The present invention provides a thermoplastic resin composition including a first graft copolymer including a conjugated diene-based polymer, an alkyl (meth)acrylate-based monomer, an aromatic vinyl-based monomer, and a vinyl cyanide-based monomer; a second graft copolymer including an alkyl (meth)acrylate-based polymer, an aromatic vinyl-based monomer, a vinyl cyanide-based monomer, and an alkyl (meth)acrylate-based monomer; and a thermoplastic copolymer including an alkyl (meth)acrylate-based monomer, an aromatic vinyl-based monomer, and a vinyl cyanide-based monomer, wherein the first graft copolymer is included in an amount of 5 to 12% by weight, and the weight of the first graft copolymer is less than the weight of the second graft copolymer and at the same time less than the weight of the thermoplastic copolymer, and a molded article manufactured using the thermoplastic resin composition.

Provided is a pneumatic tire having both improved run-flat durability and excellent wet grip properties; the pneumatic tire including a rubber composition used in a tread part, and a rubber support layer having a gauge thickness in a specified range; the rubber composition including specified compounded amounts of natural rubber, a terminal-modified styrene-butadiene rubber, silica, and a thermoplastic resin, wherein the rubber composition is largely strain-dependent for the storage elastic modulus.

The present application relates to a chain extender masterbatch for PET extrusion foaming, preparation method therefor, and a use thereof. The masterbatch is mainly prepared by the following components in parts by weight: 5-30 parts of PMDA, 25-90 parts of PBT, 5-70 parts of POE+POE-g-GMA, in which POE accounts for 0-85% of POE+POE-g-GMA by weight; a melting temperature of PBT is 170-225° C. The preparation method includes melting and mixing the above components at a melting temperature of 180-230° C. and a screw speed of 100-500 rpm, and air cooling strand granulating or air cooling die face granulating. The masterbatch can be used in foaming processes of fiber grade PET, film grade PET, bottle grade PET, engineering plastic grade PET and recycled PET.

A thermoplastic resin composition including 100 parts by weight of a base resin including 0.5 to 45% by weight of a graft copolymer (A-1) including acrylate rubber having an average particle diameter of 50 to 150 nm, an aromatic vinyl compound, and a vinyl cyanide compound, 20 to 80% by weight of a graft copolymer (A-2) including acrylate rubber having an average particle diameter of 151 to 600 nm, an aromatic vinyl compound, and a vinyl cyanide compound, and 10 to 45% by weight of an α-methylstyrene-based copolymer (B) having a weight average molecular weight of 60,000 to 180,000 g/mol; and 0.5 to 10 parts by weight of an ultra-high molecular weight copolymer (C) having a weight average molecular weight of 1,000,000 to 12,000,000 g/mol. A method of preparing the thermoplastic resin composition and a molded article including the thermoplastic resin composition are also disclosed.

Disclosed are a thermoplastic resin composition, a method of preparing the same, and a molded article manufactured using the same. The thermoplastic resin composition includes 3 to 22% by weight of a graft copolymer (A-1) including an acrylate-based rubber having an average particle diameter of 200 to 400 nm, an aromatic vinyl compound, and a vinyl cyanide compound; 17 to 40% by weight of a graft copolymer (A-2) including an acrylate-based rubber having an average particle diameter of 50 to 199 nm, an aromatic vinyl compound, and a vinyl cyanide compound; 30 to 57% by weight of a copolymer (B) including a (meth)acrylic acid alkyl ester compound, an α-methyl styrene-based compound, and a vinyl cyanide compound; and 6 to 30% by weight of a polymethacrylate resin (C) (except for α-methyl styrene), wherein an average multi-axial impact strength is 22 J/mm or more.

Provided is a thermoplastic resin composition which includes: a first graft copolymer including a C.sub.4 to C.sub.10 alkyl (meth)acrylate-based monomer unit, an aromatic vinyl-based monomer unit, and a vinyl cyan-based monomer unit; a second graft copolymer including a C.sub.4 to C.sub.10 alkyl (meth)acrylate-based monomer unit, an aromatic vinyl-based monomer unit, and a vinyl cyan-based monomer unit; and a first styrene-based copolymer being a copolymer of a monomer mixture including a C.sub.1 to C.sub.3 alkyl-substituted styrene-based monomer, a vinyl cyan-based monomer, and a C.sub.1 to C.sub.3 alkyl (meth)acrylate-based monomer, wherein the first graft copolymer and the second graft copolymer have cores having mutually different average particle diameters. The thermoplastic resin composition is excellent in colorability, weather resistance, tensile strength, flexural strength, and impact strength.

A method for styling hair comprises placing the hair in a desired configuration and applying a hair styling composition to the hair. The hair styling composition comprises a powder of a multistage polymer of a soft polymer of Tg<40° C.; and a hard polymer having a Tg>40° C., and at least 10° C. higher than the Tg of the soft polymer wherein the hard polymer forms a complete or partial shell around the soft polymer the weight ratio of hard polymer to soft polymer being 1.01:1 to 2:1. After exposure to liquid water and drying at temperatures below 100° C., a maximum thermal transition temperature of the multistage polymer in an atmosphere of 0% relative humidity that differs by 20° C. or less from the maximum thermal transition temperature in an atmosphere of 75% relative humidity.

A thermoplastic resin composition can include 25 to 75% by weight of an alkyl acrylate-aromatic vinyl compound-vinyl cyanide compound graft copolymer (A) containing alkyl acrylate rubber having an average particle diameter of 50 to 120 nm; and 25 to 75% by weight of a (meth)acrylic acid alkyl ester compound-aromatic vinyl compound-vinyl cyanide compound non-graft copolymer (B). The thermoplastic resin composition has an alkyl acrylate coverage value (X) of 67% or more as calculated by Equation 1. A method of preparing the thermoplastic resin composition, and a molded article including the thermoplastic resin composition are also disclosed.

Provided is a rubber-containing graft polymer which is excellent in mechanical strength such as weld strength or impact strength, required as a rubber-containing graft polymer. A rubber-containing graft polymer (A) of the present invention is a rubber-containing graft polymer having a graft chain, in which when the rubber-containing graft polymer is mixed with an organic solvent and separated into an organic solvent insoluble component and an organic solvent soluble component, a caprolactone unit is contained in a graft chain contained in the organic solvent insoluble component.

A resin composition includes 20 wt % to 70 wt % of an ethylene polymer based on a total weight of the resin composition, wherein the ethylene polymer comprises a polar comonomer; and 30 wt % to 80 wt % of an acrylate phase based on the total weight of the resin composition, wherein the acrylate phase comprises units derived from butyl acrylate and units derived from methyl methacrylate.