A hot melt adhesive film, and a preparation method, use, and an organosilicon polymer thereof are provided. The hot melt adhesive film includes: an inner layer, which is a polyolefin elastomer (POE); outer layers, which are an ethylene-vinyl acetate (EVA) copolymer on two surfaces of the inner layer; and intermediate layers, which are an organosilicon polymer between the inner layer and the outer layers. As intermediate layers, the organosilicon polymer plays the role of connection and transition, improves a bonding force between EVA and POE layers, and improves the stability of the hot melt adhesive film during long-term use. The hot melt adhesive film can be used as a packaging material for solar panels, touch screens, and the like.

A masterbatch having functionalized silicone with an epoxy group or a secondary amine group as a slip additive, the polyethylene compound that the silicone-containing masterbatch has been let down into, and the plastic articles and films from such compounds having improved slip properties are disclosed. The improved slip properties are evidenced by essentially no migration of the slip additive 12 weeks after manufacturing and a dynamic coefficient of friction value of less than 0.4 and a static coefficient of friction 0.5 or less as measured within the first day of manufacturing according to the ASTM D1894-01 method.

The invention relates to a process of preparing a polyolefin polylactic acid polymer blend comprising the steps of i) providing a polyolefin selected from polyethylene, polypropylene, and mixtures and copolymers thereof, ii) providing polylactic acid, iii) providing a polyolefin selected from polyethylene, polypropylene, and mixtures and copolymers thereof grafted with at least one epoxide-functional monomer, iv) providing a polylactic acid grafted with at least one carboxylic acid or carboxylic anhydride functional monomer, v) mixing the components i) to iv) at elevated temperature in a range from 150° C. to 260° C., and wherein component i) is provided in an amount of 5.0 to 50.0% by weight, component ii) is provided in an amount of 40.0 to 90.0% by weight, component iii) is provided in an amount of 1.0 to 20.0% by weight, and component iv) is provided in an amount of 1.0 to 15.0% by weight, calculated on the sum of components i) to iv).

Stabilized compositions having an organic material to be stabilized and a resin masterbatch system provided as closed end pellets are provided herein, along with processes for producing stabilized articles.

Disclosed herein are composite masterbatch granules containing reprocessed PET derived from recycled PET bottles, a method for making the same, and a use of the same in a foamed shoe material. Recycled PET is melted and mixed with EVA and a compatibilizer until they form a new polymer alloy through chemical modification, and the polymer alloy is processed with a high-torque extruder to produce the composite masterbatch granules. The composite masterbatch granules can be further mixed with EVA and a thermoplastic elastic material in order to make a shoe material by a foaming and molding process. The disclosure is intended to contribute to the recycling and reuse of waste PET so as to reduce carbon dioxide emissions, protect the environment, and lower the demand for virgin PET polymer materials and hence for petrochemical materials in general.

TABLE-US-00001 TABLE 3 Z-axis X-axis dimension, dimension, i.e., i.e., Type of raw Measuring width thickness material point (mm) (mm) r-PET #1 17.0 221 Injection-molded #2 16.5 221 in the modified #3 16.3 219 mold EVA #1 16.7 220 EVA molded in #2 16.3 220 the original #3 16.0 219 mold Conclusion: Z- and X-axis data resulting from the modified mold are similar to those produced by molding EVA in the original mold.

A method for preparing a vulcanizable composition of matter, the method comprising mixing rubber, silica, silica coupling agent, a strong base, and nicotinamide to form a masterbatch, introducing a curative to the masterbatch, and mixing the curative into the masterbatch to form a vulcanizable composition of matter.

The present invention provides a thermoplastic elastomer composition containing: (A-1) a crosslinked ethylene copolymer containing monomer units derived from ethylene and monomer units derived from propylene and/or α-olefins having 4 to 10 carbon atoms, (B) a propylene polymer containing monomer units derived from propylene and having a content of the monomer units derived from propylene of greater than 50% by weight, and (E) an inorganic filler having an average particle diameter of less than 1.0 μm. In the thermoplastic elastomer composition, the content of the component (E) is 10% by weight to 23% by weight and the Shore A durometer hardness of the thermoplastic elastomer composition is 30 to 99. Molded articles formed of the thermoplastic elastomer composition are superior in adhesiveness to thermoplastic elastomer molded articles.

Provided is a rubber composition for tires having low tan δ at approximately 60° C. and excellent fracture energy at approximately 25° C. Included is a rubber composition for tires, containing a rubber component including an isoprene-based rubber, the rubber composition having a correlation length Ξ.sub.b of 55 nm or less as determined by fitting the following Equations 1 to 6 to a scattering intensity curve I(q) obtained by X-ray scattering analysis or neutron scattering analysis: $\begin{array}{cc}{I}_{\left(q\right)}=\frac{A}{1+q^2{\xi }^2}+\frac{B}{{\left(1+q^2{\Xi }_b^2\right)}^2}+\frac{C}{{\left(1+q^2{\Xi }_c^2\right)}^2}& (\mathrm{Equation}\end{array}$

According to the process for preparing a vulcanized rubber composition of the invention comprising (a) a step of preparing a master batch comprising a modified conjugated diene polymer and silica, (b) a step of preparing a master batch comprising an isoprene rubber and silica, (c) a step of kneading the master batch obtained in (a) and the master batch obtained in (b), and (d) a step of vulcanizing a kneaded product obtained in (c), wherein the obtained vulcanized rubber composition comprises a phase A comprising a modified conjugated diene polymer and a phase B comprising an isoprene rubber, which are incompatible with each other, an abundance ratio α of silica in the phase A satisfies 0.5≦α≦0.9 (Relation 1), and a proportion β of the modified conjugated diene polymer satisfies 0.4≦β≦0.8 (Relation 2) it is possible to improve performance on ice and abrasion resistance and to provide a vulcanized rubber composition having excellent performance on ice and abrasion resistance, and a studless tire with a tread made using the same.

The present invention provides a process for making a silica masterbatch that contains hydrophobated silica, solution-made rubber and emulsion-made rubber. Hydrophobated silica is mixed into a latex emulsion. Solution-rubber crumb in an aqueous suspension is mixed into the latex emulsion, which is coagulated, and a crumb is recovered, further homogenized, dried and baled to yield the silica masterbatch. A well-dispersed mixture of hydrophobated silica and emulsion-made rubber is added into a steam distillation step of a solution-rubber process from which a silica masterbatch is recovered. The emulsion-made rubber can be omitted to make a silica masterbatch of solution rubber and silica without emulsion rubber. The silica masterbatch has physical properties similar to those found in a comparable dry-mixed composition, but the silica masterbatch can be incorporated more easily and less expensively into tires and other rubber products than the dry-mixed composition.