Aqueous alkyd resin emulsion compositions and methods of applying them for providing an exceptionally durable film capable of imparting a gloss sheen to the substrate while simultaneously entrapping pigments, MYLAR or glitter flakes, or other low aspect ratio materials so that they might durably adhere to a variety of surfaces, including, but not limited to, urethane rubber, vehicle tires, and vinyl. The emulsion compositions comprise an alkyd resin, a mixture of alkyd resins, a mixture of alkyd resins and conventional latex resins, or a mixture of all or part of the above and silicone oils. The low aspect ratio materials component of the compositions may be comprised of any combination of various pigments, MYLAR or metallic flakes, or standard glitter flakes, all in a wide variety of sizes, colors and shapes. The emulsion compositions also optionally comprise thickeners, metallic driers, defoamers, and/or preservatives. The methods comprise applying the alkyd resin emulsion composition with low aspect ratio materials to a substrate surface.

Aqueous alkyd resin emulsion compositions and methods of applying them for providing an exceptionally durable film capable of imparting a gloss sheen to the substrate while simultaneously entrapping pigments, MYLAR or glitter flakes, or other low aspect ratio materials so that they might durably adhere to a variety of surfaces, including, but not limited to, urethane rubber, vehicle tires, and vinyl. The emulsion compositions comprise an alkyd resin, a mixture of alkyd resins, a mixture of alkyd resins and conventional latex resins, or a mixture of all or part of the above and silicone oils. The low aspect ratio materials component of the compositions may be comprised of any combination of various pigments, MYLAR or metallic flakes, or standard glitter flakes, all in a wide variety of sizes, colors and shapes. The emulsion compositions also optionally comprise thickeners, metallic driers, defoamers, and/or preservatives. The methods comprise applying the alkyd resin emulsion composition with low aspect ratio materials to a substrate surface.

Aqueous alkyd resin emulsion compositions and methods of applying them for providing exceptionally durable gloss sheen to a variety of surfaces, including, but not limited to, urethane rubber, vehicle tires, and vinyl, The emulsion compositions comprise an alkyd resin, a mixture of alkyd resins, a mixture of alkyd resins and conventional latex resins, or a mixture of all or part of the above and silicone oils. The emulsion compositions also comprise thickeners, metallic driers, defoamers, and/or preservatives. The methods generally comprise applying an alkyd resin emulsion composition to a substrate surface in need of treatment and allowing the composition to cure by oxidative polymerization on and within the surface.

The invention pertains generally to a process and resulting product of following the steps of the process involving adding an Iron- or Manganese- or Vanadium- or Copper-drier in combination with a multidentate ligand to form a metalligand complex with at least two Lewis Acids comprising at least two different Lewis Acid halides to an alkyd resin, said steps performed in any order or the combination performed in-situ.

The present invention relates to hydrophilized polyurethanes having a particularly high content of hydroxy-functional, unsaturated triglycerides, to a process for preparing polyurethane dispersions based thereon, to the use of the dispersions as binders in oxidatively drying coating materials having particularly high chemical resistance, and to articles and substrates coated with these coating materials.

The present invention relates to hydrophilized polyurethanes having a particularly high content of hydroxy-functional, unsaturated triglycerides, to a process for preparing polyurethane dispersions based thereon, to the use of the dispersions as binders in oxidatively drying coating materials having particularly high chemical resistance, and to articles and substrates coated with these coating materials.

The invention pertains generally to paints containing a binder curable by an autoxidation mechanism and at least one drier comprising a sulfonate compound of vanadium of formula (VII) where R.sup.1 and R.sup.2 are independently selected from a group involving hydrogen, C.sub.1-C.sub.12 alkyl, C.sub.1-C.sub.12 halogenated alkyl, C.sub.6-C.sub.10 aryl, benzyl; and whereas aryl and benzyl can be optionally substituted by up to three substituents independently selected from a group involving C.sub.1-C.sub.20 alkyl, and hydroxy(C.sub.1-C.sub.2)alkyl in combination with at least one inorganic acid and optionally in combination with at least one organic acid.

##STR00001##

The invention pertains generally to paints containing a binder curable by an autoxidation mechanism and at least one drier comprising a sulfonate compound of vanadium of formula (VII) where R.sup.1 and R.sup.2 are independently selected from a group involving hydrogen, C.sub.1-C.sub.12 alkyl, C.sub.1-C.sub.12 halogenated alkyl, C.sub.6-C.sub.10 aryl, benzyl; and whereas aryl and benzyl can be optionally substituted by up to three substituents independently selected from a group involving C.sub.1-C.sub.20 alkyl, and hydroxy(C.sub.1-C.sub.2)alkyl in combination with at least one inorganic acid and optionally in combination with at least one organic acid.

##STR00001##

Compositions containing 1,1-difluoroethane and 3,3,3-trifluoropropene, that can be used in multiple fields of application. The composition may include from 25 to 65 mol % of 1,1-difluoroethane and from 75 to 35 mol % of 3,3,3-trifluoropropene at a temperature of between 25 C. and 25 C. and a pressure of between 1 and 6 bar. The composition may further include hydrogen fluoride. The composition may include from 20 to 55 mol % of HF, 30 to 40 mol % of 1,1-difluoroethane and 30 to 40 mol % of 3,3,3-trifluoropropene.

Compositions containing 1,1-difluoroethane and 3,3,3-trifluoropropene, that can be used in multiple fields of application. The composition may include from 25 to 65 mol % of 1,1-difluoroethane and from 75 to 35 mol % of 3,3,3-trifluoropropene at a temperature of between 25 C. and 25 C. and a pressure of between 1 and 6 bar. The composition, may further include hydrogen fluoride. The composition may include from 20 to 55 mol % of HF, 30 to 40 mol % of 1,1-difluoroethane and 30 to 40 mol % of 3,3,3-trifluoropropene.