C09D141/00

Surface modifying agents, modified materials and methods
10240031 · 2019-03-26 · ·

The present invention relates to surface modifying agents for polymeric and/or textile materials, methods of making and/or using a surface modifying agent to modify and functionalize polymeric and/or textile materials, and/or methods of using surface modified or functionalized polymeric and textile materials, and/or products using or incorporating surface modified or functionalized polymeric and textile materials. For example, the surface modifying agent in precursor form can be styrene sulfonyl azide monomer, polymer or copolymer capable of undergoing a chemical reaction in the presence of heat or light to form one or more styrene sulfonated nitrene monomers, polymers or copolymers, which are capable of chemically reacting with the surface of a polymeric or textile material to endow a specific or desired chemical surface functionality to the surface of a polymeric or textile material. Furthermore, the present invention is possibly preferably directed to a surface modifying agent which comprises a styrene sulfonated nitrene monomer, polymer or polymer containing one or more nitrene functional groups, which are capable of chemically reacting via an insertion reaction into one or more carbon-hydrogen bonds on the surface of a polymeric or textile material in order to chemically attach a specific or desired chemical functionality to the surface of a polymeric or textile material.

Amphoteric polymer composition

The present invention relates to a composition comprising an amphoteric polymer having pendant acid groups, or salts thereof, and pendant mono- or dialkylamino ethylene oxide groups or alkylammonium ethylene oxide groups characterized by either of the following formulas: ##STR00001##
where R.sup.1-R.sup.3 and X.sup. are as defined herein. The composition of the present invention improves hiding efficiency for coating compositions formulated using associative rheology modifiers, binders, and titanium dioxide.

Amphoteric polymer composition

The present invention relates to a composition comprising an amphoteric polymer having pendant acid groups, or salts thereof, and pendant mono- or dialkylamino ethylene oxide groups or alkylammonium ethylene oxide groups characterized by either of the following formulas: ##STR00001##
where R.sup.1-R.sup.3 and X.sup. are as defined herein. The composition of the present invention improves hiding efficiency for coating compositions formulated using associative rheology modifiers, binders, and titanium dioxide.

MULTIFUNCTIONAL MONOMERS, METHODS FOR MAKING MULTIFUNCTIONAL MONOMERS, POLYMERIZABLE COMPOSITIONS AND PRODUCTS FORMED THEREFORM

The present invention provides multifunctional monomers, including, but not limited to include multifunctional methylene malonate and methylene beta-ketoester monomers; methods for producing the same; and compositions and products formed therefrom. The multifunctional monomers of the invention may be produced by transesterification or by direct synthesis from monofunctional methylene malonate monomers or methylene beta-ketoester monomers. The present invention further compositions and products formed from methylene beta-ketoester monomers of the invention, including monomer-based products (e.g., inks, adhesives, coatings, sealants or reactive molding) and polymer-based products (e.g., fibers, films, sheets, medical polymers, composite polymers and surfactants).

MULTIFUNCTIONAL MONOMERS, METHODS FOR MAKING MULTIFUNCTIONAL MONOMERS, POLYMERIZABLE COMPOSITIONS AND PRODUCTS FORMED THEREFORM

The present invention provides multifunctional monomers, including, but not limited to include multifunctional methylene malonate and methylene beta-ketoester monomers; methods for producing the same; and compositions and products formed therefrom. The multifunctional monomers of the invention may be produced by transesterification or by direct synthesis from monofunctional methylene malonate monomers or methylene beta-ketoester monomers. The present invention further compositions and products formed from methylene beta-ketoester monomers of the invention, including monomer-based products (e.g., inks, adhesives, coatings, sealants or reactive molding) and polymer-based products (e.g., fibers, films, sheets, medical polymers, composite polymers and surfactants).

USAGE OF BORIC ACID IN THE PRODUCTION OF DEPOT:PSS FILM.

The invention relates to production method of PEDOT:PSS film which comprises the steps of preparing substrate, preparing the mixture of boric acid doped PEDOT:PSS prepare on the substrate surface.

USAGE OF BORIC ACID IN THE PRODUCTION OF DEPOT:PSS FILM.

The invention relates to production method of PEDOT:PSS film which comprises the steps of preparing substrate, preparing the mixture of boric acid doped PEDOT:PSS prepare on the substrate surface.

CURABLE CONDUCTIVE COMPOSITIONS

A composition comprising i) at least one polythiophene selected from the group consisting ofa polythiophene comprising monomer units of structure (I) in which * indicates the bond to the neighboring monomer units, x, z represent O or S, R.sup.1-R.sup.4 independently from each other represent a hydrogen atom or an organic residue R, with the proviso that at least one of residues R.sup.1 to R.sup.4 represents an organic residue R; a polythiophene which is characterized by its compatibility in PGME (1-methoxypropan-2-ol), demonstrated by an RF-value of at least 0.8; iii) at least one ethylenically unsaturated compound; iv) at least one organic solvent; v) at least one radical initiator. The present invention also relates to a process for preparing a layer structure, to a layer structure obtainable by this process, to a layer structure, to an electronic component and to the use of composition according to the present invention.

CURABLE CONDUCTIVE COMPOSITIONS

A composition comprising i) at least one polythiophene selected from the group consisting ofa polythiophene comprising monomer units of structure (I) in which * indicates the bond to the neighboring monomer units, x, z represent O or S, R.sup.1-R.sup.4 independently from each other represent a hydrogen atom or an organic residue R, with the proviso that at least one of residues R.sup.1 to R.sup.4 represents an organic residue R; a polythiophene which is characterized by its compatibility in PGME (1-methoxypropan-2-ol), demonstrated by an RF-value of at least 0.8; iii) at least one ethylenically unsaturated compound; iv) at least one organic solvent; v) at least one radical initiator. The present invention also relates to a process for preparing a layer structure, to a layer structure obtainable by this process, to a layer structure, to an electronic component and to the use of composition according to the present invention.

Removable tattoo ink and the use thereof

Provided is a removable tattoo ink that is composed of colored micro-particles that create permanent tissue markings, such as tattoos. The micro-particles include an inner core housing a bio-absorbable chromophore and an outer shell, which includes polystyrene sulfonate and polyallylamine hydrochloride and is designed for rupture with ultrasonic energy. The micro-particles can be implanted in the tissue of a subject, for example to create a tattoo and ruptured in situ by the application of ultrasonic energy to remove the tattoo. Also provided are methods of making the colored micro-particles.