The present invention relates to a method for preparing a graft copolymer including polymerizing a conjugated diene-based monomer to prepare a small-size conjugated diene-based polymer; enlarging the small-size conjugated diene-based polymer to prepare a large-size conjugated diene-based polymer; and polymerizing the small-size conjugated diene-based polymer, the large-size conjugated diene-based polymer, an aromatic vinyl-based monomer and a vinyl cyan-based monomer to prepare a graft copolymer, wherein a weight ratio of the small-size conjugated diene-based polymer and the large-size conjugated diene-based polymer is 10:90 to 40:60 in preparing the graft copolymer.

The present invention relates to a method for preparing a graft copolymer including polymerizing a conjugated diene-based monomer to prepare a small-size conjugated diene-based polymer; enlarging the small-size conjugated diene-based polymer to prepare a large-size conjugated diene-based polymer; and polymerizing the small-size conjugated diene-based polymer, the large-size conjugated diene-based polymer, an aromatic vinyl-based monomer and a vinyl cyan-based monomer to prepare a graft copolymer, wherein a weight ratio of the small-size conjugated diene-based polymer and the large-size conjugated diene-based polymer is 10:90 to 40:60 in preparing the graft copolymer.

The present invention relates to a petroleum resin having the content of a volatile organic compound component of less than 100 wt ppm; and a hydrogenated petroleum resin having the content of a volatile organic compound component of less than 100 wt ppm.

The present invention relates to a petroleum resin having the content of a volatile organic compound component of less than 100 wt ppm; and a hydrogenated petroleum resin having the content of a volatile organic compound component of less than 100 wt ppm.

Cellulose nanocrystals (CNCs) from the plant Miscanthus Giganteus (MxG) and a matrix material are present in a composite composition. Impressive yields of MxG-CNCs are obtained through a combination of processing steps including base hydrolysis, bleaching and acid hydrolysis. MxG-CNCs are produced having high aspect ratios, are biorenewable and can be used for a wide range of applications such as nanofillers in composites.

The present invention relates to a polymer emulsion that is capable of exhibiting excellent rub fastness even when formed into a coating film or even when printed on a low-liquid absorbing printing medium, and a water-based ink for ink-jet printing which is excellent in ejection stability and antibleeding properties upon the ink-jet printing. The present invention provides [1] a polymer emulsion containing a polymer and water, in which the polymer is a random copolymer or a block copolymer which contains a constitutional unit derived from (a) at least one monomer selected from the group consisting of acrylic acid and methacrylic acid and a constitutional unit derived from (b) a hydrophobic vinyl monomer, and is in the form of a carboxy group-containing polymer having an acid value of 150 to 300 mgKOH/g; and the polymer emulsion further contains a formaldehyde-releasing compound; and [2] a water-based ink for ink-jet printing containing a pigment, the aforementioned polymer, a water-soluble organic solvent and water, in which the water-soluble organic solvent contains at least one compound selected from the group consisting of a polyhydric alcohol and a polyhydric alcohol alkyl ether, and a total content of the polyhydric alcohol and the polyhydric alcohol alkyl ether in the ink is not less than 18% by mass; and the water-based ink further contains a formaldehyde-releasing compound.

The present invention relates to a polymer emulsion that is capable of exhibiting excellent rub fastness even when formed into a coating film or even when printed on a low-liquid absorbing printing medium, and a water-based ink for ink-jet printing which is excellent in ejection stability and antibleeding properties upon the ink-jet printing. The present invention provides [1] a polymer emulsion containing a polymer and water, in which the polymer is a random copolymer or a block copolymer which contains a constitutional unit derived from (a) at least one monomer selected from the group consisting of acrylic acid and methacrylic acid and a constitutional unit derived from (b) a hydrophobic vinyl monomer, and is in the form of a carboxy group-containing polymer having an acid value of 150 to 300 mgKOH/g; and the polymer emulsion further contains a formaldehyde-releasing compound; and [2] a water-based ink for ink-jet printing containing a pigment, the aforementioned polymer, a water-soluble organic solvent and water, in which the water-soluble organic solvent contains at least one compound selected from the group consisting of a polyhydric alcohol and a polyhydric alcohol alkyl ether, and a total content of the polyhydric alcohol and the polyhydric alcohol alkyl ether in the ink is not less than 18% by mass; and the water-based ink further contains a formaldehyde-releasing compound.

Curable film-forming sol-gel compositions that are essentially free of inorganic oxide particles are provided. The compositions contain: a tetraalkoxysilane; a solvent component; and non-oxide particles, and further contain either i) a mineral acid or ii) an epoxy functional trialkoxysilane and a metal-containing catalyst. Coated articles demonstrating antiglare properties are also provided, comprising: (a) a substrate having at least one surface; and (b) a cured film-forming composition applied thereon, formed from a curable sol-gel composition comprising a silane and non-oxide particles. A method of forming an antiglare coating on a substrate is also provided. The method comprises: (a) applying a curable film-forming sol-gel composition on at least one surface of the substrate to form a coated substrate; and (b) subjecting the coated substrate to thermal conditions for a time sufficient to effect cure of the sol-gel composition and form a coated substrate with a sol-gel network layer having anti-glare properties.

Curable film-forming sol-gel compositions that are essentially free of inorganic oxide particles are provided. The compositions contain: a tetraalkoxysilane; a solvent component; and non-oxide particles, and further contain either i) a mineral acid or ii) an epoxy functional trialkoxysilane and a metal-containing catalyst. Coated articles demonstrating antiglare properties are also provided, comprising: (a) a substrate having at least one surface; and (b) a cured film-forming composition applied thereon, formed from a curable sol-gel composition comprising a silane and non-oxide particles. A method of forming an antiglare coating on a substrate is also provided. The method comprises: (a) applying a curable film-forming sol-gel composition on at least one surface of the substrate to form a coated substrate; and (b) subjecting the coated substrate to thermal conditions for a time sufficient to effect cure of the sol-gel composition and form a coated substrate with a sol-gel network layer having anti-glare properties.

The rubber composition for a tread comprises: 5 to 30 parts by mass of a carbon black, 95 parts by mass or more of silica, 25 parts by mass or more of a powder of an inorganic compound represented by a given formula (A) and having an average primary particle size of 10 m or less, and 70 parts by mass or more of a softening agent comprising 2 to 15 parts by mass of a coumarone-based resin, based on 100 parts by mass of a rubber component comprising 70% by mass or more of a styrene-butadiene rubber having a styrene content of from 20 to 50% by mass and a vinyl content of from 15 to 65%, and the tire has a tread composed of the rubber composition for a tread.