An object of the present invention is to provide a novel electrochromic device (ECD). Disclosed is an electrochromic device (ECD) comprising two metal-complex-based electrochromic thin films individually acting as a working electrode and a counter electrode; (i) one of the two metal-complex-based electrochromic thin films being a film of a cathodically coloring metallo-supramolecular polymer comprising at least one organic ligand having a plurality of metal coordination positions and a metal ion of at least one transition metal and/or lanthanoid metal with the at least one organic ligand and the metal ion being arranged alternately, and the other of the two metal-complex-based electrochromic thin films being a film of an anodically coloring metal hexacyanoferrate (MHCF) represented by the formula: M(II).sub.3[Fe(III)CN.sub.6].sub.2 (where M=Fe, Ni or Zn), and (ii) the electrochromic device having a first conducting substrate; the film of the cathodically coloring metallo-supramolecular polymer; an electrolyte; the film of the anodically coloring metal hexacyanoferrate (MHCF); and a second conducting substrate being arranged in this order.

An object of the present invention is to provide a novel electrochromic device (ECD). Disclosed is an electrochromic device (ECD) comprising two metal-complex-based electrochromic thin films individually acting as a working electrode and a counter electrode; (i) one of the two metal-complex-based electrochromic thin films being a film of a cathodically coloring metallo-supramolecular polymer comprising at least one organic ligand having a plurality of metal coordination positions and a metal ion of at least one transition metal and/or lanthanoid metal with the at least one organic ligand and the metal ion being arranged alternately, and the other of the two metal-complex-based electrochromic thin films being a film of an anodically coloring metal hexacyanoferrate (MHCF) represented by the formula: M(II).sub.3[Fe(III)CN.sub.6].sub.2 (where M=Fe, Ni or Zn), and (ii) the electrochromic device having a first conducting substrate; the film of the cathodically coloring metallo-supramolecular polymer; an electrolyte; the film of the anodically coloring metal hexacyanoferrate (MHCF); and a second conducting substrate being arranged in this order.

An electrochromic film and an electrochromic device including the electrochromic film are disclosed. The electrochromic film includes an electrochromic layer and a passivation layer on one side of the electrochromic layer. The coloration level of the electrochromic film is different from the coloration level of the passivation layer. The film may change optical properties as a result of electrochromism according to an electrochemical reaction. The electrochromic film and the electrochromic device have improved electrochromism, excellent durability, excellent color-switching speed, and stepwise control of optical properties.

An electrochromic film and an electrochromic device including the electrochromic film are disclosed. The electrochromic film includes an electrochromic layer and a passivation layer on one side of the electrochromic layer. The coloration level of the electrochromic film is different from the coloration level of the passivation layer. The film may change optical properties as a result of electrochromism according to an electrochemical reaction. The electrochromic film and the electrochromic device have improved electrochromism, excellent durability, excellent color-switching speed, and stepwise control of optical properties.

A method of producing a photochromic resin body includes a first step, a second step and a third step. In the first step, a sublimable photochromic dye having sublimability is applied to a base body so as to obtain a function-adding base body. In the second step, the function-adding base body obtained in the first step is set to face a resin body, the function-adding base body is heated to sublimate the sublimable photochromic dye applied to the function-adding base body, and the sublimable photochromic dye is deposited on the resin body. In the third step, the resin body on which the sublimable photochromic dye is deposited in the second step is heated to fix the sublimable photochromic dye on the resin body.

A method of producing a photochromic resin body includes a first step, a second step and a third step. In the first step, a sublimable photochromic dye having sublimability is applied to a base body so as to obtain a function-adding base body. In the second step, the function-adding base body obtained in the first step is set to face a resin body, the function-adding base body is heated to sublimate the sublimable photochromic dye applied to the function-adding base body, and the sublimable photochromic dye is deposited on the resin body. In the third step, the resin body on which the sublimable photochromic dye is deposited in the second step is heated to fix the sublimable photochromic dye on the resin body.

Various embodiments herein relate to electrochromic devices and electrochromic device precursors, as well as methods and apparatus for fabricating such electrochromic devices and electrochromic device precursors. In certain embodiments, the electrochromic device or precursor may include one or more particular materials such as a particular electrochromic material and/or a particular counter electrode material. In various implementations, the electrochromic material includes tungsten titanium molybdenum oxide. In these or other implementation, the counter electrode material may include nickel tungsten oxide, nickel tungsten tantalum oxide, nickel tungsten niobium oxide, nickel tungsten tin oxide, or another material.

Various embodiments herein relate to electrochromic devices and electrochromic device precursors, as well as methods and apparatus for fabricating such electrochromic devices and electrochromic device precursors. In certain embodiments, the electrochromic device or precursor may include one or more particular materials such as a particular electrochromic material and/or a particular counter electrode material. In various implementations, the electrochromic material includes tungsten titanium molybdenum oxide. In these or other implementation, the counter electrode material may include nickel tungsten oxide, nickel tungsten tantalum oxide, nickel tungsten niobium oxide, nickel tungsten tin oxide, or another material.

An electrochromic device including an electrode layer, an electrochromic layer and a conductive band having a closed ring shape. The electrochromic device having the above structure has excellent color-switching speeds and electrochromic uniformity.

The present invention relates to a coating of the surface of an electrical household appliance comprising a decoration (a) comprising a pigmentary compound B1VO4 having a ΔE* in the coating greater than or equal to 11 between ambient temperature and 150° C., ΔE* being defined by the formula CIE1976 in the CIELAB colour space: Formula (I): L1*, a1* and b1* characterising the values L*a*b* of said compound at ambient temperature; L2*, a2* and b2* characterising the values L*a*b* of said compound at 150° C.