The present invention relates to new coating compositions for the preparation of functional surface coatings on various base material substrates. The coating compositions are polysilazane polybutadiene hybrid coating compositions which are based on a silazane polymer and a specific functionalized butadiene polymer. The coating compositions are particularly suitable for the preparation of functional surface coatings on various base material substrates to provide improved physical and/or chemical surface properties.

A polymer nanocomposite coating of an elastomeric film containing at least 30 wt % conductive nanoparticles based on combined weight of elastomer and conductive nanoparticles is provided. The conductive nanoparticles have an average particle size along each dimension of less than 500 nm for nanoparticles having an aspect ratio of less than 20:1 or have an average particle size along each dimension of less than 2000 nm for nanoparticles having an aspect ratio of 20:1 or greater. The conductive nanoparticles are formed into hierarchical micro- and nano-sized aggregates having re-entrant morphology. The coating is both superoleophobic and conductive and retains these properties even when stretched under strain to over 100%. The coatings may be produced with simple spray technology.

A polymer nanocomposite coating of an elastomeric film containing at least 30 wt % conductive nanoparticles based on combined weight of elastomer and conductive nanoparticles is provided. The conductive nanoparticles have an average particle size along each dimension of less than 500 nm for nanoparticles having an aspect ratio of less than 20:1 or have an average particle size along each dimension of less than 2000 nm for nanoparticles having an aspect ratio of 20:1 or greater. The conductive nanoparticles are formed into hierarchical micro- and nano-sized aggregates having re-entrant morphology. The coating is both superoleophobic and conductive and retains these properties even when stretched under strain to over 100%. The coatings may be produced with simple spray technology.

A coating agent for oil seal comprising 10 to 90 parts by weight in total of fluororesin particles having a particle size of 2 μm or less and filler particles other than fluororesin particles having a particle size of 0.5 to 30 μm, and 10 to 40 parts by weight of a wax having a melting point of 40 to 160° C., based on 100 parts by weight of isocyanate group-containing 1,2-polybutadiene, and being prepared as an organic solvent solution, wherein the fluororesin particles are used at a ratio of 20 to 80 wt. % of the total filler amount. The coating agent for oil seal can improve abrasion resistance while maintaining the roughness of a coating surface to which the coating agent is applied.

A coating agent for oil seal comprising 10 to 90 parts by weight in total of fluororesin particles having a particle size of 2 μm or less and filler particles other than fluororesin particles having a particle size of 0.5 to 30 μm, and 10 to 40 parts by weight of a wax having a melting point of 40 to 160° C., based on 100 parts by weight of isocyanate group-containing 1,2-polybutadiene, and being prepared as an organic solvent solution, wherein the fluororesin particles are used at a ratio of 20 to 80 wt. % of the total filler amount. The coating agent for oil seal can improve abrasion resistance while maintaining the roughness of a coating surface to which the coating agent is applied.

A coating agent for oil seal comprising 10 to 90 parts by weight of a filler and 10 to 40 parts by weight of a wax, based on 100 parts by weight of isocyanate group-containing 1,2-polybutadiene, and being prepared as an organic solvent solution, wherein as the filler, silicone resin particles having a particle size of 0.5 to 10 μm and fluororesin particles having a particle size of 0.1 to 2 μm are each used at a ratio of 20 to 80 wt. % of the total filler amount. The coating agent for oil seal can exhibit excellent seal performance inherent in oil seal while maintaining excellent dispersibility of the coating agent, and can further achieve low torque characteristics.

A coating agent for oil seal comprising 10 to 90 parts by weight of a filler and 10 to 40 parts by weight of a wax, based on 100 parts by weight of isocyanate group-containing 1,2-polybutadiene, and being prepared as an organic solvent solution, wherein as the filler, silicone resin particles having a particle size of 0.5 to 10 μm and fluororesin particles having a particle size of 0.1 to 2 μm are each used at a ratio of 20 to 80 wt. % of the total filler amount. The coating agent for oil seal can exhibit excellent seal performance inherent in oil seal while maintaining excellent dispersibility of the coating agent, and can further achieve low torque characteristics.

Provided is an electrophotographic electroconductive member, including: an electroconductive support; an electroconductive layer; and a surface layer in order, wherein an impedance is 1.0×10.sup.3Ω to 1.0×10.sup.8Ω at an outer surface of the electroconductive member, in the surface layer, an electronic electroconductive agent is dispersed, the electroconductive layer has a matrix containing a cross-linked product of a first rubber and domains each containing a cross-linked product of a second rubber and electroconductive particles, and wherein, and wherein among the domains observed in specified observation regions, 80% by number or more of the domains satisfy (1) and (2): (1) a proportion of sectional areas of the electroconductive particles with respect to the domain is 20% or more; (2) A/B is 1.00 to 1.10 when A is a perimeter of the domain and B is an envelope perimeter.

Provided is an electrophotographic electroconductive member, including: an electroconductive support; an electroconductive layer; and a surface layer in order, wherein an impedance is 1.0×10.sup.3Ω to 1.0×10.sup.8Ω at an outer surface of the electroconductive member, in the surface layer, an electronic electroconductive agent is dispersed, the electroconductive layer has a matrix containing a cross-linked product of a first rubber and domains each containing a cross-linked product of a second rubber and electroconductive particles, and wherein, and wherein among the domains observed in specified observation regions, 80% by number or more of the domains satisfy (1) and (2): (1) a proportion of sectional areas of the electroconductive particles with respect to the domain is 20% or more; (2) A/B is 1.00 to 1.10 when A is a perimeter of the domain and B is an envelope perimeter.

There is provided a water-based resin composition that contains a polymer (A) containing, as essential raw materials, a hydrogenated polybutadiene (a1) with an iodine value in the range of 5 to 25, a monomer (a2) with an acid group, and a monomer (a3) with a hydroxy group, a basic compound (B), and an aqueous medium (C), wherein the hydrogenated polybutadiene (a1) constitutes 4% to 38% by mass of the raw materials of the polymer (A), and the polymer (A) has an acid value in the range of 10 to 65 mgKOH/g. A water-based resin composition of the present invention has high storage stability and forms a coating film with good physical properties, such as high adhesiveness to various substrates and high blocking resistance, and is therefore suitably used in a water-based paint.