Patent classifications
C08L69/00
Polycarbonate-polyorganosiloxane copolymer, polycarbonate resin composition including same, and molded product thereof
Provided is a polycarbonate-polyorganosiloxane copolymer including polycarbonate blocks (A-1) each formed of a specific repeating unit and polyorganosiloxane blocks (A-2) each containing a specific repeating unit, wherein the polycarbonate-polyorganosiloxane copolymer satisfies the following expression (F1a):
15≤wM1 (F1a)
wherein wM1 represents the average content of the polyorganosiloxane blocks (A-2) in polycarbonate-polyorganosiloxane copolymers each having a molecular weight determined by using a polycarbonate as a conversion reference of from 56,000 or more to 200,000 or less among polycarbonate-polyorganosiloxane copolymers obtained through the separation of the polycarbonate-polyorganosiloxane copolymer by gel permeation chromatography.
Polycarbonate-polyorganosiloxane copolymer, polycarbonate resin composition including same, and molded product thereof
Provided is a polycarbonate-polyorganosiloxane copolymer including polycarbonate blocks (A-1) each formed of a specific repeating unit and polyorganosiloxane blocks (A-2) each containing a specific repeating unit, wherein the polycarbonate-polyorganosiloxane copolymer satisfies the following expression (F1a):
15≤wM1 (F1a)
wherein wM1 represents the average content of the polyorganosiloxane blocks (A-2) in polycarbonate-polyorganosiloxane copolymers each having a molecular weight determined by using a polycarbonate as a conversion reference of from 56,000 or more to 200,000 or less among polycarbonate-polyorganosiloxane copolymers obtained through the separation of the polycarbonate-polyorganosiloxane copolymer by gel permeation chromatography.
Thermoplastic resin composition and molded article using same
The present invention relates to a thermoplastic resin composition and a molded article using same, the thermoplastic resin composition comprising: (D) 4 to 12 parts by weight of a methyl methacrylate-butadiene-styrene graft copolymer; (E) 0.1 to 0.3 parts by weight of a phosphate-based heat stabilizer; and (F) 25 to 35 parts by weight of an inorganic filler having an average particle diameter (D50) of 1 to 5 μm, with respect to 100 parts by weight of a basic resin including (A) 65 to 75 wt % of a polycarbonate, (B) 20 to 30 wt % of an aromatic vinyl-cyanized vinyl copolymer; and (C) 1 to 10 wt % of a polyethylene terephthalate resin.
Thermoplastic resin composition and molded article using same
The present invention relates to a thermoplastic resin composition and a molded article using same, the thermoplastic resin composition comprising: (D) 4 to 12 parts by weight of a methyl methacrylate-butadiene-styrene graft copolymer; (E) 0.1 to 0.3 parts by weight of a phosphate-based heat stabilizer; and (F) 25 to 35 parts by weight of an inorganic filler having an average particle diameter (D50) of 1 to 5 μm, with respect to 100 parts by weight of a basic resin including (A) 65 to 75 wt % of a polycarbonate, (B) 20 to 30 wt % of an aromatic vinyl-cyanized vinyl copolymer; and (C) 1 to 10 wt % of a polyethylene terephthalate resin.
Thermoplastic resin composition and molded article using same
The present invention relates to a thermoplastic resin composition and a molded article using same, the thermoplastic resin composition comprising: (D) 4 to 12 parts by weight of a methyl methacrylate-butadiene-styrene graft copolymer; (E) 0.1 to 0.3 parts by weight of a phosphate-based heat stabilizer; and (F) 25 to 35 parts by weight of an inorganic filler having an average particle diameter (D50) of 1 to 5 μm, with respect to 100 parts by weight of a basic resin including (A) 65 to 75 wt % of a polycarbonate, (B) 20 to 30 wt % of an aromatic vinyl-cyanized vinyl copolymer; and (C) 1 to 10 wt % of a polyethylene terephthalate resin.
NdFeB POLYMER MAGNET COMPOSITE INCLUDING POLYCARBONATE MATRIX AND PROCESSING THEREOF
Polymer magnet composites including NdFeB in a polycarbonate (PC) binder matrix are processed using processes including batch mixing and twin screw extrusion. One method includes adding PC to a compartment of a batch mixer and mixing the PC while the compartment is at a temperature greater than a flow temperature of the PC, to form a mixed PC material. The method also includes adding a NdFeB magnetic material to the compartment with the mixed PC material in four batches while the compartment is at the temperature greater than the flow temperature of the PC to form a mixed PC and NdFeB magnetic material, wherein each batch is mixed in the compartment for 1 to 3 minutes before the next batch is added. In addition, a total mixing time is 6 to 12 minutes, and the compartment includes an inert atmosphere. Other embodiments are described and claimed.
NdFeB POLYMER MAGNET COMPOSITE INCLUDING POLYCARBONATE MATRIX AND PROCESSING THEREOF
Polymer magnet composites including NdFeB in a polycarbonate (PC) binder matrix are processed using processes including batch mixing and twin screw extrusion. One method includes adding PC to a compartment of a batch mixer and mixing the PC while the compartment is at a temperature greater than a flow temperature of the PC, to form a mixed PC material. The method also includes adding a NdFeB magnetic material to the compartment with the mixed PC material in four batches while the compartment is at the temperature greater than the flow temperature of the PC to form a mixed PC and NdFeB magnetic material, wherein each batch is mixed in the compartment for 1 to 3 minutes before the next batch is added. In addition, a total mixing time is 6 to 12 minutes, and the compartment includes an inert atmosphere. Other embodiments are described and claimed.
POLYCARBONATE RESIN COMPOSITION AND RESIN MOLDED BODY
A resin composition, including an aromatic polycarbonate resin, wherein when colorimetry is performed by using a molded body for optical characteristic measurement formed of the resin composition, the molded body including an entering portion from which light enters, an emitting portion from which the entered light is emitted, and a light-guiding portion configured to guide the light that has entered from the entering portion to the emitting portion, and the light-guiding portion including an optical path having such a curvature that the entered light is totally reflected, and by using a white light-emitting diode as a light source, a difference (Y2−Y1) between a y(Y1) of the molded body for optical characteristic measurement in a CIE 1931 color system at a position of a light-guiding path distant from the entering portion by 125 mm.
POLYCARBONATE RESIN COMPOSITION AND RESIN MOLDED BODY
A resin composition, including an aromatic polycarbonate resin, wherein when colorimetry is performed by using a molded body for optical characteristic measurement formed of the resin composition, the molded body including an entering portion from which light enters, an emitting portion from which the entered light is emitted, and a light-guiding portion configured to guide the light that has entered from the entering portion to the emitting portion, and the light-guiding portion including an optical path having such a curvature that the entered light is totally reflected, and by using a white light-emitting diode as a light source, a difference (Y2−Y1) between a y(Y1) of the molded body for optical characteristic measurement in a CIE 1931 color system at a position of a light-guiding path distant from the entering portion by 125 mm.
ANTISTATIC AGENT, ANTISTATIC RESIN COMPOSITION, AND MOLDED PRODUCT
An object of the present invention is to provide an antistatic agent which imparts excellent antistatic properties to thermoplastic resins. The antistatic agent of the present invention contains a block polymer (A) having a block of a polyamide (a) and a block of a hydrophilic polymer (b) as structure units; and an amide-forming monomer (c), wherein a weight ratio of the amide-forming monomer (c) to the block polymer (A), i.e., amide-forming monomer (c)/block polymer (A), is 2/98 to 12/88.