The invention provides an anthracene-based organic dye and a preparation method thereof. The organic dye provided by the invention has a structure of formula (I) or formula (II), wherein R.sub.a, R.sub.b, and R.sub.2-1 to R.sub.2-4 are as defined herein. The organic dye provided by the invention is obtained by modifying an anthracene with R.sub.a and R.sub.b or modifying anthracene-based groups decorated with an aryl group or a heteroaryl group with R.sub.a and R.sub.b, thereby the power conversion efficiency of a dye sensitized solar cell is significantly improved when the organic dye prepared according to the present invention is applied in a dye-sensitized solar cell. Furthermore, the preparation method of the organic dye according to the present invention is quite simple together with abundant raw materials and low cost, making it possible to be commercialized.

The invention provides an anthracene-based organic dye and a preparation method thereof. The organic dye provided by the invention has a structure of formula (I) or formula (II), wherein R.sub.a, R.sub.b, and R.sub.2-1 to R.sub.2-4 are as defined herein. The organic dye provided by the invention is obtained by modifying an anthracene with R.sub.a and R.sub.b or modifying anthracene-based groups decorated with an aryl group or a heteroaryl group with R.sub.a and R.sub.b, thereby the power conversion efficiency of a dye sensitized solar cell is significantly improved when the organic dye prepared according to the present invention is applied in a dye-sensitized solar cell. Furthermore, the preparation method of the organic dye according to the present invention is quite simple together with abundant raw materials and low cost, making it possible to be commercialized.

A dye-doped laser protective film is disclosed, comprising a polymer layer A and a polymer layer B. The polymer molecules in the polymer layer A are arranged in a left-handed helical structure which can reflect a left-handed polarized laser. The polymer molecules in the polymer layer B are arranged in a right-handed helical structure which can reflect a right-handed polarized laser. The combination of the polymer layer having the left-handed helical structure and the polymer layer having the right-handed helical structure can completely reflect circularly polarized light. In addition, the dye can absorb incident laser, so as to expand the protection angle of the laser protective film. The dye-doped laser protective film of the present disclosure has a simple manufacturing process, large protection angle and good flexibility, and can refit existing devices. Thus, the dye-doped laser protective film of the present disclosure has a good application prospect in many fields such as laser goggles, window films and the like.

A dye-doped laser protective film is disclosed, comprising a polymer layer A and a polymer layer B. The polymer molecules in the polymer layer A are arranged in a left-handed helical structure which can reflect a left-handed polarized laser. The polymer molecules in the polymer layer B are arranged in a right-handed helical structure which can reflect a right-handed polarized laser. The combination of the polymer layer having the left-handed helical structure and the polymer layer having the right-handed helical structure can completely reflect circularly polarized light. In addition, the dye can absorb incident laser, so as to expand the protection angle of the laser protective film. The dye-doped laser protective film of the present disclosure has a simple manufacturing process, large protection angle and good flexibility, and can refit existing devices. Thus, the dye-doped laser protective film of the present disclosure has a good application prospect in many fields such as laser goggles, window films and the like.

An organic EL device includes a pair of electrodes and an organic compound layer between pair of electrodes. The organic compound layer includes an emitting layer including a first material, a second material and a third material, in which singlet energy EgS(H) of the first material, singlet energy EgS(H2) of the second material, and singlet energy EgS(D) of the third material satisfy a specific relationship.

An organic EL device includes a pair of electrodes and an organic compound layer between pair of electrodes. The organic compound layer includes an emitting layer including a first material, a second material and a third material, in which singlet energy EgS(H) of the first material, singlet energy EgS(H2) of the second material, and singlet energy EgS(D) of the third material satisfy a specific relationship.

Compounds useful as fluorescent or colored dyes are disclosed. The compounds have the following structure (I): ##STR00001##
including stereoisomers, salts and tautomers thereof, wherein R.sup.1, R.sup.2, R.sup.3, L.sup.1, L.sup.2, L.sup.3, L.sup.4, L.sup.5, L.sup.6, M.sup.1, M.sup.2, A, q, w and n are as defined herein. Methods associated with preparation and use of such compounds are also provided.

Compounds useful as fluorescent or colored dyes are disclosed. The compounds have the following structure (I): ##STR00001##
including stereoisomers, salts and tautomers thereof, wherein R.sup.1, R.sup.2, R.sup.3, L.sup.1, L.sup.2, L.sup.3, L.sup.4, L.sup.5, L.sup.6, M.sup.1, M.sup.2, A, q, w and n are as defined herein. Methods associated with preparation and use of such compounds are also provided.

A method for chlorinating blue anthrone, violanthrone or isoviolanthrone is provided. Reaction is carried out with a chlorinating agent (any one of sulfonyl chloride, thionyl chloride and triphosgene) in a reaction solvent (a Lewis acid ionic liquid with anions being of a transition metal halide) for 2 h to 40 h at a chlorination temperature not lower than room temperature and not higher than 120? C.; and then the reaction product is subjected to post-treatment to obtain a target product. The present disclosure cuts off a generation route of harmful substances such as dioxins and their derivatives from the source. There are no dioxins or similar substances generated in the product, and the reaction has high atomic utilization rate and low energy consumption, which fills the gap in the field of chemical technologies at home and abroad.

The present invention is generally directed to the synthesis and use of fluorophores. It is more specifically directed to the synthesis and use of deuterated fluorophores. In one case, the present invention provides a compound of the structure shown in FIG. 44.