Patent classifications
C08L59/00
POLYOXYMETHYLENE-BASED ALL-SOLID-STATE POLYMER ELECTROLYTE PREPARED BY IN-SITU RING-OPENING POLYMERIZATION AND APPLICATION
A polyoxymethylene-based all-solid-state polymer electrolyte prepared by in-situ ring-opening polymerization is used in forming an all-solid-state secondary lithium battery. A trioxymethylene monomer, an additive and lithium salt initiates in-situ ring-opening polymerization on a porous support material through a catalyst to form the all-solid-state polymer electrolyte, which has a thickness of 10 μm-800 μm, an ionic conductivity of 4×10.sup.−5 S/cm—8×10.sup.−3 S/cm at room temperature and an electrochemical window not lower than 4.2 V.
Production method of polyacetal resin composition
A method for producing a polyacetal resin composition which allows for suppression of formaldehyde generation from a molded article to an extremely low level, and stable suppression of mold deposits during molding. The polyacetal resin composition contains: 100 parts by mass of a polyacetal polymer (A); 0.01 to 0.50 parts by mass of an aliphatic carboxylic acid hydrazide (B); 0.001 to 0.50 parts by mass of a hydantoin compound having two hydrazinocarbonylalkyl groups (C); and 0.001 to 0.30 parts by mass of an alkaline earth metal salt of aliphatic carboxylic acid (D), wherein the total amount of the components (B) and (C) with respect to 100 parts by mass of the polyacetal polymer (A) is 0.03 to 0.55 parts by mass, and the polyacetal polymer (A) is a polyacetal copolymer obtained by copolymerizing trioxane as a principal monomer (a) with a cyclic ether having at least one carbon-carbon bond as a comonomer (b) using a heteropolyacid represented by general formula (1) as a polymerization catalyst (c) to obtain a reaction product, and subsequently adding a carbonate of an alkali metal element or alkaline earth metal element (d) to the reaction product to deactivate the polymerization catalyst (c).
Production method of polyacetal resin composition
A method for producing a polyacetal resin composition which allows for suppression of formaldehyde generation from a molded article to an extremely low level, and stable suppression of mold deposits during molding. The polyacetal resin composition contains: 100 parts by mass of a polyacetal polymer (A); 0.01 to 0.50 parts by mass of an aliphatic carboxylic acid hydrazide (B); 0.001 to 0.50 parts by mass of a hydantoin compound having two hydrazinocarbonylalkyl groups (C); and 0.001 to 0.30 parts by mass of an alkaline earth metal salt of aliphatic carboxylic acid (D), wherein the total amount of the components (B) and (C) with respect to 100 parts by mass of the polyacetal polymer (A) is 0.03 to 0.55 parts by mass, and the polyacetal polymer (A) is a polyacetal copolymer obtained by copolymerizing trioxane as a principal monomer (a) with a cyclic ether having at least one carbon-carbon bond as a comonomer (b) using a heteropolyacid represented by general formula (1) as a polymerization catalyst (c) to obtain a reaction product, and subsequently adding a carbonate of an alkali metal element or alkaline earth metal element (d) to the reaction product to deactivate the polymerization catalyst (c).
Production method of polyacetal resin composition
A method for producing a polyacetal resin composition which allows for suppression of formaldehyde generation from a molded article to an extremely low level, and stable suppression of mold deposits during molding. The polyacetal resin composition contains: 100 parts by mass of a polyacetal polymer (A); 0.01 to 0.50 parts by mass of an aliphatic carboxylic acid hydrazide (B); 0.001 to 0.50 parts by mass of a hydantoin compound having two hydrazinocarbonylalkyl groups (C); and 0.001 to 0.30 parts by mass of an alkaline earth metal salt of aliphatic carboxylic acid (D), wherein the total amount of the components (B) and (C) with respect to 100 parts by mass of the polyacetal polymer (A) is 0.03 to 0.55 parts by mass, and the polyacetal polymer (A) is a polyacetal copolymer obtained by copolymerizing trioxane as a principal monomer (a) with a cyclic ether having at least one carbon-carbon bond as a comonomer (b) using a heteropolyacid represented by general formula (1) as a polymerization catalyst (c) to obtain a reaction product, and subsequently adding a carbonate of an alkali metal element or alkaline earth metal element (d) to the reaction product to deactivate the polymerization catalyst (c).
Cellulose-containing gear
A gear is provided that has excellent continuous moldability for practical use, and both high slidability and high durability. The provided gear is a molded resin constructed of a resin composition comprising a thermoplastic resin (A) and cellulose nanofibers (B) with an average fiber diameter of 1000 nm or smaller, and having a number average molecular weight of the thermoplastic resin (A) in the range of 10,000 to 150,000, wherein a sliding surface of the gear with another gear teeth has an arithmetic mean surface roughness Sa of 3.0 .Math.m or lower.
