Compositions of at least one matrix polymer that may be a thermoplastic and/or curable polymer having at least one functional group for crosslinking for use in forming articles are disclosed as well as methods for making such articles, wherein the compositions and methods include a carbon nanostructure additive that is three-dimensional, branched and crosslinked. The resulting articles can in one embodiment provide a volume resistivity level of about 0.5 ohm-cm or less which are useful in applications requiring conductivity sufficient to provide electromagnetic interference shielding and/or radio frequency interference shielding. Other articles formed using compositions disclosed herein in other embodiments can demonstrate dissipative and/or quantum tunneling effects and so are useful as self-sensing pressure sensitive articles, such as self-sensing seals.

Compositions of at least one matrix polymer that may be a thermoplastic and/or curable polymer having at least one functional group for crosslinking for use in forming articles are disclosed as well as methods for making such articles, wherein the compositions and methods include a carbon nanostructure additive that is three-dimensional, branched and crosslinked. The resulting articles can in one embodiment provide a volume resistivity level of about 0.5 ohm-cm or less which are useful in applications requiring conductivity sufficient to provide electromagnetic interference shielding and/or radio frequency interference shielding. Other articles formed using compositions disclosed herein in other embodiments can demonstrate dissipative and/or quantum tunneling effects and so are useful as self-sensing pressure sensitive articles, such as self-sensing seals.

The invention provides a method of preparing an electrically conductive polymeric material. The method comprises providing a polymeric network having a short chain conductive polymer dispersed in the polymeric network and electropolymerising a conductive polymer within the polymeric network. Also described is a free standing flexible electrically conductive polymeric material comprising a conductive polymer within a polymeric network.

The invention provides a method of preparing an electrically conductive polymeric material. The method comprises providing a polymeric network having a short chain conductive polymer dispersed in the polymeric network and electropolymerising a conductive polymer within the polymeric network. Also described is a free standing flexible electrically conductive polymeric material comprising a conductive polymer within a polymeric network.

A polybenzodifuran ladder polymer is disclosed.

A polybenzodifuran ladder polymer is disclosed.

A three-dimensional printing ink that has a viscosity suitable for three-dimensional printing, and improved performance.

A three-dimensional printing ink that has a viscosity suitable for three-dimensional printing, and improved performance.

An oligomer, composition, and composite material employing the same are provided. The oligomer can be a reaction product of a reactant (a) and a reactant (b). The reactant (a) is a reaction product of a reactant (c) and a reactant (d). The reactant (b) can be

##STR00001##

or a combination thereof, wherein a is 0 or 1, and R.sup.1 is independently hydrogen

##STR00002##

or and wherein b is 0-6; c is 0 or 1; and, d is 0-6. The reactant (c) is

##STR00003##

wherein R.sup.2 is C.sub.5-10 alkyl group. The reactant (d) is

##STR00004##

wherein e is 0-10.

An oligomer, composition, and composite material employing the same are provided. The oligomer can be a reaction product of a reactant (a) and a reactant (b). The reactant (a) is a reaction product of a reactant (c) and a reactant (d). The reactant (b) can be

##STR00001##

or a combination thereof, wherein a is 0 or 1, and R.sup.1 is independently hydrogen

##STR00002##

or and wherein b is 0-6; c is 0 or 1; and, d is 0-6. The reactant (c) is

##STR00003##

wherein R.sup.2 is C.sub.5-10 alkyl group. The reactant (d) is

##STR00004##

wherein e is 0-10.