An object has a superhydrophic, self-cleaning, and icephobic coating includes a substrate and a layer disposed on the substrate, the layer resulting from coating with a formulation having an effective amount of microstructuring microparticles, liquid silane having one or more groups configured to graft to a microstructuring microparticle and at least another group that results in hydrophobicity. The microstructuring microparticles are dispersed in the liquid silane. Another effective amount of synthetic adhesive, selected from thermosetting adhesives, moisture curing adhesives or polymers that form a strong interaction with a surface, is in solution with a solvent. Upon curing, the layer has a contact angle greater than 90° and a sliding angle of less than 10° and, less than 5% of an area of the layer is removed in a Tape test.

An object has a superhydrophic, self-cleaning, and icephobic coating includes a substrate and a layer disposed on the substrate, the layer resulting from coating with a formulation having an effective amount of microstructuring microparticles, liquid silane having one or more groups configured to graft to a microstructuring microparticle and at least another group that results in hydrophobicity. The microstructuring microparticles are dispersed in the liquid silane. Another effective amount of synthetic adhesive, selected from thermosetting adhesives, moisture curing adhesives or polymers that form a strong interaction with a surface, is in solution with a solvent. Upon curing, the layer has a contact angle greater than 90° and a sliding angle of less than 10° and, less than 5% of an area of the layer is removed in a Tape test.

The adhesive composition includes: a cyclic organosilazane compound of the following general formula (1): ##STR00001##
wherein R.sup.1s each independently represent a substituted or unsubstituted monovalent hydrocarbon group having 1 to 10 carbon atoms, and p represents an integer of 3 to 8; and a hydrolyzable group-containing organosilicon compound containing an alkoxysilane compound of the following general formula (2) and/or a partial hydrolytic condensate thereof:
R.sup.2.sub.x—Si(OR.sup.3).sub.4-x   (2)
wherein R.sup.2 represents an unsubstituted monovalent hydrocarbon group having 1 to 10 carbon atoms and optionally having an oxygen atom, R.sup.3 represents an unsubstituted monovalent hydrocarbon group having 1 to 10 carbon atoms, and x represents an integer of 0 to 2.

The adhesive composition includes: a cyclic organosilazane compound of the following general formula (1): ##STR00001##
wherein R.sup.1s each independently represent a substituted or unsubstituted monovalent hydrocarbon group having 1 to 10 carbon atoms, and p represents an integer of 3 to 8; and a hydrolyzable group-containing organosilicon compound containing an alkoxysilane compound of the following general formula (2) and/or a partial hydrolytic condensate thereof:
R.sup.2.sub.x—Si(OR.sup.3).sub.4-x   (2)
wherein R.sup.2 represents an unsubstituted monovalent hydrocarbon group having 1 to 10 carbon atoms and optionally having an oxygen atom, R.sup.3 represents an unsubstituted monovalent hydrocarbon group having 1 to 10 carbon atoms, and x represents an integer of 0 to 2.

An adhesive film formed of an adhesive composition including a hydroxyl group-containing (meth)acrylic copolymer and a silicone-containing (meth)acrylic compound, the adhesive film having a peel strength ratio of about 50% or more, as calculated by Equation 1, an optical member including the same, and an optical display apparatus including the same are disclosed.

An adhesive film formed of an adhesive composition including a hydroxyl group-containing (meth)acrylic copolymer and a silicone-containing (meth)acrylic compound, the adhesive film having a peel strength ratio of about 50% or more, as calculated by Equation 1, an optical member including the same, and an optical display apparatus including the same are disclosed.

An adhesive film formed of an adhesive composition including a hydroxyl group-containing (meth)acrylic copolymer and a silicone-containing (meth)acrylic compound, the adhesive film having a peel strength ratio of about 50% or more, as calculated by Equation 1, an optical member including the same, and an optical display apparatus including the same are disclosed.

The present invention provides a UV curable adhesive, wherein based on a total weight of the UV curable adhesive, the UV curable adhesive comprises: from 30 to 70 wt % of an acrylate oligomer; from 20 to 65 wt % of an acrylate monomer; from 1 to 10 wt % of acryloyl morpholine; from 1 to 15 wt % of a photo initiator; and from 0 to 10 wt % of a thickening agent, wherein the acrylate oligomer has a weight average molecular weight in a range of from 10,000 to 100,000 grams/mole and a glass transition temperature in a range of from −50 to 0° C. According to the technical solution of the present invention, the adhesive layer obtained from curing the UV curable adhesive is relatively thick (for example, 0.8 mm), and the adhesive layer has good adhesion property, cohesive force, and tackiness.

The present invention provides a UV curable adhesive, wherein based on a total weight of the UV curable adhesive, the UV curable adhesive comprises: from 30 to 70 wt % of an acrylate oligomer; from 20 to 65 wt % of an acrylate monomer; from 1 to 10 wt % of acryloyl morpholine; from 1 to 15 wt % of a photo initiator; and from 0 to 10 wt % of a thickening agent, wherein the acrylate oligomer has a weight average molecular weight in a range of from 10,000 to 100,000 grams/mole and a glass transition temperature in a range of from −50 to 0° C. According to the technical solution of the present invention, the adhesive layer obtained from curing the UV curable adhesive is relatively thick (for example, 0.8 mm), and the adhesive layer has good adhesion property, cohesive force, and tackiness.

Provided by the present invention is a two-component adhesive which includes a first composition and a second composition, in which the first composition contains: a complex derived from an organoborane and a first compound having a first group capable of undergoing an addition reaction to an isocyanate group; and a second compound having a plurality of hydroxy groups, and the second composition contains: a third compound having a plurality of isocyanate groups; a fourth compound having a polymerizable group; and a dehydrating agent. Provided that a mass of the fourth compound in the second composition is X, and that a total mass of the second compound in the first composition and the third compound in the second composition is Y, a value X/(X+Y) is preferably no less than 0.4 and no greater than 0.85.