The wet adhesion of a coating composition may be improved through the use of voided latex particles as opacifying agents which contain a hollow interior as well as an outer shell of a polymer containing functional groups such as amino, 1,3-diketo, urea or ureido. Other types of functional groups may be introduced to the outer shell polymer in order to vary other desired characteristics of the coating. The voided latex particles are non-film-forming.

This invention relates to a graft copolymer comprising: a) a macromonomer, wherein the macromonomer comprises in polymerized form a first monoethylenically unsaturated monomer selected from a group consisting of esters of methacrylic acid and acrylic acid with straight or branched alcohols having 1 to 3 carbon atoms and no more than 5 mole % an addition fragmentation chain transfer agent; and b) at least one side chain on the macromonomer, wherein the at least one side chain comprises at least 95 wt.-% of acrylic acid in polymerized form,
and its use for improving the dirt pick-up resistance of a paint or coating.

An aqueous dispersion of a multistage polymer, an aqueous coating composition having an extended open time and capable of providing coatings with good water resistance, and a process of preparing the coatings.

A multistage aqueous emulsion polymer comprising from 88% to 98% by dry weight, based on total dry weight of the multistage aqueous emulsion polymer, of a first polymer core; and from 2% to 12% by dry weight, based on total dry weight of the multistage aqueous emulsion polymer, of a second polymer shell, wherein the first polymer core and the second polymer shell each independently comprises, as polymerized units, one or more ethylenically unsaturated nonionic monomers, wherein the second polymer shell further comprises, as polymerized units, from 20% to 60% by dry weight, based on total dry weight of the second polymer shell, of an acid monomer, wherein said acid monomer is, as polymerized units, from 1.1% to 4.2% by dry weight, based on total dry weight of the multistage aqueous emulsion polymer. An aqueous coating composition comprising said multistage aqueous emulsion polymer.

A method of forming a coating on a food or beverage container, which includes spraying a coating composition onto an interior surface of the food or beverage container, where the coating composition includes an emulsion-polymerized latex copolymer having copolymer chains of one or more ethylenically-unsaturated monomers and one or more styrene offset monomers. Preferably, the coating composition is substantially free of BPA, PVC, and styrene. The method may also include curing the sprayed coating composition, thereby providing the coating on the interior surface of the food or beverage container.

There is described an acrylic polyester resin, obtainable by grafting an acrylic polymer with a polyester material. The polyester material is obtainable by polymerizing (i) a polyacid component, with (ii) a polyol component. At least one of the polyacid component and/or the polyol component comprises a monomer having an aliphatic group containing at least 15 carbon atoms. At least one of the polyacid component and/or the polyol component comprises a functional monomer operable to impart functionality on to the polyester resin, such that an acrylic polymer may be grafted with the polyester material via the use of said functionality. Also provided is an aqueous coating composition comprising the acrylic polyester resin and a packaging coated with the composition.

The present invention relates to a process for producing an aqueous polymer dispersion of polymerized ethylenically unsaturated monomers, where the process has a first polymerization step as an aqueous radical emulsion polymerization of a first monomer composition M.a and a subsequent further polymerization step as an aqueous radical emulsion polymerization of a second monomer composition M.b,

where the monomers M comprise at least one monomer M0 which is selected from compounds of formula 1, wherein X is Cl, Br or OS(O).sub.2R.sup.3, Y is H, Cl, Br, OS(O).sub.2R.sup.4, C.sub.1-C.sub.10-alkyl, or C(═O)OR.sup.5, R.sup.1 is H or C.sub.1-C.sub.10-alkyl, R.sup.2 is H or C.sub.1-C.sub.10-alkyl, R.sup.3 is C.sub.1-C.sub.10-alkyl, R.sup.4 is C.sub.1-C.sub.10-alkyl, R.sup.5 is C.sub.1-C.sub.20-alkyl.

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The invention also relates to an aqueous polymer dispersion obtainable by such a process as well as the use of such dispersions.

The present invention relates to latex paints containing a) a multistage carboxylated polymer latex binder obtainable by multistage aqueous emulsion polymerisation of at least one non-ionic monomer which is selected from C.sub.1-C.sub.20-alkyl esters of acrylic acid, C.sub.1-C.sub.20-alkylesters of methacrylic acid, and vinyl aromatic monomers; one or more monoethylenically unsaturated monomers M2, which are selected from monoethylenically unsaturated monocarboxylic acids having 3 to 6 carbon atoms and monoethylenically unsaturated dicarboxylic acids having 4 to 6 carbon atoms, and where in at least one stage, monomers M2 added in this stage is at least 6% by weight; b) a titanium dioxide pigment; c) a polymeric dispersant selected from monoethylenically unsaturated monocarboxylic acids having 3 to 6 carbon atoms and monoethylenically unsaturated dicarboxylic acids having 4 to 6 carbon atoms, where the monomers make up at least 85% of the monomers forming the polymeric dispersant; and d) a thickener polymer.

A graft copolymer is provided herein. The graft copolymer includes a polymeric backbone. The polymeric backbone includes a cyclic amine-containing moiety. The graft copolymer further includes a first side chain bound to the polymeric backbone, wherein the first side chain includes an acid-containing moiety. The graft copolymer further includes a second side chain bound to the polymeric backbone, wherein the second side chain includes an alkoxylated moiety. Another graft copolymer is provided herein. The graft copolymer includes a polymeric backbone. The polymeric backbone includes a quaternary ammonium moiety formed from a reaction of an amine-containing moiety and an alkylation agent. The graft copolymer further includes a first side chain bound to the polymeric backbone, wherein the first side chain includes an acid-containing moiety. The graft copolymer further includes a second side chain bound to the polymeric backbone, wherein the second side chain includes an alkoxylated moiety.

An embodiment of the present invention provides a coating composition comprising a composite in which a dissociated natural polymer compound is bound onto at least a portion of the surface of acrylic polymer particles.