The present invention relates to [1] a method of producing a polymer emulsion for water-resistant coating films with excellent water resistance, including emulsion polymerizing a radical polymerizable monomer (B) in the presence of a compound (A) represented by the following formula (1); and [2] a method of producing a polymer coating film, including a step 1 of emulsion polymerizing a radical polymerizable monomer (B) in the presence of a compound (A) represented by the following formula (1), to obtain a polymer emulsion having an average particle diameter of 30 nm or more and 300 nm or less, and a step 2 of applying the obtained polymer emulsion on a substrate and then drying: ##STR00001##
wherein R.sup.1 represents an alkyl group having 16 or more and 24 or less carbon atoms; m represents an average addition molar number of (CH.sub.2H.sub.2O) and is 0.5 or more and 10 or less; and M represents a cation or a hydrogen atom.

The present invention relates to [1] a method of producing a polymer emulsion for water-resistant coating films with excellent water resistance, including emulsion polymerizing a radical polymerizable monomer (B) in the presence of a compound (A) represented by the following formula (1); and [2] a method of producing a polymer coating film, including a step 1 of emulsion polymerizing a radical polymerizable monomer (B) in the presence of a compound (A) represented by the following formula (1), to obtain a polymer emulsion having an average particle diameter of 30 nm or more and 300 nm or less, and a step 2 of applying the obtained polymer emulsion on a substrate and then drying: ##STR00001##
wherein R.sup.1 represents an alkyl group having 16 or more and 24 or less carbon atoms; m represents an average addition molar number of (CH.sub.2H.sub.2O) and is 0.5 or more and 10 or less; and M represents a cation or a hydrogen atom.

The purpose of the present invention is to obtain a method for forming an excellent multi-layer coating film of high chroma and brightness and a rich color. With the method, color mottling does not occur easily in the coating film and the design obtained is homogeneous even without strict control of variations in film thickness during coating. The method for forming the excellent multi-layer coating film comprises: forming a metallic base coating film on the surface of the object to be coated by applying a metallic base coating containing a shiny material; then forming a color base coating film by applying a color base coating; subsequently forming a clear coating film by applying a clear coating on the color base coating film; and heat-curing the metallic base coating film, the color base coating film and the clear coating film obtained. In the method, the light reflectance of the metallic base coating film is in a specified range and the light transmittance of the single color base coating film obtained by heat-curing the color base coating film as a single film is adjusted to a specified range.

The purpose of the present invention is to obtain a method for forming an excellent multi-layer coating film of high chroma and brightness and a rich color. With the method, color mottling does not occur easily in the coating film and the design obtained is homogeneous even without strict control of variations in film thickness during coating. The method for forming the excellent multi-layer coating film comprises: forming a metallic base coating film on the surface of the object to be coated by applying a metallic base coating containing a shiny material; then forming a color base coating film by applying a color base coating; subsequently forming a clear coating film by applying a clear coating on the color base coating film; and heat-curing the metallic base coating film, the color base coating film and the clear coating film obtained. In the method, the light reflectance of the metallic base coating film is in a specified range and the light transmittance of the single color base coating film obtained by heat-curing the color base coating film as a single film is adjusted to a specified range.

A cleaning method may include: bringing an article to be cleaned into contact with a liquid-phase solvent composition including 1-chloro-2,3,3-trifluoro-1-propene and 1-chloro-2,2,3,3-tetrafluoropropane; and exposing the article to be cleaned to steam generated by evaporating the liquid-phase solvent composition. In the liquid-phase composition, a proportion of a content of 1-chloro-2,2,3,3-tetrafluoropropane to a total of a content of 1-chloro-2,3,3-trifluoro-1-propene and a content of 1-chloro-2,2,3,3-tetrafluoropropane may be 0.0001 to 1 mass %.

A cleaning method may include: bringing an article to be cleaned into contact with a liquid-phase solvent composition including 1-chloro-2,3,3-trifluoro-1-propene and 1-chloro-2,2,3,3-tetrafluoropropane; and exposing the article to be cleaned to steam generated by evaporating the liquid-phase solvent composition. In the liquid-phase composition, a proportion of a content of 1-chloro-2,2,3,3-tetrafluoropropane to a total of a content of 1-chloro-2,3,3-trifluoro-1-propene and a content of 1-chloro-2,2,3,3-tetrafluoropropane may be 0.0001 to 1 mass %.

The present invention provides a coating composition capable of forming a coating film that is applicable to a variety of industrial products, particularly automobile exterior panels, while exhibiting a high lightness and a low ultraviolet transmittance at a wavelength of 420 to 480 nm. The present invention relates to a coating composition comprising a chloride process titanium oxide pigment, a yellow iron oxide pigment, a carbon black pigment having a primary average particle size of 15 to 80 nm, and a resin composition, which is a vehicle-forming component.

The present invention provides a coating composition capable of forming a coating film that is applicable to a variety of industrial products, particularly automobile exterior panels, while exhibiting a high lightness and a low ultraviolet transmittance at a wavelength of 420 to 480 nm. The present invention relates to a coating composition comprising a chloride process titanium oxide pigment, a yellow iron oxide pigment, a carbon black pigment having a primary average particle size of 15 to 80 nm, and a resin composition, which is a vehicle-forming component.

The present application provides switchable, homogeneous paint composition and methods of painting and/or forming films or coatings using the composition. The composition includes a liquid having an aqueous solution and dissolved acid gas (e.g., carbonated water), and a switchable polymer. The switchable polymer converts from a protonated, water-soluble form in the liquid to a water-insoluble unprotonated form following removal or substantial removal of the liquid and acid gas.

The present application provides switchable, homogeneous paint composition and methods of painting and/or forming films or coatings using the composition. The composition includes a liquid having an aqueous solution and dissolved acid gas (e.g., carbonated water), and a switchable polymer. The switchable polymer converts from a protonated, water-soluble form in the liquid to a water-insoluble unprotonated form following removal or substantial removal of the liquid and acid gas.