The composition includes an acrylic monomer having a carboxylic acid group, an acrylic monomer having a hydroxyl group, and a compound composed of divalent segments L and at least two X groups. The divalent segments L are represented by the formula ##STR00001##
Each divalent segment L is respectively directly bonded to two secondary N atoms, two tertiary N atoms, or a secondary and a tertiary N atom. Each R.sup.1 represents an alkylene group having from 1 to 4 carbon atoms, and at least some of the R.sup.1 groups are —CH.sub.2—CH.sub.2—CH.sub.2—CH.sub.2—. Each X group is independently represented by the formula CH.sub.2═C(R)—C(O)—O—V-W—C(O)—. The acrylic monomer having a carboxylic acid group is present in an amount of at least 20 percent by weight, based on the total weight of acrylic-functional compounds. Articles and a method of using the composition are also described.

The composition includes an acrylic monomer having a carboxylic acid group, an acrylic monomer having a hydroxyl group, and a compound composed of divalent segments L and at least two X groups. The divalent segments L are represented by the formula ##STR00001##
Each divalent segment L is respectively directly bonded to two secondary N atoms, two tertiary N atoms, or a secondary and a tertiary N atom. Each R.sup.1 represents an alkylene group having from 1 to 4 carbon atoms, and at least some of the R.sup.1 groups are —CH.sub.2—CH.sub.2—CH.sub.2—CH.sub.2—. Each X group is independently represented by the formula CH.sub.2═C(R)—C(O)—O—V-W—C(O)—. The acrylic monomer having a carboxylic acid group is present in an amount of at least 20 percent by weight, based on the total weight of acrylic-functional compounds. Articles and a method of using the composition are also described.

A resin composition includes a first (meth)acrylate monomer a second (meth)acrylate monomer containing an oxy group or a divalent alkyl group, a urethane (meth)acrylate oligomer, and at least one photoinitiator. A content of the first (meth)acrylate monomer is about 1.6 to about 4.7 times greater than a content of the urethane (meth)acrylate oligomer.

A resin composition includes a first (meth)acrylate monomer a second (meth)acrylate monomer containing an oxy group or a divalent alkyl group, a urethane (meth)acrylate oligomer, and at least one photoinitiator. A content of the first (meth)acrylate monomer is about 1.6 to about 4.7 times greater than a content of the urethane (meth)acrylate oligomer.

A resin composition includes a first (meth)acrylate monomer a second (meth)acrylate monomer containing an oxy group or a divalent alkyl group, a urethane (meth)acrylate oligomer, and at least one photoinitiator. A content of the first (meth)acrylate monomer is about 1.6 to about 4.7 times greater than a content of the urethane (meth)acrylate oligomer.

A process is disclosed for preparing a pressure sensitive adhesive hydrogel. The process (A) provides an oligomeric precursor, the oligomeric precursor comprising a polyether moiety endcapped with ethylenic unsaturation, the oligomeric precursor being associated with methacrylic acid; (B) provides an ethylenically unsaturated crosslinking agent selected from the group consisting of difunctional ethylenically unsaturated monomer, difunctional ethylenically unsaturated monomer and combinations of the foregoing; (C) provides a thiol; and (D) free radically curing a mixture of the oligomeric precursor, the ethylenically unsaturated crosslinking agent, and the thiol in water in the presence of the methacrylic acid at a pH between about 3.5 and about 9 to provide the pressure sensitive adhesive hydrogel.

A process is disclosed for preparing a pressure sensitive adhesive hydrogel. The process (A) provides an oligomeric precursor, the oligomeric precursor comprising a polyether moiety endcapped with ethylenic unsaturation, the oligomeric precursor being associated with methacrylic acid; (B) provides an ethylenically unsaturated crosslinking agent selected from the group consisting of difunctional ethylenically unsaturated monomer, difunctional ethylenically unsaturated monomer and combinations of the foregoing; (C) provides a thiol; and (D) free radically curing a mixture of the oligomeric precursor, the ethylenically unsaturated crosslinking agent, and the thiol in water in the presence of the methacrylic acid at a pH between about 3.5 and about 9 to provide the pressure sensitive adhesive hydrogel.

A process is disclosed for preparing a pressure sensitive adhesive hydrogel. The process (A) provides an oligomeric precursor, the oligomeric precursor comprising a polyether moiety endcapped with ethylenic unsaturation, the oligomeric precursor being associated with methacrylic acid; (B) provides an ethylenically unsaturated crosslinking agent selected from the group consisting of difunctional ethylenically unsaturated monomer, difunctional ethylenically unsaturated monomer and combinations of the foregoing; (C) provides a thiol; and (D) free radically curing a mixture of the oligomeric precursor, the ethylenically unsaturated crosslinking agent, and the thiol in water in the presence of the methacrylic acid at a pH between about 3.5 and about 9 to provide the pressure sensitive adhesive hydrogel.

The present invention refers to a curable two-part adhesive composition comprising a first part comprising one or more cyanoacrylate monomer(s), one or more (metha)acrylate monomer(s), a per-compound and, optionally, additives to control viscosity and rheology; and a second part comprising: a non-reactive diluent and a transition metal catalyst, and optionally an electron rich initiator for cyanoacrylates. It also relates to a syringe or a cartridge comprising said two-part curable composition, to the use of such composition for bonding substrates, to the use of such composition filling depressions, cracks or holes in a substrate or between substrates to a method for bonding substrates using said composition, and to a repair method for filling depressions, cracks or holes in a substrate or between substrates using said composition.

The present invention refers to a curable two-part adhesive composition comprising a first part comprising one or more cyanoacrylate monomer(s), one or more (metha)acrylate monomer(s), a per-compound and, optionally, additives to control viscosity and rheology; and a second part comprising: a non-reactive diluent and a transition metal catalyst, and optionally an electron rich initiator for cyanoacrylates. It also relates to a syringe or a cartridge comprising said two-part curable composition, to the use of such composition for bonding substrates, to the use of such composition filling depressions, cracks or holes in a substrate or between substrates to a method for bonding substrates using said composition, and to a repair method for filling depressions, cracks or holes in a substrate or between substrates using said composition.