A core/shell polymer material suitable for three-dimensional printing is provided. The core/shell polymer material may include at least one amorphous polymer as a core particle and at least one semicrystalline polymer as a shell material surrounding the core particle.

A core/shell polymer material suitable for three-dimensional printing is provided. The core/shell polymer material may include at least one amorphous polymer as a core particle and at least one semicrystalline polymer as a shell material surrounding the core particle.

A method for producing an aqueous polyimide precursor solution composition includes reacting a tetracarboxylic dianhydride and a diamine in the presence of an imidazole, using water as a reaction solvent to provide an aqueous polyimide precursor solution composition. The polyamic acid and the imidazole are dissolved in the water. A concentration of the polyamic acid is 5 to 45 wt %, The imidazole is an imidazole having two or more alkyl groups as substituents. An amount of the imidazole is 1.6 moles or more per mole of the tetracarboxylic dianhydride, and a concentration of the imidazole compound based on a sum of the imidazole compound and the water is 9.47 wt % or less. The diamine component includes a diamine having a solubility in water at 25° C. of 0.1 g/L or more.

A method for producing an aqueous polyimide precursor solution composition includes reacting a tetracarboxylic dianhydride and a diamine in the presence of an imidazole, using water as a reaction solvent to provide an aqueous polyimide precursor solution composition. The polyamic acid and the imidazole are dissolved in the water. A concentration of the polyamic acid is 5 to 45 wt %, The imidazole is an imidazole having two or more alkyl groups as substituents. An amount of the imidazole is 1.6 moles or more per mole of the tetracarboxylic dianhydride, and a concentration of the imidazole compound based on a sum of the imidazole compound and the water is 9.47 wt % or less. The diamine component includes a diamine having a solubility in water at 25° C. of 0.1 g/L or more.

The invention relates to the use of at least one catalyst, at least one copper heat stabiliser and at least one oligo- or poly-carbodiimide with a matrix including at least one polyamide, in order to form a composition that has a good melt viscosity and is stable during transformation, in particular during extrusion.

The invention relates to the use of at least one catalyst, at least one copper heat stabiliser and at least one oligo- or poly-carbodiimide with a matrix including at least one polyamide, in order to form a composition that has a good melt viscosity and is stable during transformation, in particular during extrusion.

The invention relates to the use of at least one catalyst, at least one copper heat stabiliser and at least one oligo- or poly-carbodiimide with a matrix including at least one polyamide, in order to form a composition that has a good melt viscosity and is stable during transformation, in particular during extrusion.

The invention relates to a noncrosslinked block copolymer foam, comprising at least one rigid block and at least one flexible block, in which the copolymer includes at least one carboxylic acid chain end blocked with a polycarbodiimide. The invention also relates to a process for manufacturing this foam and to articles manufactured therefrom.

The polycarbodiimide composition is a reaction product of polyisocyanate having a primary isocyanate group with alcohol, wherein the alcohol contains at least one oxyethylene-containing alcohol containing an oxyethylene group, and at least one oxyethylene-noncontaining alcohol containing no oxyethylene group, the at least one oxyethylene-noncontaining alcohol has a solubility parameter of 11.20 (cal/cm.sup.3).sup.1/2 or less.

The polycarbodiimide composition is a reaction product of polyisocyanate having a primary isocyanate group with alcohol, wherein the alcohol contains at least one oxyethylene-containing alcohol containing an oxyethylene group, and at least one oxyethylene-noncontaining alcohol containing no oxyethylene group, the at least one oxyethylene-noncontaining alcohol has a solubility parameter of 11.20 (cal/cm.sup.3).sup.1/2 or less.