Quantum dots that are cadmium-free and/or stoichiometrically tuned are disclosed, as are methods of making them. Inclusion of the quantum dots and others in a stabilizing polymer matrix is also disclosed. The polymers are chosen for their strong binding affinity to the outer layers of the quantum dots such that the bond dissociation energy between the polymer material and the quantum dot is greater than the energy required to reach the melt temperature of the cross-linked polymer.

Described are luminescent components with excellent performance and stability. The luminescent components comprise a solid material composition comprising luminescent crystals 11 from the class of perovskite crystals, embedded in a solid matrix 14 comprising a polymer P1 or Small Molecules SM1 and metal selected from Mg, Sr, Ba, Sc, Y, Zn, Cd, In, and Sb. Further described are components and devices comprising the same. Also described are methods for manufacturing such components and devices comprising such components and liquid compositions useful for such manufacturing.

Described are luminescent components with excellent performance and stability. The luminescent components comprise a solid material composition comprising luminescent crystals 11 from the class of perovskite crystals, embedded in a solid matrix 14 comprising a polymer P1 or Small Molecules SM1 and metal selected from Mg, Sr, Ba, Sc, Y, Zn, Cd, In, and Sb. Further described are components and devices comprising the same. Also described are methods for manufacturing such components and devices comprising such components and liquid compositions useful for such manufacturing.

A preparation method and use of a green fluorescent transparent ceramic are disclosed. The preparation method includes: weighing, according to a stoichiometric ratio, elements present in Ca.sub.3-x-yCe.sub.xA.sub.ySc.sub.2-xB.sub.zSi.sub.3-mC.sub.mO.sub.12, in forms of oxides, carbonates or nitrates as raw materials; mixing the raw materials, annealing, melting at a high temperature, cooling and annealing at a low temperature; putting the glass into a high-temperature furnace, holding, raising the temperature, and performing crystallization and densification sintering; finally cutting, reducing and surface-polishing, where A is at least one from the group consisting of Lu, Y, Gd, La and Na; B is at least one from the group consisting of Zr, Hf and Mg; C is at least one from the group consisting of Al and P; x, y, z and m satisfy 0.001?x?0.06, 0?y?0.06, 0?z?0.06 and 0?m?0.3, respectively.

A preparation method and use of a green fluorescent transparent ceramic are disclosed. The preparation method includes: weighing, according to a stoichiometric ratio, elements present in Ca.sub.3-x-yCe.sub.xA.sub.ySc.sub.2-xB.sub.zSi.sub.3-mC.sub.mO.sub.12, in forms of oxides, carbonates or nitrates as raw materials; mixing the raw materials, annealing, melting at a high temperature, cooling and annealing at a low temperature; putting the glass into a high-temperature furnace, holding, raising the temperature, and performing crystallization and densification sintering; finally cutting, reducing and surface-polishing, where A is at least one from the group consisting of Lu, Y, Gd, La and Na; B is at least one from the group consisting of Zr, Hf and Mg; C is at least one from the group consisting of Al and P; x, y, z and m satisfy 0.001?x?0.06, 0?y?0.06, 0?z?0.06 and 0?m?0.3, respectively.

A scintillator includes a support substrate, an emission layer formed on the substrate, made of ZnO with impurities added to have an electron concentration of 210.sup.19 cm.sup.3 or more and 210.sup.20 cm.sup.3 or less, and for generating scintillation light in response to incidence of radiation, a protective layer formed on the emission layer and made of a material having a hand gap wider than that of ZnO, and a metal layer formed on the protective layer. The support substrate is made of a material transmitting the scintillation light generated in the emission layer. Further, the metal layer functions as a reflection layer for reflecting the scintillation light from the emission layer.

A scintillator includes a support substrate, an emission layer formed on the substrate, made of ZnO with impurities added to have an electron concentration of 210.sup.19 cm.sup.3 or more and 210.sup.20 cm.sup.3 or less, and for generating scintillation light in response to incidence of radiation, a protective layer formed on the emission layer and made of a material having a hand gap wider than that of ZnO, and a metal layer formed on the protective layer. The support substrate is made of a material transmitting the scintillation light generated in the emission layer. Further, the metal layer functions as a reflection layer for reflecting the scintillation light from the emission layer.

A phosphor device includes a phosphor layer composed of a phosphor glass or phosphor single crystal, a reflective film provided on the phosphor layer, a warping suppression layer provided on the reflective film, and a supporting body bonded to the warping suppression layer by direct bonding. Excitation light incident into the phosphor layer is converted to fluorescence, and the fluorescence and excitation light are reflected by the reflective film and emitted from the phosphor layer.

Provided is a wavelength conversion member that is less decreased in luminescence intensity with time by irradiation with light of an LED or LD and a light emitting device using the wavelength conversion member. A wavelength conversion member is formed of an inorganic phosphor dispersed in a glass matrix, wherein the glass matrix contains, in % by mole, 30 to 85% SiO.sub.2, 0 to 20% B.sub.2O.sub.3, 0 to 25% Al.sub.2O.sub.3, 0 to 3% Li.sub.2O, 0 to 3% Na.sub.2O, 0 to 3% K.sub.2O, 0 to 3% Li.sub.2O+Na.sub.2O+K.sub.2O, 0 to 35% MgO, 0 to 35% CaO, 0 to 35% SrO, 0 to 35% BaO, 0.1 to 45% MgO+CaO+SrO+BaO, and 0 to 4% ZnO, and the inorganic phosphor is at least one selected from the group consisting of an oxide phosphor, a nitride phosphor, an oxynitride phosphor, a chloride phosphor, an oxychloride phosphor, a halide phosphor, an aluminate phosphor, and a halophosphoric acid chloride phosphor.

Provided is a wavelength conversion member that is less decreased in luminescence intensity with time by irradiation with light of an LED or LD and a light emitting device using the wavelength conversion member. A wavelength conversion member is formed of an inorganic phosphor dispersed in a glass matrix, wherein the glass matrix contains, in % by mole, 30 to 85% SiO.sub.2, 0 to 20% B.sub.2O.sub.3, 0 to 25% Al.sub.2O.sub.3, 0 to 3% Li.sub.2O, 0 to 3% Na.sub.2O, 0 to 3% K.sub.2O, 0 to 3% Li.sub.2O+Na.sub.2O+K.sub.2O, 0 to 35% MgO, 0 to 35% CaO, 0 to 35% SrO, 0 to 35% BaO, 0.1 to 45% MgO+CaO+SrO+BaO, and 0 to 4% ZnO, and the inorganic phosphor is at least one selected from the group consisting of an oxide phosphor, a nitride phosphor, an oxynitride phosphor, a chloride phosphor, an oxychloride phosphor, a halide phosphor, an aluminate phosphor, and a halophosphoric acid chloride phosphor.