Patent classifications
C09B1/00
Organic electroluminescent element
An organic EL device includes a pair of electrodes and an organic compound layer between pair of electrodes. The organic compound layer includes an emitting layer including a first material, a second material and a third material, in which singlet energy EgS(H) of the first material, singlet energy EgS(H2) of the second material, and singlet energy EgS(D) of the third material satisfy a specific relationship.
Electrowetting element
Electrowetting element including a compound comprising a plurality of colorant moieties and a linker. The plurality of colorant moieties includes a first colorant moiety having a first net dipole and a second colorant moiety having a second net dipole. The plurality of colorant moieties are linked by and disposed around the linker so that the first net dipole and the second net dipole at least partially cancel each other.
NOVEL IN-VIVO PROBE FOR REAL TIME LONGITUDINAL MONITORING OF INDUCIBLE NITRIC-OXIDE SYNTHASE IN LIVING CELLS AND ANIMALS
The present disclosure relates to an in vivo fluorescent or radioactive probe represented by a compound of formula I which is capable of longitudinal imaging of inducible nitric oxide synthase (iNOS) expression in living cells and living animals on a real time basis. The probe of the present disclosure can exhibit specific and high affinity binding to the iNOS enzyme with reduced enzyme inhibitory property and also enables longitudinal monitoring of iNOS expression along with its activity or NO production in a same experimental subject throughout the progression of a physiological or disease process without employing separate subjects as controls and experimental. The present disclosure further provides a rapid and inexpensive real time method for visualizing iNOS expression and its activity in living cells and living animals precisely, conveniently and reversibly along with simultaneous in vivo imaging of its catalytic product, nitric oxide (NO) in live physiological settings.
Water soluble fluorescent or colored dyes and methods for their use
Compounds useful as fluorescent or colored dyes are disclosed. The compounds have the following structure (I): including stereoisomers, salts and tautomers thereof, wherein R.sup.1, R.sup.2, R.sup.3, L.sup.1, L.sup.2, L.sup.3, L.sup.4, L.sup.5, L.sup.6, M.sup.1, M.sup.2, A, q, w and n are as defined herein. Methods associated with preparation and use of such compounds are also provided. ##STR00001##
Water soluble fluorescent or colored dyes and methods for their use
Compounds useful as fluorescent or colored dyes are disclosed. The compounds have the following structure (I): including stereoisomers, salts and tautomers thereof, wherein R.sup.1, R.sup.2, R.sup.3, L.sup.1, L.sup.2, L.sup.3, L.sup.4, L.sup.5, L.sup.6, M.sup.1, M.sup.2, A, q, w and n are as defined herein. Methods associated with preparation and use of such compounds are also provided. ##STR00001##
Organic electroluminescent element and electronic device
An organic EL device with high emission efficiency, an electronic equipment including the organic EL device, and a compound providing the organic EL device are provided. The compound is represented by formula (1): ##STR00001##
wherein Ar.sup.1 represents a substituted or unsubstituted naphthalene ring; the substituent on the naphthalene ring is at least one selected from a fluorine atom, a cyano group, an alkyl group, a cycloalkyl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group, a group represented by Si(R.sub.101)(R.sub.102)(R.sub.103), and a group represented by ZR.sup.a; R.sup.1 and R.sup.2 each independently represent a hydrogen atom, an alkyl group, a cycloalkyl group, a group represented by Si(R.sub.101)(R.sub.102)(R.sub.103), an aryl group, or a heteroaryl group; R.sup.11 to R.sup.18 each independently represent a hydrogen atom, a fluorine atom, a cyano group, an alkyl group, a cycloalkyl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group, a group represented by Si(R.sub.101)(R.sub.102)(R.sub.103), or a group represented by ZR.sup.a; each Z represents a single bond, an arylene group, a heteroarylene group, or a divalent linking group in which 2 to 4 groups selected from the above groups are linked together; R.sup.a represents a group represented by N(R.sub.104)(R.sub.105), an aryl group, or a heteroaryl group; and R.sub.101 to R.sub.105 each represent a hydrogen atom, an alkyl group, a cycloalkyl group, aryl group, or a heteroaryl group; provided that at least one selected from the substituent on the naphthalene ring and R.sup.11 to R.sup.18 represents a group represented by ZR.sup.a.