Cellulose-containing gear
A gear is provided that has excellent continuous moldability for practical use, and both high slidability and high durability. The provided gear is a molded resin constructed of a resin composition comprising a thermoplastic resin (A) and cellulose nanofibers (B) with an average fiber diameter of 1000 nm or smaller, and having a number average molecular weight of the thermoplastic resin (A) in the range of 10,000 to 150,000, wherein a sliding surface of the gear with another gear teeth has an arithmetic mean surface roughness Sa of 3.0 .Math.m or lower.
POLYACETAL RESIN COMPOSITION, EXTRUSION-MOLDED ARTICLE, AND INJECTION-MOLDED ARTICLE
The present invention provides a polyacetal resin composition, which comprises a polyacetal resin, and which further comprises the following (A), (B) and (C), with respect to 100 parts by weight of the polyacetal resin: (A) 0.05 to 5.5 parts by weight of a low-density polyethylene having a melt flow rate of 1.0 to 50 g/10 minutes (190° C., 2.16 kg), (B) 0.05 to 2.0 parts by weight of a fatty acid compound (excluding calcium stearate), and (C) 0.001 to 1.0 part by weight of a layered double hydroxide represented by the following general formula (1): [(M.sup.2+)x(M.sup.3+).sub.y(OH).sub.2(x+y)](A.sup.n.Math.).sub.x/u.Math.z(H.sub.2O) (1) (wherein, in the general formula (1), M.sup.2+ represents a divalent metal ion, M.sup.3+ represents a trivalent metal ion, A.sup.n- represents an n-valent anion, wherein one or more of the anions are contained in the layered double hydroxide, x represents a number in the range of 0 < x ≤ 6.0, n represents 1, 2, or 3. and y and z each represent a number of 0 or greater).
POLYACETAL RESIN COMPOSITION, EXTRUSION-MOLDED ARTICLE, AND INJECTION-MOLDED ARTICLE
The present invention provides a polyacetal resin composition, which comprises a polyacetal resin, and which further comprises the following (A), (B) and (C), with respect to 100 parts by weight of the polyacetal resin: (A) 0.05 to 5.5 parts by weight of a low-density polyethylene having a melt flow rate of 1.0 to 50 g/10 minutes (190° C., 2.16 kg), (B) 0.05 to 2.0 parts by weight of a fatty acid compound (excluding calcium stearate), and (C) 0.001 to 1.0 part by weight of a layered double hydroxide represented by the following general formula (1): [(M.sup.2+)x(M.sup.3+).sub.y(OH).sub.2(x+y)](A.sup.n.Math.).sub.x/u.Math.z(H.sub.2O) (1) (wherein, in the general formula (1), M.sup.2+ represents a divalent metal ion, M.sup.3+ represents a trivalent metal ion, A.sup.n- represents an n-valent anion, wherein one or more of the anions are contained in the layered double hydroxide, x represents a number in the range of 0 < x ≤ 6.0, n represents 1, 2, or 3. and y and z each represent a number of 0 or greater).
POLYACETAL RESIN COMPOSITION, EXTRUSION-MOLDED ARTICLE, AND INJECTION-MOLDED ARTICLE
The present invention provides a polyacetal resin composition, which comprises a polyacetal resin, and which further comprises the following (A), (B) and (C), with respect to 100 parts by weight of the polyacetal resin: (A) 0.05 to 5.5 parts by weight of a low-density polyethylene having a melt flow rate of 1.0 to 50 g/10 minutes (190° C., 2.16 kg), (B) 0.05 to 2.0 parts by weight of a fatty acid compound (excluding calcium stearate), and (C) 0.001 to 1.0 part by weight of a layered double hydroxide represented by the following general formula (1): [(M.sup.2+)x(M.sup.3+).sub.y(OH).sub.2(x+y)](A.sup.n.Math.).sub.x/u.Math.z(H.sub.2O) (1) (wherein, in the general formula (1), M.sup.2+ represents a divalent metal ion, M.sup.3+ represents a trivalent metal ion, A.sup.n- represents an n-valent anion, wherein one or more of the anions are contained in the layered double hydroxide, x represents a number in the range of 0 < x ≤ 6.0, n represents 1, 2, or 3. and y and z each represent a number of 0 or greater).
Resin composition
The present disclosure is directed to provide a resin composition which enables production of a molded product generating less formaldehyde and having excellent appearance and weather resistance, and also achieves suppression of mold deposit during molding. Presently disclosed is a polyacetal resin composition comprising 100 parts by mass of a polyacetal resin (A); and 0.1 to 10 parts by weight of an aluminum pigment (B), the aluminum pigment (B) containing 0.1 to 2.0 mass % of particles with a particle diameter of 1 μm or less with respect to a total amount of the aluminum pigment (B), and a volume average particle size of the aluminum pigment (B) being 3 to 40 μm.