A primer-attached thermoplastic resin material having a thermoplastic resin material and one or plural primer layers laminated on the thermoplastic resin material, wherein at least one layer of the primer layers is a layer derived from a film.

Provided are a pressure-sensitive adhesive that is suppressed from being reduced in pressure-sensitive adhesive strength at the time of its contact with an oil content or an alcohol component, and a pressure-sensitive adhesive tape including the pressure-sensitive adhesive. The pressure-sensitive adhesive of the present invention is a pressure-sensitive adhesive configured to express an adhesive property by being pressure-bonded, including: an acrylic polymer having an acid functional group; and a crystalline resin having a melting point of 25° C. or more. In one embodiment, the pressure-sensitive adhesive is configured to express the adhesive property by being warmed. In one embodiment, the acrylic polymer having an acid functional group has a constituent unit “a” derived from a (meth)acrylic acid alkyl ester having a linear or branched alkyl group having 4 or more carbon atoms.

Provided are a pressure-sensitive adhesive that is suppressed from being reduced in pressure-sensitive adhesive strength at the time of its contact with an oil content or an alcohol component, and a pressure-sensitive adhesive tape including the pressure-sensitive adhesive. The pressure-sensitive adhesive of the present invention is a pressure-sensitive adhesive configured to express an adhesive property by being pressure-bonded, including: an acrylic polymer having an acid functional group; and a crystalline resin having a melting point of 25° C. or more. In one embodiment, the pressure-sensitive adhesive is configured to express the adhesive property by being warmed. In one embodiment, the acrylic polymer having an acid functional group has a constituent unit “a” derived from a (meth)acrylic acid alkyl ester having a linear or branched alkyl group having 4 or more carbon atoms.

A bonding material is described that is well suited to bonding polymer films, such as polyester films, to other substrates. In one embodiment, for instance, the bonding material can be used to bond a polyester film to a polypropylene article. The bonding material generally comprises an adhesive agent combined with a cross-linking agent. The adhesive agent may comprise a carboxylic acid modified polypropylene homopolymer, copolymer or ionomer. In one embodiment, the adhesive agent comprises a polypropylene modified by an unsaturated dicarboxylic acid anhydride. The cross-linking agent, on the other hand, may comprise an oxazoline polymer.

Provided are an adhesive resin laminate having an excellent adhesive force to two adherends, a laminate in which this adhesive resin laminate is laminated with two adherends, and a method of producing them. An adhesive resin laminate having at least a first adhesive layer and a second adhesive layer, in which the first adhesive layer includes a base resin and a crosslinking agent, the base resin is a modified polyolefin resin, the crosslinking agent is an epoxy-based compound, the second adhesive layer includes a polyolefin-based resin, and when an adhesion initiation temperature of the first adhesive layer is set to T1, and an adhesion initiation temperature of the second adhesive layer is set to T2, T2 is higher than T1 by 30° C. or more.

Provided are an adhesive resin laminate having an excellent adhesive force to two adherends, a laminate in which this adhesive resin laminate is laminated with two adherends, and a method of producing them. An adhesive resin laminate having at least a first adhesive layer and a second adhesive layer, in which the first adhesive layer includes a base resin and a crosslinking agent, the base resin is a modified polyolefin resin, the crosslinking agent is an epoxy-based compound, the second adhesive layer includes a polyolefin-based resin, and when an adhesion initiation temperature of the first adhesive layer is set to T1, and an adhesion initiation temperature of the second adhesive layer is set to T2, T2 is higher than T1 by 30° C. or more.

A pressure sensitive adhesive includes an acryl-based base polymer. The acryl-based base polymer contains an acryl-based segment and a urethane-based segment. In the acryl-based base polymer, the content of the urethane-based segment is 3 to 20 parts by weight based on 100 parts by weight of the acryl-based segment. A pressure sensitive adhesive sheet can be obtained by applying a pressure sensitive adhesive composition on a substrate in a layer form. The pressure sensitive adhesive composition may be curable and may include a polymerization initiator. In formation of the pressure sensitive adhesive sheet, the curable pressure sensitive adhesive composition may be, as necessary.

Provided are adhesives containing a phenoxy resin grafted with methyl methacrylate (MMA) and/or methacrylic acid (MAA), and including a uretdione or a silane. The adhesive compositions are completely or substantially absent free isocyanate. The grafted phenoxy resin forms crosslinking which allows the adhesive to chemisorb to a metal surface, diffuse and entangle in a urethane elastomer and/or provide crossbridging and/or crosslinking across an interface of the adhesive and a cast urethane. Methods of adhering a castable urethane to a substrate, using the provided adhesives, are also provided.

The invention relates to a two-component adhesive based on hybrid urethane-acrylate epoxies comprising a core/shell rubber demonstrating good T-peel strength. The adhesives are suitable for use in industry, e.g., as adhesives for transportation industry applications.

The invention relates to an aqueous polymer dispersion which comprises: a) an aqueous polymer dispersion comprising grafted rubber polymeric particles from rubber polymer being selected from natural or synthetic rubber, b) an aqueous polymer dispersion with polymeric particles of a second polymer comprising monomeric units derived from a monomeric composition b) comprising: b1) a (meth)acrylate of a linear or branched alcohol in C.sub.4 to C.sub.10 or a mixture of such (meth)acrylates, said (meth)acrylate having Tg.sub.b1 lower than −30° C., b2) optionally, at least one comonomer having Tg.sub.b2 higher than −30° C.,

with said grafted rubber polymeric particles being grafted in an aqueous dispersion by a part of said monomeric composition b) as defined above. The invention covers also a specific process of preparation of said dispersion, an adhesive composition comprising said dispersion, the use of said dispersion in pressure sensitive adhesives and the resulting adhesive.