Organic coating composition are provided including antireflective coating compositions that can reduce reflection of exposing radiation from a substrate back into an overcoated photoresist layer and/or function as a planarizing or via-fill layer. Preferred organic coating compositions of the invention comprise one or more resins that can harden upon thermal treatment without generation of a cleavage product. Particularly preferred organic coating compositions of the invention comprise one or more components that comprise anhydride and hydroxy moieties.

Organic coating composition are provided including antireflective coating compositions that can reduce reflection of exposing radiation from a substrate back into an overcoated photoresist layer and/or function as a planarizing or via-fill layer. Preferred organic coating compositions of the invention comprise one or more resins that can harden upon thermal treatment without generation of a cleavage product. Particularly preferred organic coating compositions of the invention comprise one or more components that comprise anhydride and hydroxy moieties.

A curable ink composition for forming a three-dimensional (3D) object via a digital additive manufacturing system is provided. The composition may comprise greater than about 30 weight % of one or more oligomers, at least two monomers comprising a lowest viscosity monomer and a highest viscosity monomer, one or more photoinitiators, and optionally, one or more additives. The ratio of the weight % of the total amount of oligomers to the weight % of the total amount of monomers may be at least about 0.5 and the ratio of the weight % of the lowest viscosity monomer to the weight % of the highest viscosity monomer may be at least about 5.

A curable ink composition for forming a three-dimensional (3D) object via a digital additive manufacturing system is provided. The composition may comprise greater than about 30 weight % of one or more oligomers, at least two monomers comprising a lowest viscosity monomer and a highest viscosity monomer, one or more photoinitiators, and optionally, one or more additives. The ratio of the weight % of the total amount of oligomers to the weight % of the total amount of monomers may be at least about 0.5 and the ratio of the weight % of the lowest viscosity monomer to the weight % of the highest viscosity monomer may be at least about 5.

Disclosed herein are polymers, which can be incorporated in pigment dispersions and inkjet ink compositions, comprising first monomers selected from ethylenically unsaturated hydrophobic monomers, and second monomers selected from maleic anhydride, maleic acid, and salts, esters, imides, and amides thereof. The polymers can have a portion of the second monomers functionalized with at least one organic group having a calcium index value greater than or equal to a calcium index value of phenylphosphonic acid. Additionally and/or alternatively, the at least one polymer can be crosslinked via the second monomers. Dispersions and inkjet ink compositions comprising such polymers can also further comprise at least one pigment and a liquid vehicle. Also disclosed are methods of making such polymers.

Disclosed herein are polymers, which can be incorporated in pigment dispersions and inkjet ink compositions, comprising first monomers selected from ethylenically unsaturated hydrophobic monomers, and second monomers selected from maleic anhydride, maleic acid, and salts, esters, imides, and amides thereof. The polymers can have a portion of the second monomers functionalized with at least one organic group having a calcium index value greater than or equal to a calcium index value of phenylphosphonic acid. Additionally and/or alternatively, the at least one polymer can be crosslinked via the second monomers. Dispersions and inkjet ink compositions comprising such polymers can also further comprise at least one pigment and a liquid vehicle. Also disclosed are methods of making such polymers.

Provided is a curable compound having a low melting temperature, having excellent workability as a result of having good solvent solubility, and being capable of forming a cured product having excellent heat resistance. The curable compound according to an embodiment of the present invention includes the following characteristics (a) to (e). (a) Number average molecular weight (calibrated with polystyrene standard): 1000 to 15000. (b) Proportion of a structure derived from an aromatic ring in the total amount of the curable compound: 50 wt. % or greater. (c) Solvent solubility at 25? C.: 1 g/100 g or greater. (d) Glass transition temperature: 280? C. or lower. (e) 5% Weight loss temperature (T.sub.d5) measured at a rate of temperature increase of 10? C./min (in nitrogen), for a cured product of the curable compound: 300? C. or higher.

Antistatic polymers include divalent segments represented by the formula wherein R.sup.1 represents an alkyl group having from 6 to 18 carbon atoms, R.sup.2 and R.sup.3 represent alkyl groups having from 1 to 4 carbon atoms, and R.sup.4 represents an alkylene group having from 2 to 8 carbon atoms. Methods of making antistatic polymers are also disclosed. ##STR00001##

A non-aqueous stannous alkoxide composition comprises: component (a) comprising a water-insoluble stannous alkoxide complex comprising stannous ions in an amount of at least 1 weight %, and a photocurable component (b), non-photocurable water-insoluble polymer component (c) having a molecular weight of at least 10,000, or both the photocurable component (b) and the non-photocurable water-insoluble polymer component (c). When photocurable component (b) is present, the non-aqueous stannous alkoxide composition further comprises photosensitizer component (d) that is different from all of components (a) through (c), in an amount of at least 1 weight %. These compositions can be used to prepare silver particles as seed catalysts in various articles that can then be used for other purposes such as electroless plating.

A non-aqueous stannous alkoxide composition comprises: component (a) comprising a water-insoluble stannous alkoxide complex comprising stannous ions in an amount of at least 1 weight %, and a photocurable component (b), non-photocurable water-insoluble polymer component (c) having a molecular weight of at least 10,000, or both the photocurable component (b) and the non-photocurable water-insoluble polymer component (c). When photocurable component (b) is present, the non-aqueous stannous alkoxide composition further comprises photosensitizer component (d) that is different from all of components (a) through (c), in an amount of at least 1 weight %. These compositions can be used to prepare silver particles as seed catalysts in various articles that can then be used for other purposes such as electroless plating.