A novel reaction resin formulation having a significantly improved properties profile contains crosslinkers, monomers, urethane methacrylates, prepolymers, optional further auxiliaries, and a curing system containing permaleinates and a tertiary organic phosphite. The reaction resin formulation is useful for marking driving surfaces or coating surfaces. The reaction resins, above all based on a novel curing system, show an improved combination of higher long-term storage stability, improved toxicological profile, reduced curing time, a low yellowing tendency and a better colour fastness.

An aqueous dispersion of a multistage polymer and an aqueous coating composition comprising the aqueous dispersion and providing coating films with good scratch resistance and balanced properties.

A method of forming a coating on a food or beverage container, which includes spraying a coating composition onto an interior surface of the food or beverage container, where the coating composition includes an emulsion-polymerized latex copolymer having copolymer chains of one or more ethylenically-unsaturated monomers and one or more styrene offset monomers. Preferably, the coating composition is substantially free of BPA, PVC, and styrene. The method may also include curing the sprayed coating composition, thereby providing the coating on the interior surface of the food or beverage container.

Disclosed herein is an aqueous latex composition comprising a substantially acrylic core-shell latex, wherein a water-retaining monomer is copolymerized to the shell. The Tg of the core ranges from about 0° C. to about 12° C., and the Tg of the shell ranges from about 13° C. to about 40° C. The mean volume average particle size of the latex ranges from about 125 nm to about 200 nm. The core-shell latex comprises at least one acrylic monomer having a solubility that ranges about 10 g/L to about 30 g/L at 30° C., and this at least one acrylic monomer is present in the shell polymer in an amount greater than about 50 wt. % of all monomers in the shell. Preferably, the at least one acrylic monomer is methyl methacrylate.

There is described an acrylic polyester resin, obtainable by grafting an acrylic polymer with a polyester material. The polyester material is obtainable by polymerizing (i) a polyacid component, with (ii) a polyol component. At least one of the polyacid component and/or the polyol component comprises a monomer having an aliphatic group containing at least 15 carbon atoms. At least one of the polyacid component and/or the polyol component comprises a functional monomer operable to impart functionality on to the polyester resin, such that an acrylic polymer may be grafted with the polyester material via the use of said functionality. Also provided is an aqueous coating composition comprising the acrylic polyester resin and a packaging coated with the composition.

Provided is a coating material composition that enables an efficient repair operation of a coating film after coating, a (meth)acrylic copolymer that is suitable for obtaining the coating material composition, and a coated article and a method for forming a multilayer coating film using the coating material composition. The (meth)acrylic copolymer includes: a constituent unit derived from a macromonomer (a); and a constituent unit derived from a vinyl monomer (b), a hydroxyl value of the (meth)acrylic copolymer is equal to or greater than 120 mgKOH/g and equal to or less than 260 mgKOH/g, and the content of a constituent unit that has a primary hydroxyl group of the (meth)acrylic copolymer is equal to or less than 30 parts by mass with respect to 100 parts by mass of the constituent unit derived from the macromonomer (a) and the constituent unit derived from the vinyl monomer (b).

The present invention relates to a process for preparing an aqueous binder composition, as well as the aqueous binder composition comprising a carboxylic acid-functional vinyl polymer (polymer A) and vinyl polymer (polymer B).

There is described an acrylic polyester resin, obtainable by grafting an acrylic polymer with a polyester material. The polyester material is obtainable by polymerizing (i) a polyacid component, with (ii) a polyol component, including—2,2,4,4-tetraallcylcyclobutane-1,3-diol. One of the polyacid component or the polyol component comprises a functional monomer operable to impart functionality on to the polyester resin, such that an acrylic polymer may be grafted with the polyester material via the use of said functionality. Also provided is an aqueous coating composition comprising the acrylic polyester resin and a metal packaging containing coated with the composition.

A graft copolymer contains crosslinked (meth)acrylic polymer particles (a) having an average particle size of 150 nm or less and a glass transition temperature of −10° C. or lower and a non-crosslinked methacrylic polymer component (b) having a weight-average molecular weight of 25×10.sup.4 or more. At least a part of the non-crosslinked polymer component (b) is grafted to the crosslinked polymer particles (a). The crosslinked polymer particles (a) account for 1 to less than 50 wt % of the total weight of the crosslinked polymer particles (a) and the non-crosslinked polymer component (b).

The wet adhesion of a coating composition may be improved through the use of voided latex particles as opacifying agents which contain a hollow interior as well as an outer shell of a polymer containing functional groups such as amino, 1,3-diketo, urea or ureido. Other types of functional groups may be introduced to the outer shell polymer in order to vary other desired characteristics of the coating. The voided latex particles are non-film-forming.