A composition for dispersing multilayer polymers has an oligomer prepared from at least one alkyl (meth)acrylate monomer in the presence of a chain transfer agent. The oligomer has a number average molecular weight of less than 10,000 g/mol and a glass transition temperature, T.sub.g, as measured by DSC, less than a coagulation temperature of a composition comprising the oligomer and a multilayer polymer, wherein the coagulation temperature is based on an average particle diameter of 200 microns. A composition containing the oligomer and a multilayer polymer, such as an acrylic core-shell polymer or methacrylate butadiene styrene core-shell polymer, and a resin composition are also disclosed.

A composition for dispersing multilayer polymers has an oligomer prepared from at least one alkyl (meth)acrylate monomer in the presence of a chain transfer agent. The oligomer has a number average molecular weight of less than 10,000 g/mol and a glass transition temperature, T.sub.g, as measured by DSC, less than a coagulation temperature of a composition comprising the oligomer and a multilayer polymer, wherein the coagulation temperature is based on an average particle diameter of 200 microns. A composition containing the oligomer and a multilayer polymer, such as an acrylic core-shell polymer or methacrylate butadiene styrene core-shell polymer, and a resin composition are also disclosed.

Provided herein are methods of making a reactive particulate material by free radically polymerizing a single-cure resin to produce a polymer, the resin comprising: a reactive blocked polyurethane prepolymer, a reactive blocked polyurea prepolymer, a reactive blocked polyurethane-polyurea copolymer, or a combination thereof, wherein said polymerizing is carried out by dispersive polymerization (e.g., an emulsion, suspension or dispersion polymerization process), to form said reactive particulate material. Methods of use of the reactive particulate material and material sets including the same are also provided.

Provided herein are methods of recycling additively manufactured objects, which may include making a reactive particulate material by recycling preformed articles or recovered coating material. Methods of use of the reactive particulate material and material sets including the same are also provided.

Provided herein are methods of recycling additively manufactured objects, which may include making a reactive particulate material by recycling preformed articles or recovered coating material. Methods of use of the reactive particulate material and material sets including the same are also provided.

Provided herein are methods of making a reactive particulate material by free radically polymerizing a single-cure resin to produce a polymer, the resin comprising: a reactive blocked polyurethane prepolymer, a reactive blocked polyurea prepolymer, a reactive blocked polyurethane-polyurea copolymer, or a combination thereof, wherein said polymerizing is carried out by dispersive polymerization (e.g., an emulsion, suspension or dispersion polymerization process), to form said reactive particulate material. Methods of use of the reactive particulate material and material sets including the same are also provided.

A method to purify a polymer is disclosed. The method is part of a manufacturing process wherein a virgin polymer is produced from a polymerization process employing at least a monomer or a comonomer as a feedstock. The monomer or the comonomer is selected from the group consisting of organic polar monomers, inorganic monomers, vinyl aromatic monomers, conjugated dienes, and mixtures thereof. In the method, the polymer in solid, liquid or molten state is brought into contact with a fluid solvent or an extraction fluid in a supercritical state or near supercritical state. The contact is at controlled temperature and pressure, allowing the fluid solvent to diffuse into the polymer and extract the impurities intended to remove. The method can be used to remove at least 10%, or at least 20%, or at least 50% of the target impurity from the polymer.

A method to purify a polymer is disclosed. The method is part of a manufacturing process wherein a virgin polymer is produced from a polymerization process employing at least a monomer or a comonomer as a feedstock. The monomer or the comonomer is selected from the group consisting of organic polar monomers, inorganic monomers, vinyl aromatic monomers, conjugated dienes, and mixtures thereof. In the method, the polymer in solid, liquid or molten state is brought into contact with a fluid solvent or an extraction fluid in a supercritical state or near supercritical state. The contact is at controlled temperature and pressure, allowing the fluid solvent to diffuse into the polymer and extract the impurities intended to remove. The method can be used to remove at least 10%, or at least 20%, or at least 50% of the target impurity from the polymer.

The present invention relates to a composition, preferably a polycarbonate composition, for production of a thermoplastic moulding compound, comprising or consisting of polycarbonate and/or polyestercarbonate, two different rubber-modified vinyl copolymers in a weight ratio of 20:80 to 90:10, wherein both rubber-modified vinyl copolymers contain vinyl copolymer incorporated in the rubber particles as a separate disperse phase, and wherein one of the vinyl copolymers contains at least one alkyl (meth)acrylate, and to the moulding compound itself, to the use of the composition or moulding compound for production of moulded articles, and to the moulded articles themselves.

The present invention relates to a composition, preferably a polycarbonate composition, for production of a thermoplastic moulding compound, comprising or consisting of polycarbonate and/or polyestercarbonate, two different rubber-modified vinyl copolymers in a weight ratio of 20:80 to 90:10, wherein both rubber-modified vinyl copolymers contain vinyl copolymer incorporated in the rubber particles as a separate disperse phase, and wherein one of the vinyl copolymers contains at least one alkyl (meth)acrylate, and to the moulding compound itself, to the use of the composition or moulding compound for production of moulded articles, and to the moulded articles themselves.