding compound containing: up to 40 wt. % of a graft copolymer A, containing 50-70 wt. % graft base A1 from an acrylic ester polymer and 30-50 wt. % of a graft shell A2, and 0-90 wt. % of a hard matrix B, wherein the reaction for producing the graft copolymer A is carried out in the presence of 0.01 to 4 times the molar amount of sodium carbonate, relative to the molar amount of initiator, wherein the reaction for producing copolymer A is carried out in the presence of 0.1 to 1 wt. % of an emulsifier relative to the amount of the respective monomers used, and wherein during the polymerisation reaction, during the post-polymerisation and/or after the polymerisation reaction, water or an aqueous alkali solution are added to the reaction mixture for producing the graft copolymer A.

ANTI-NEWTON RING FILM, AND MANUFACTURING METHOD AND USE THEREOF
20200355855 · 2020-11-12 · ·

The anti-Newton ring film of the present invention is manufactured by subjecting a liquid phase containing one or a plurality of polymers, one or a plurality of curable resin precursors, and a solvent to phase separation through spinodal decomposition in association with evaporation of the solvent to thereby form a phase-separated structure, and then curing the curable resin precursor to form an anti-Newton ring layer having an arithmetic mean roughness Ra of 30 nm or less. This film may have a parallel light transmittance of 90% or greater, a haze of 3% or less, and a transmission image clarity of 90% or higher as measured by an image clarity meter using an optical comb with a width of 0.5 mm. The anti-Newton ring layer may contain the polymer and the curable resin precursor at a ratio (weight ratio) of from 1/99 to 60/40. This film can effectively suppress the occurrence of a Newton's ring in a resistive touch screen, and can suppress glare even in a high-definition LCD and an organic EL display.

METHOD FOR PRODUCING DN GEL MEMBRANE

A method of producing a DN gel membrane includes a step (1) including producing a 1st gel membrane by (i) casting, on a substrate, a solution containing an ionic liquid A and an ionic liquid B, the ionic liquid A being made up of 1st monomers each of which has a polymerizable functional group and (ii) polymerizing the 1st monomers; and a step (2) including producing the DN gel membrane by (i) immersing the 1st gel membrane in a solution containing 2nd monomers which are different from the 1st monomers and (ii) polymerizing the 2nd monomers. This method allows for continuous-type production which is suitable for industrial mass production of DN gel membranes or acid gas separation membranes.

THERMOSETTING RESIN COMPOSITION, PREPREG MADE THEREFROM, LAMINATE CLAD WITH METAL FOIL, AND HIGH-FREQUENCY CIRCUIT BOARD
20200207899 · 2020-07-02 ·

Disclosed are a thermosetting resin composition, a prepreg made therefrom, a laminate clad with a metal foil, and a high-frequency circuit board, wherein the thermosetting resin composition contains thermosetting ingredients. The thermosetting ingredients include a phosphorus-containing monomer or a phosphorus-containing resin and another thermosetting resin containing an unsaturated group, and the phosphorus-containing monomer or the phosphorus-containing resin has a structure as shown in formula I. By using the phosphorus-containing monomer or the phosphorus-containing resin as a cross-linking agent of the other thermosetting resin containing an unsaturated group and by means of a cross-linking reaction of a large number of unsaturated double bonds in the resin, the high-frequency dielectric properties and high-temperature-resistance required by a circuit substrate are provided.

Crosslinkable fluoropolymers

The present invention pertains to a process for the manufacture of a crosslinkable fluoropolymer, to said crosslinkable fluoropolymer and the crosslinked fluoropolymer obtainable therefrom, to a film comprising said crosslinkable fluoropolymer or said crosslinked fluoropolymer and to uses of said crosslinked fluoropolymer film in various applications.

Acrylic film, method for producing same, laminate film, laminated injection molded article, and method for producing rubber-containing polymer

An acrylic film having few fish eyes and a method for producing latex of an acrylic rubber-containing polymer having low amounts of coarse particles, excellent filtering properties, and low filter clogging frequency during a filtration step for removing foreign substances. An acrylic film containing an acrylic rubber-containing polymer and a thickness of 30 to 300 m, wherein the number of fish eyes that are 0.001 mm.sup.2 or greater in size is 130/m.sup.2 or fewer when a section having a light transmission rate of 75% or less for light having a wavelength of 400 to 1100 nm was detected as a fish eye A laminate film formed by laminating the acrylic film and a layer of at least one resin selected from thermoplastic resin, thermosetting resin, and photo curable resin. A laminated injection molded article formed by laminating the acrylic film on an injection molded article.

LIQUID-RETAINING ELASTOMERIC COMPOSITIONS, PROCESS OF PREPARATION AND USES THEREOF

Provided are compositions-of-matter comprising a continuous elastomeric matrix that is structurally-templated by an external phase of a high internal phase emulsion (HIPE), and a liquid dispersed and entrapped in the elastomeric matrix in a form of a plurality of discrete liquid-filled voids. Also provided are processes for obtaining said compositions-of-matter and uses thereof.

Surface modification method

Provided are methods for surface-modifying a thermoplastic resin which produce surfaces that show not only low adsorption of proteins and cells but also selective adsorption or adhesion of specific cells such as cancer cells, and further have excellent durability. A method for surface-modifying an object made of a thermoplastic resin, the method including: step 1 of forming polymerization initiation points on the surface of the object; and step 2 of radically polymerizing at least a hydrophilic monomer starting from the polymerization initiation points by irradiation with UV light having a wavelength of 300 to 400 nm to form a graft layer having a thickness of 2 to 100 nm on the surface of the object.

Reverse-phase polymerisation process

A reverse-phase suspension polymerisation process for the manufacture of polymer beads comprising forming aqueous monomer beads of an aqueous solution comprising water-soluble ethylenically unsaturated monomer or monomer blend and polymerising the monomer or monomer blend to form polymer beads while suspended in a non-aqueous liquid, recovering polymer beads, and then cleaning the non-aqueous liquid in which the process comprises providing the non-aqueous liquid in a vessel (1), forming a suspension of monomer beads from the aqueous monomer or monomer blend in the non-aqueous liquid, initiating polymerisation to form polymerising beads, removing a suspension of the polymer beads in non-aqueous liquid from the vessel and recovering, water soluble or water swellable polymer beads from the suspension, in which the non-aqueous liquid contains impurities which comprise particles, and then transferring the non-aqueous liquid from the suspension to a cleaning stage, in which the cleaning stage provides a cleaned non-aqueous liquid suitable for use in a reverse-phase suspension polymerisation process, which cleaning stage comprises removing particles from the non-aqueous liquid in at least one filtration step. The invention also relates to the apparatus suitable for carrying out a reverse-phase suspension polymerisation and polymer beads obtainable by the process or employing the apparatus. The invention further relates to a cleaned non-aqueous liquid obtainable by the process.