Organic electroluminescent element and electronic device
An organic EL device with high emission efficiency, an electronic equipment including the organic EL device, and a compound providing the organic EL device are provided. The compound is represented by formula (1): ##STR00001##
wherein Ar.sup.1 represents a substituted or unsubstituted naphthalene ring; the substituent on the naphthalene ring is at least one selected from a fluorine atom, a cyano group, an alkyl group, a cycloalkyl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group, a group represented by Si(R.sub.101)(R.sub.102)(R.sub.103), and a group represented by ZR.sup.a; R.sup.1 and R.sup.2 each independently represent a hydrogen atom, an alkyl group, a cycloalkyl group, a group represented by Si(R.sub.101)(R.sub.102)(R.sub.103), an aryl group, or a heteroaryl group; R.sup.11 to R.sup.18 each independently represent a hydrogen atom, a fluorine atom, a cyano group, an alkyl group, a cycloalkyl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group, a group represented by Si(R.sub.101)(R.sub.102)(R.sub.103), or a group represented by ZR.sup.a; each Z represents a single bond, an arylene group, a heteroarylene group, or a divalent linking group in which 2 to 4 groups selected from the above groups are linked together; R.sup.a represents a group represented by N(R.sub.104)(R.sub.105), an aryl group, or a heteroaryl group; and R.sub.101 to R.sub.105 each represent a hydrogen atom, an alkyl group, a cycloalkyl group, aryl group, or a heteroaryl group; provided that at least one selected from the substituent on the naphthalene ring and R.sup.11 to R.sup.18 represents a group represented by ZR.sup.a.
AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME
Provided are: an aromatic amine derivative in which a terminal substituent such as a dibenzofuran ring or a dibenzothiophene ring is bonded to a nitrogen atom directly or through an arylene group or the like; an organic electroluminescence device including an organic thin film layer formed of one or more layers including a light emitting layer and interposed between a cathode and an anode in which a layer of the organic thin film layer contains the aromatic amine derivative by itself or as a component of a mixture, and the device has a long lifetime and high luminous efficiency; and an aromatic amine derivative for realizing the device.
AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME
Provided are: an aromatic amine derivative in which a terminal substituent such as a dibenzofuran ring or a dibenzothiophene ring is bonded to a nitrogen atom directly or through an arylene group or the like; an organic electroluminescence device including an organic thin film layer formed of one or more layers including a light emitting layer and interposed between a cathode and an anode in which a layer of the organic thin film layer contains the aromatic amine derivative by itself or as a component of a mixture, and the device has a long lifetime and high luminous efficiency; and an aromatic amine derivative for realizing the device.
Carboxylate-bridged binuclear iron-sulfur clusters fluorescent probe, preparation method and application thereof
The present invention provides a carboxylate-bridged binuclear iron-sulfur clusters fluorescent probe having the structure of Formula I. The preparation method comprises the following steps: anthracenylmethanamine and p-methoxycarbonylphenyl isocyanate have an addition reaction to get a substitutional methyl benzoate, which is hydrolyzed to get a corresponding carboxylic acid; react the resulting carboxylic acid with alkali to get carboxylate, and then coordinate with binuclear iron precursor to obtain the fluorescent probe. Compared with the prior art, the invention firstly provides the carboxylate-bridged binuclear iron-sulfur clusters of metal complex which similar to the central structure of bio-enzyme. The metal complex, as a fluorescent probe, has good selectivity to the fluorinion detection. The fluorescence titration experiment is simple and easy to operate and the fluorescence changes are sensitive. ##STR00001##