The present disclosure discloses a preparation method for a transparent conductive polymer film, wherein the method comprises the following steps: (a) providing a precursor solution, wherein the precursor solution comprises a main solvent, an auxiliary solvent, an oxidizing agent and a thiophene monomer, wherein the auxiliary solvent comprises one or more of water, an aqueous solution containing hydrogen ions, a cyclic amide, a cyclic urea, a chain alkyl urea, phosphate or phosphoramide, and (b) coating the surface of a substrate with the precursor solution, so that the thiophene monomer is subjected to a polymerization reaction to form a conductive polymer film. The preparation method according to the present disclosure is economical, effective and simple, and the fabrication of high-quality transparent conductive polymer films by a one-step solution method has promising applications.

The present disclosure discloses a preparation method for a transparent conductive polymer film, wherein the method comprises the following steps: (a) providing a precursor solution, wherein the precursor solution comprises a main solvent, an auxiliary solvent, an oxidizing agent and a thiophene monomer, wherein the auxiliary solvent comprises one or more of water, an aqueous solution containing hydrogen ions, a cyclic amide, a cyclic urea, a chain alkyl urea, phosphate or phosphoramide, and (b) coating the surface of a substrate with the precursor solution, so that the thiophene monomer is subjected to a polymerization reaction to form a conductive polymer film. The preparation method according to the present disclosure is economical, effective and simple, and the fabrication of high-quality transparent conductive polymer films by a one-step solution method has promising applications.

The present invention provides multifunctional monomers, including, but not limited to include multifunctional methylene malonate and methylene beta-ketoester monomers; methods for producing the same; and compositions and products formed therefrom. The multifunctional monomers of the invention may be produced by transesterification or by direct synthesis from monofunctional methylene malonate monomers or methylene beta-ketoester monomers. The present invention further compositions and products formed from methylene beta-ketoester monomers of the invention, including monomer-based products (e.g., inks, adhesives, coatings, sealants or reactive molding) and polymer-based products (e.g., fibers, films, sheets, medical polymers, composite polymers and surfactants).

This invention relates to a coating composition comprising an ionomer having a polymer backbone and side chains, the side chains comprising ionic groups, wherein the ionic groups are sulfonic acid groups and sulfonate groups, from 50 to 95% of the total number of sulfonic acid groups and sulfonate groups are in the sulfonate form, and the sulfonate groups have counter ions M selected from the group consisting of lithium, sodium, magnesium, calcium, and mixtures thereof. This invention also relates to an article comprising a polymeric substrate having an antistatic coating thereon, wherein the antistatic coating is formed from the inventive coating composition. The article may be a cable, a cable cover or a cable jacket.

A method for the reversible crosslinking of, for example, adhesives or coating materials, and a composition stable on storage at room temperature for implementing the crosslinking reaction. The reversible crosslinking method allows very rapid crosslinking even at a low first temperature, and undoing of the crosslinks at higher temperatures, thereby recovering thermoplastic processability and, for example, allowing the originally bonded substrates to be parted from one another again easily. A particular aspect is that a plurality of cycles of crosslinking and undoing of the crosslinks are possible with the present system. A feature of the system used for the reversible crosslinking is that it contains two components, A and B, where component A is a compound having at least two protected dithioester functionalities, preferably cyanodithioester functionalities, and component B is a compound having at least two diene functionalities.

A method for the reversible crosslinking of, for example, adhesives or coating materials, and a composition stable on storage at room temperature for implementing the crosslinking reaction. The reversible crosslinking method allows very rapid crosslinking even at a low first temperature, and undoing of the crosslinks at higher temperatures, thereby recovering thermoplastic processability and, for example, allowing the originally bonded substrates to be parted from one another again easily. A particular aspect is that a plurality of cycles of crosslinking and undoing of the crosslinks are possible with the present system. A feature of the system used for the reversible crosslinking is that it contains two components, A and B, where component A is a compound having at least two protected dithioester functionalities, preferably cyanodithioester functionalities, and component B is a compound having at least two diene functionalities.

A solid electrolytic capacitor that includes an anode body having a porous part on surface thereof and a manufacturing method thereof including a step (i) of forming a first solid electrolyte layer on a dielectric layer and a step (ii) of forming a second solid electrolyte layer on the first solid electrolyte layer. The first and second solid electrolyte layers contain first and second conductive polymers, respectively. The step (i) includes a step (i-a) of supplying a reaction solution containing a monomer and a silane compound to the surface of the dielectric layer, and a step (i-b) of forming the first solid electrolyte layer by polymerizing the monomer in the supplied reaction solution to form the first conductive polymer. The monomer contains a compound represented by the following formula (I) (in the formula (I), R represents an alkyl group whose carbon number is within a range of 1 to 10).

A solid electrolytic capacitor that includes an anode body having a porous part on surface thereof and a manufacturing method thereof including a step (i) of forming a first solid electrolyte layer on a dielectric layer and a step (ii) of forming a second solid electrolyte layer on the first solid electrolyte layer. The first and second solid electrolyte layers contain first and second conductive polymers, respectively. The step (i) includes a step (i-a) of supplying a reaction solution containing a monomer and a silane compound to the surface of the dielectric layer, and a step (i-b) of forming the first solid electrolyte layer by polymerizing the monomer in the supplied reaction solution to form the first conductive polymer. The monomer contains a compound represented by the following formula (I) (in the formula (I), R represents an alkyl group whose carbon number is within a range of 1 to 10).

An aqueous dispersion including a polymer having a 2-oxazoline group; and a surfactant, the surfactant containing a sulfuric acid ester compound represented by the following Chemical Formula (S):
R.sup.1O(R.sup.2O)nSO.sub.3X(S)
wherein R.sup.1 represents an aliphatic hydrocarbon group having 8 to 20 carbon atoms; R.sup.2 represents an alkylene group having 2 to 4 carbon atoms; n represents 2 to 15; and X represents a monovalent cation.

An aqueous dispersion including a polymer having a 2-oxazoline group; and a surfactant, the surfactant containing a sulfuric acid ester compound represented by the following Chemical Formula (S):
R.sup.1O(R.sup.2O)nSO.sub.3X(S)
wherein R.sup.1 represents an aliphatic hydrocarbon group having 8 to 20 carbon atoms; R.sup.2 represents an alkylene group having 2 to 4 carbon atoms; n represents 2 to 15; and X represents a monovalent cation.