C08J2369/00

Fiber reinforced thermoplastic resin molded article and fiber reinforced thermoplastic resin molding material

There are provided a fiber reinforced thermoplastic resin molded article including a thermoplastic resin [A], carbon fibers [B] and a polyrotaxane [C], the thermoplastic resin [A], the carbon fibers [B] and the polyrotaxane [C] being included in amounts of 40 to 98 parts by weight, 1 to 40 parts by weight and 1 to 20 parts by weight, respectively, based on 100 parts by weight of the total content of the thermoplastic resin [A], the carbon fibers [B] and the polyrotaxane [C], wherein the carbon fibers [B] included in the molded article have a weight-average fiber length [Lw] in a range of 0.5 to 20 mm, and a ratio ([C]/[B]) of the content of the polyrotaxane [C] to that of the carbon fibers [B] is 0.04 or more and 0.5 or less; and a thermoplastic resin molded article which has excellent impact strength and also has excellent conductivity.

METHOD FOR MANUFACTURING FIBER-CONTAINING SHEET AND FIBER-CONTAINING SHEET
20230053997 · 2023-02-23 ·

A method for manufacturing a fiber-containing sheet. In extruding resin into sheet form using a T-die, the extrusion from the T-die is performed with a first resin for forming a core layer and a second resin for forming both skin layers on both sides of the core layer laminated together. The first resin contains fiber material and the second resin does not contain fiber material.

RECOVERY AND REUSE OF ACTIVATORS AND INITIATORS FOLLOWING POLYCARBONATE SYNTHESIS

Methods of recovering and/or reusing activators and/or initiators following polycarbonate synthesis may include: contacting an amine compound with a carboxylic acid compound to form a first ammonium salt including a first ammonium cation associated with a carboxylate group; mixing the first ammonium salt with a reaction solution to obtain a first solution comprising a protonated polycarbonate, an activator adduct, and a second ammonium salt in which the second ammonium cation is associated with the carboxylate group from the first ammonium salt; contacting the first solution to precipitate the polycarbonate out of solution; separating the activator adduct from the precipitated polycarbonate and the second ammonium salt to obtain a second solution; separating the precipitated polycarbonate from the second ammonium salt to recover the second ammonium salt; and separating the activator adduct from the second solution to recover an activator capable of being reused for synthesizing additional polycarbonates.

NORMAL TEMPERATURE-CURABLE HARD COAT COMPOSITION
20220363851 · 2022-11-17 · ·

The present invention is a normal temperature-curable hard coat composition containing at least (A) a polysilazane compound having structures shown by the following formula (1) and (B) an alkoxysilane compound. The ratio of [a] the number of Si—H bonds in the polysilazane compound and [b] the number of alkoxy groups in the alkoxysilane compound is in a range of [b]/[a]=1.5 to 3. The present invention provides the normal temperature-curable hard coat composition which has excellent workability on outdoors, cures at normal temperature, improves surface hardness of plastic materials, and is used as an alternative material to glass.

##STR00001##

Process for preparing crosslinked polyolefin particles

Provided is a method of making a polymeric composition comprising (a) providing a dispersion of initial polyolefin particles in an aqueous medium, wherein the initial polyolefin particles comprise (i) one or more hydrocarbon polyolefin, (ii) one or more non-hydrocarbon polyolefin, and (iii) one or more crosslinking agent; (b) contacting the initial polyolefin particles with a peroxide initiator to form crosslinked polyolefin particles.

Protective film

A protective film of the present invention is used at the time of performing heat bending on the resin substrate, and includes a base material layer and a pressure sensitive adhesive layer adhered to a resin substrate, in which the base material layer includes a first layer which is positioned on an opposite side of the pressure sensitive adhesive layer and has a melting point of 150° C. or higher, and includes a second layer which is positioned on a pressure sensitive adhesive layer side and has a melting point of lower than 150° C., the pressure sensitive adhesive layer has a melting point of lower than 150° C., and MFR of a thermoplastic resin contained in the second layer, which is measured in conformity with JIS K7210, is in a range of 0.5 g/10 min to 4.0 g/10 min.

Transparent resin substrate

A transparent resin substrate composed of a light-transmitting resin base sheet, and an underlying layer, a hard coat layer, and an antireflection coating formed sequentially on the base sheet. The antireflection coating includes a medium refractive index layer on the hard coat layer, and a low refractive index layer on the medium refractive index layer. The underlying layer is a cured product of a hexa- or higher functional urethane acrylate monomer. The hard coat layer is a cured product of a hard coat layer composition containing a polymerizable monomer containing 50% by mass or more of a tri- or lower functional urethane acrylate monomer, silica particles, a silane coupling agent, and a metal chelate compound. The medium refractive index layer is a cured product of a medium refractive index layer composition. The low refractive index layer is a particle-free cured product of a low refractive index layer composition.

Sheet formed from carbon fiber reinforced thermoplastic resin, and production method of said sheet

A sheet formed from a carbon fiber reinforced thermoplastic resin with a simplified production process and excellent mechanical characteristics, and a production method of said sheet is provided. This sheet is formed from a carbon fiber reinforced thermoplastic resin that contains carbon fibers, dichloromethane, and a thermoplastic resin containing at least one of a polycarbonate resin and a polyarylate resin, and the content of the dichloromethane contained in the sheet is 10-10,000 ppm by mass.

CARBON FIBER REINFORCED THERMOPLASTIC SHEETS FOR EFFICIENT MICROWAVE HEATING WITH DISPERSED WAVY CARBON NANOTUBES

A non-woven carbon fiber reinforced thermoplastic (CFRTP) composite object is formed by the variable frequency microwave (VFM) irradiation of a mixed fiber sheet of thermoplastic fibers, carbon fibers and wavy carbon nanotubes (CNTs). The mixed fiber sheets are prepared from a slurry of the thermoplastic fibers, carbon fibers, and wavy CNTs such that the wavy CNTs contact the carbon fibers and thermoplastic fibers. Upon irradiation with VFM radiation, the wavy CNTs generate heat and transfer the heat to the thermoplastic fibers, causing melting of the thermoplastic to form the matrix of the CFRTP composite object. The mixed fiber sheets can be combined alone or with other sheets to form laminar composites that are molded into objects and heated by VFM irradiation.

Impact-resistant lightweight polymeric laminates

Bonded polymeric film laminates comprising core polymer film layers individually coated on at least one side with a heat fusible polymer layer and fusion bonded together by the application of heat and pressure at a temperature at which each heat fusible polymer coating bonds together adjacent core polymer film layers, where the melting point or softening temperature of the heat fusible polymer is at least 3° C. below that of the core layer polymer, and the lamination temperature is at or above the melting point or softening temperature of the heat fusible coating polymer, where the heat fusible polymer coating layers are thinner than the core polymer film layers, where the coated core polymer film layers are uniaxially stretched by 2× to 40×, and the stretched coated core polymer film layers are cross-plied. Methods for forming the laminates, coated films from which the laminates are formed, and articles formed from the laminates are also disclosed.