C08J2353/00

Method of Fabricating Block-Copolymer-based 3D Polymorphic Artificial Bilayer Membrane Structure

The present invention relates to a method for manufacturing a three-dimensional structure based on a block copolymer. The method comprises the steps of injecting a block copolymer (BCP) solution into each micro-well formed on the substrate and drying it to form a block copolymer layer, and applying a buffer to the block copolymer layer to hydrate the micro-well in three dimensions Forming the structure, after the three-dimensional structure is formed, injecting and curing a hydrogel solution around the three-dimensional structure may include the step of enhancing stability. In particular, the process of hydration by applying a buffer to the micro-well is performed while an electric field is applied. By controlling the concentration of the block copolymer (BCP) and the amplitude and frequency of the electric field, a three-dimensional artificial cell membrane having a desired size and shape, such as a spherical or ciliary shape and high stability (100% survival for 50 days) is manufactured can do. The present invention can be efficiently applied to various biological fields such as artificial cells, cell-mimicking biosensors, and bioreactors.

Foam compositions and uses thereof
11739201 · 2023-08-29 · ·

Components for articles of footwear and athletic equipment are provided including a foam. A variety of foams and foam components and compositions for forming the foams are provided. In some aspects, the foams and components including the foams can have exceptionally high energy return while also having improved durability and softness. In particular, midsoles including the foams are provided for use in an article of footwear. Methods of making the compositions and foams are provided, as well as methods of making an article of footwear including one of the foam components. In some aspects, the foams and foam components can be made by injection molding or injection molding followed by compression molding.

PROCESSABLE AND PRINTABLE ACRYLIC FILMS AND ARTICLES FORMED THEREFROM
20230265253 · 2023-08-24 ·

Films of flexible acrylic polymers in combination with thermoplastic elastomers are disclosed that are conformable like thermoplastic PVC, processable, and printable. Articles comprising these films with adhesive and optional printed indicia and optional liners are also disclosed.

TEMPERATURE-DEPENDENT SHAPE MEMORY POLYMER
20230256143 · 2023-08-17 ·

The present invention relates to a shape memory polymer that can be restored to an original shape from a deformed shape by means of body temperature in the body. When using the shape memory polymer of the present invention and a device for wrapping the outer wall of blood vessels prepared thereby, it is possible to effectively prevent abnormal blood vessel dilatation, and prevent stenosis by effectively inhibiting neointimal formation.

ERASABLE AND REUSABLE MARKING SURFACE

An erasable laminate for marking is disclosed. The laminate comprises a substrate with a marking surface, allowing a user to provide markings on the marking surface using the marking material. The marking surface comprises an outer layer containing a sulfonated block copolymer having an ion exchange capacity (IEC) of >0.5 meq/g. At least 50% of the markings can be erased from the marking surface with a wipe moist with a cleaning fluid (e.g., water, isopropyl alcohol, etc.) after wiping for less than 5 min. The laminate with erasable and reusable marking surface can be used for obtaining writing instruments, e.g., notebooks, artist easels, sketches, etc.

Polyolefin-based resin film
11718746 · 2023-08-08 · ·

A polyolefin-based resin film containing (a) 90 to 97 parts by weight of at least one polyolefin-based resin selected from a propylene-ethylene block copolymer and a propylene-α olefin random copolymer and (b) 3 to 10 parts by weight of an ethylene-propylene copolymer elastomer, wherein the propylene-α olefin random copolymer is present in an amount of 0 to 50% by weight relative to the total amount of the propylene-ethylene block copolymer and the propylene-α olefin random copolymer, and the polyolefin-based resin film has a thermal shrinkage ratio in a longitudinal direction of 3% or more and 20% or less, a thermal shrinkage ratio in a rectangular direction to a width direction of 1% or less, and a yield stress in the longitudinal direction of 150 MPa or more and 250 MPa or less.

Method for producing thermoplastic elastomer composition

Provided is a method for producing a thermoplastic elastomer composition that can form a molded article having both good appearance and high stiffness. The method for producing a thermoplastic elastomer composition comprises the following first step and second step, wherein the produced thermoplastic elastomer composition contains 5 mass % or less of a mineral oil (C): first step: a step of melt-kneading polypropylene (A-1) and an ethylene-based copolymer rubber (B) in the presence of an organic peroxide, the polypropylene (A-1) being polypropylene of which 20° C. xylene insoluble fraction has an intrinsic viscosity [η.sub.cxis] of 0.1 dl/g or more and less than 1.5 dl/g; and second step: a step of further adding polypropylene (A-2) of which 20° C. xylene insoluble fraction has an intrinsic viscosity [η.sub.cxis] of 1.5 dl/g or more and 7 dl/g or less, and melt-kneading the resulting mixture.

METHOD FOR PRODUCING A PHASE DIFFERENCE FILM
20230241829 · 2023-08-03 · ·

A method for producing a phase difference film is provided. The phase difference film includes an orientation layer formed of a resin C having a negative intrinsic birefringence value. The resin C contains a block copolymer having a block (A) including as a main component a polymerization unit A having a negative intrinsic birefringence value and a block (B) including as a main component a polymerization unit B, and a weight fraction of the block (A) therein being 50% by weight or more and 90% by weight or less. The phase difference film has an NZ factor of greater than 0 and smaller than 1. The method comprising: forming a single layer film of the resin C; and causing phase separation of the resin C in the film, which includes a step of applying to the film a stress along a thickness direction thereof.

ACTINIC-RAY-CURABLE COATING COMPOSITION, CURED COATING FILM, COATED ARTICLE, AND METHOD FOR FORMING COATING FILM
20220119668 · 2022-04-21 · ·

An active energy ray-curable coating composition, includes the following components (A), (B), (C), and (D): (A) urethane (meth)acrylate having a polycarbonate skeleton and three or more polymerizable unsaturated groups in one molecule and having a weight average molecular weight in a range of 10,000 to 40,000; (B) urethane (meth)acrylate having a weight average molecular weight in a range of 1,000 or more and less than 10,000; (C) at least one compound selected from the group consisting of (c1) to (c3); and (D) a photopolymerization initiator.

SULFONATED POLYMERS AND COMPOSITIONS THEREOF
20230242698 · 2023-08-03 · ·

A composition is disclosed comprising a sulfonated styrenic block copolymer (SSBC) having an ion exchange capacity (IEC) of at least 0.5 meq/g; and at least one compound which reacts with the SSBC forming a cross-linked SSBC. The compound is selected from: (i) a cross-linking agent, (ii) a metal cation, and (iii) a non-sulfonated polymer. A film prepared from the composition containing the cross-linked SSBC has a toughness in wet state measured after 1 week of 1.2 to 8 MJ/m.sup.3; and a tensile stress in wet state measured after 1 week of 3.2 to 8 MPa, according to ASTM D412. The film can be used as a water 10 purification membrane or an antimicrobial protection layer.